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Removal of Phenol Loaded with Activated Carbon by Potentiostatic Method (정전위전해에 의한 활성탄에 함유된 페놀 제거)

  • 김성우;박승조
    • Resources Recycling
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    • v.10 no.4
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    • pp.18-23
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    • 2001
  • Air pollutants, phenol was generated in case of thermal regeneration of used activated carbon loaded with phenol and because of this problem, removal process of phenol were studied. Electrolytic oxidation of samples, used S.company granular activated carbon (WS-GAC), used C.company granular activated carbon (WC-GAC) and used L.company granular activated carbon (WL-GAC) loaded with phenol carried out by potentiostatic method in this study. In case of experiment was to come into operation in condition of samples containing 100 mg/g phenol, supporting electrolyte was 1.0% sodium chloride solution, Ti-Ir (10$\times$10$\textrm{cm}^2$) electrode and electrode distance was 2 cm, current density was $1.25 A/dm^2$, Obtained from the results of electrolytic oxidation experiments were not detected residual phenol. And then we knew about reaction time of electrolytic oxidation, current density, concentration of supporting electrolyte and electrode and electrode distance were 60 minutes, 1.25 A/dm$^2$, 1.0%, 2 cm.

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Pilot Scale Feasibility Test of In-situ Soil Flushing by using 'Tween 80' Solution at Low Concentration for the Xylene Contaminated Site

  • Um, Jae-Yeon;Lee, Gyusang;Song, Sung-Ho;Hong, Sunwook;Lee, Minhee
    • Journal of Soil and Groundwater Environment
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    • v.18 no.6
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    • pp.38-47
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    • 2013
  • This study was performed to identify the optimal operating conditions and to evaluate the xylene removal efficiency, applying in-situ soil flushing with the low concentrated solution of 'Tween 80' at the xylene contaminated site. The pilot scale test site ($5m{\times}5m{\times}3m$), was mainly composed of 'sandy loam', with the average hydraulic conductivity of $9.1{\times}10^{-4}cm\;s^{-1}$. The average xylene concentration of the site was 42.1 mg $kg^{-1}$, which was more than 2.5 times higher than Korea soil pollution warning limit (15 mg $kg^{-1}$). For the soil flushing, 7,800 L of 0.1~0.2% surfactant solution was injected into three injection wells at the average injection time of 9 hr $d^{-1}$ for 10 days, followed by the additional only groundwater injection of 6,000 L. The same amount of the effluent solution was extracted from three extraction wells. From the analysis for xylene concentration of all effluent at 3 extraction wells, total 166 g of xylene was removed by in-situ surfactