• Title/Summary/Keyword: residual time

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Treatment Characteristics of Plating Wastewater Containing Freecyanide, Cyanide Complexes and Heavy Metals (I) (도금폐수내 유리시안과 착염시안 및 중금속의 처리특성 (I))

  • Jung, Yeon-Hoon;Lee, Soo-Koo
    • Journal of Korean Society on Water Environment
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    • v.25 no.6
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    • pp.979-983
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    • 2009
  • The mean pH of wastewater discharged from the plating process is 2, so a less amount of alkali is required to raise pH 2 to 5. In addition, if sodium sulfite is used to raise pH 5 to 9 in the secondary treatment, caustic soda or slaked lime is not necessary or only a small amount is necessary because sodium sulfite is alkali. Thus, it is considered desirable to use only $FeSO_4{\cdot}7H_2O$ in the primary treatment. At that time, the free cyanide removal rate was highest as around 99.3%, and among heavy metals, Ni showed the highest removal rate as around 92%, but zinc and chrome showed a low removal rate. In addition, the optimal amount of $FeSO_4{\cdot}7H_2O$ was 0.3g/L, at which the cyanide removal rate was highest. Besides, the free cyanide removal rate was highest when pH value was 5. Of cyanide removed in the primary treatment, the largest part was removed through the precipitation of ferric ferrocyanide: $[Fe_4(Fe(CN)_6]_3$, and the rest was precipitated and removed through the production of $Cu_2[Fe(CN)_6]$, $Ni_2[Fe(CN)_6]$, CuCN, etc. Furthermore, it appeared more effective in removing residual cyanide in wastewater to mix $Na_2SO_3$ and $Na_2S_2O_5$ at an optimal ratio and put the mixture than to put them separately, and the optimal weight ratio of $Na_2SO_3$ to $Na_2S_2O_5$ was 1:2, at which the oxidative decomposition of residual cyanide was the most active. However, further research is required on the simultaneous removal of heavy metals such as chrome and zinc.

Optimization of organosolv pretreatment with sulfuric acid for enhancing enzymatic hydrolysis of Pitch Pine (Pinus rigida)

  • Park, Na-Hyun;Kim, Hye-Yun;Gwak, Ki-Seob;Koo, Bon-Wook;Yeo, Hwan-Myeong;Choi, In-Gyu
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.505-505
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    • 2009
  • The object is to optimize the best condition of organosolv pretreatment process with sulfuric acid as a catalyst. As a material, Pitch pine (Pinus rigida) was ground and sieved through 40-mesh screen, and Celluclast and $\beta$-glucosidase were used as enzymes for enzymatic hydrolysis. Pretreatment processes were carried out in the minibomb, and 20 g of materials with 200 ml of 50% ethanol solution (v/v) with 1% sulfuric acid as a catalyst. Pretreatment temperature was varied from $150^{\circ}C$ to $190^{\circ}C$, and time was varied from 0 to 20 min. Then, residual materials were used for enzymatic hydrolysis. The best conditions were selected by estimating followed enzymatic hydrolysis rate and degradable rates after pretreatment process. The highest value of enzymatic hydrolysis rate was obtained as 55 - 60% at 160 and at $180^{\circ}C$, but the value decreased under more severe conditions. As the residual rates decreased under severe conditions, it infered that the decrease of sugar contents limits enzymatic hydrolysis rates. Combined with enzymatic hydrolysis rate, degradable rates and H-factors, the temperatures at $160^{\circ}C$ for 20 min and at $180^{\circ}C$ for 0 min were concluded as the optimized conditions where have the lowest H-factor value for considering energy input.

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A Numerical Study on CUSUM Test for Volatility Shifts Against Long-Range Dependence (변동성 변화와 장기억성을 구분하는 CUSUM 검정통계량에 대한 실증분석)

  • Lee, Youngsun;Lee, Taewook
    • The Korean Journal of Applied Statistics
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    • v.27 no.2
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    • pp.291-305
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    • 2014
  • Persistence is one of the typical characteristics appearing in the volatility of financial time series. According to the recent researches, the volatility persistence may be due to either volatility shifts or long-range dependence. In this paper, we consider residual-based CUSUM tests to distinguish volatility persistence, long-range dependence and volatility shifts in GARCH models. It is observed that this test procedure achieve reasonable powers without a size distortion. Moreover, we employ AIC and BIC criteria to estimate the change points and the number of change points in volatility. We demonstrate the superiority of residual-based CUSUM tests on various Monte Carlo simulations and empirical data analysis.

Observation of Size Effect and Measurement of Mechanical Properties of Ti Thin Film by Bulge Test (벌지 실험을 통한 Ti 박막의 크기 효과 관찰 및 기계적 물성 측정)

  • Jung, Bong-Bu;Lee, Hun-Kee;Hwang, Kyung-Ho;Park, Hyun-Chul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.1
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    • pp.19-25
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    • 2013
  • In this study, the mechanical properties of a Ti thin film are measured by a bulge test. In the bulge test, uniform pressure is applied to one side of the film. Measurement of the membrane deflection as a function of the applied pressure allows one to determine the mechanical properties of the film. Ti thin films with thicknesses of 1.0, 1.5, and $2.0{\mu}m$ were deposited on a Si wafer by using an RF magnetron sputtering system. These specimens were annealed at $600^{\circ}C$ for 150, 300, and 600 s to investigate the effect of temperature on the yield stress and mechanical properties of the Ti films. The elastic modulus, residual stress, and yield stress of these membranes are measured by a bulge test. The experimental results suggest that the yield stress is sensitive to the film thickness and annealing time.

Using Hyperspectral Fluorescence Spectra of Deli Commodities to Select Wavelengths for Surveying Deli Food Contact Surfaces

  • Lefcourt, Alan M.;Beck, Elizabeth A.;Lo, Y. Martin;Kim, Moon S.
    • Journal of Biosystems Engineering
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    • v.40 no.2
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    • pp.145-152
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    • 2015
  • Purpose: The inability to adequately judge the efficacy of cleaning and sanitation procedures in deli departments is a recognized food safety concern. In a prior study, our research group demonstrated that visual inspection of cleaned produce processing surfaces could be enhanced through the use of a portable fluorescence imaging device that detected residual produce residues. Methods: To explore the feasibility of using fluorescence imaging to similarly detect residual deli residues, spectra of American, Cheddar, Provolone, and Swiss cheeses and of processed chicken, ham, roast beef, and turkey were acquired using a laboratory hyperspectral imaging system. Circular punches of these commodities were placed onto stainless steel and high density polyethylene coupons for imaging. The coupon materials were selected to represent common surfaces found in deli departments. Results: Analysis of hyperspectral fluorescence images showed that cheeses exhibited peaks in the blue-green region and at around 675 nm. Meats exhibited peaks in the blue-green region with one of four ham and one of four chicken brands exhibiting peaks at around 675 nm, presumably due to use of plant-derived additives. When commodities were intermittently imaged over two weeks, locations of spectral peaks were preserved while intensity of peaks at shorter wavelengths increased with time. Conclusion: These results demonstrate that fluorescence imaging techniques have the potential to enhance surface hygiene inspection in deli departments and, given the immediate availability of imaging results, to help optimize routine cleaning procedures.

Immobilization of Thermolysin for Synthesis of Aspartame Precursor (아스파탐 전구체의 합성을 위한 Thermolysin의 고정화)

  • Han, Min-Su;Kim, Woo-Jung
    • Korean Journal of Food Science and Technology
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    • v.27 no.5
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    • pp.753-756
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    • 1995
  • Optimum conditions for immobilization of thermolysin, a metalloendopeptidase catalyzing synthesis of aspartame precursors, were investigated with using Amberlie XAD-7 as carrier and glutaraldehyde as cross-linking agent. Adsorption of thermolysin onto the carrier was rapid at the initial stage and 96% of the enzyme was adsorbed after 24 hours at $5^{\circ}C$. There was a linear relationship between amount of thermolysin adsorbed and thermolysin loaded upto 300g per liter of carrier. The effective range of cross-linking time, concentration of glutaraldehyde and pH for immobilization of the enzyme were $3{\sim}7\;hours,\;6{\sim}12.5%\;and\;pH\;6.0{\sim}7.0$, respectively. Degree of cross-linking and residual enzyme activity were high when cross-linked for 7 hours with 6% glutaraldehyde or for 3 hours with 12.5% glutaraldehyde. The residual enzyme activity was over 30% under these conditions.

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The Finite Element Formulation and Its Classification of Dynamic Thermoelastic Problems of Solids (구조동역학-열탄성학 연성문제의 유한요소 정식화 및 분류)

  • Yun, Seong-Ho
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.13 no.1
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    • pp.37-49
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    • 2000
  • This paper is for the first essential study on the development of unified finite element formulations for solving problems related to the dynamics/thermoelastics behavior of solids. In the first part of formulations, the finite element method is based on the introduction of a new quantity defined as heat displacement, which allows the heat conduction equations to be written in a form equivalent to the equation of motion, and the equations of coupled thermoelasticity to be written in a unified form. The equations obtained are used to express a variational formulation which, together with the concept of generalized coordinates, yields a set of differential equations with the time as an independent variable. Using the Laplace transform, the resulting finite element equations are described in the transform domain. In the second, the Laplace transform is applied to both the equation of heat conduction derived in the first part and the equations of motions and their corresponding boundary conditions, which is referred to the transformed equation. Selections of interpolation functions dependent on only the space variable and an application of the weighted residual method to the coupled equation result in the necessary finite element matrices in the transformed domain. Finally, to prove the validity of two approaches, a comparison with one finite element equation and the other is made term by term.

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A study of seasonal variation of the residual flow before and after Saemangeum reclamation (새만금간척전 .후 잔차류의 계절변화에 관한 연구)

  • 신문섭
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 1999.10c
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    • pp.155-161
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    • 1999
  • The land reclamation area of Saemangeum(Kunsan) is located between 126$^{\circ}$10' E~126$^{\circ}$50' E and 35$^{\circ}$35' N~356$^{\circ}$05'N at the western coast of the Korean peninsula. The are many small islands including extensive areas of semi-diurnally flooded and dewatered tidal flats. The reclamation area of Saemangeum has a range of 5.6m spring tide and the maximum tidal current speed is about 1.41m s-1 in ordinary spring tide. Most of the sediments deposited on the tidal flats are transported from the Geum river, the Manjyung river and The Dongjin river. The soil in this area consists of silty sand with the depth of 10m to 30m . The wind in winter is strong from the direction of northwest. In the past twenty years, land reclamation projects for agricutural purpose or industrial cocmplex have been mostly implemented along the western coast of Korea. Saemangeum coastal area is being constructed the33km sea dike and 40, 100ha reclamation area. The purpose of this study is to find the residual circulations in four seasons after the dike construction by a robust diagnostic and prognostic numerical model. Heat flux at the sea surface in January ,May , August , October was asopted on the basis on the daily inflow of solar radiation at the earth surface, assuming an average atomospheric transmission and no clouds , as a function of latitude and time of year(George L.P.J.E William, 1990). The discharge from the Geum , the Mankyung and the Dongjin rivers was adopted on the basis of experience formula of river flow in January , May ,August, October (The M. of C.Korea, 1993) . Water temperature and salinity along the open boundaries are obtained from the results of field observation s.

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Prediction of Changing Forest Conditions Using a Simulation Model (Simulation Model에 의한 임분상태(林分狀態)의 변동예측(變動豫測) -임분축적(林分蓄積)의 변동(變動)을 중심으로-)

  • Woo, Jong Choon
    • Journal of Korean Society of Forest Science
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    • v.80 no.1
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    • pp.9-19
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    • 1991
  • This paper discusses the applicability of two simulation models for a ten year planning period in order to predict changing forest conditions. Two simulation models therefore were developed and applied to 3,844 ha of a national forest in Kangwondo province, which is managed by Joongbu Forest District Headquaters. Growth functions of three species were derived and used to predict the residual timber volume over time. Two alternative cutting schedules caused 10-14% difference in the residual timber volume in the end of ten year planning period. This suggests the important of correct decision-makings of forest managers in forest management planning.

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Performance Analysis of NM-MMA Adaptive Equalization Algorithm in Nonconstant Modulus Signal (Nonconstant Modulus 신호에서 NM-MMA 적응 등화 알고리즘의 성능 해석)

  • Lim, Seung Gag
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.17 no.2
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    • pp.113-118
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    • 2017
  • This paper propose the NM-MMA (Novel Mixed-MMA) that is possible to improving the convergence speed of current MMA algorithm and reducing the high MSE of SE-MMA algorithm, and its equalization performance were analyzed. The cost function of the NM-MMA configured as the sum of appropriate weights of gradient vector of current MMA and SE-MMA, and then it used for the updating the tap coefficient of equalizer. The computer simulation was performed applying the same environment in the channel, step size and signal to noise ratio, and the same performance index in equalizer output signal constellation, residual isi, MSE, SER was used. As a result of computer simulation, the proposed NM-MMA has fast convergence time than MMA, and less in MSE and SER performance compared to SE-MMA.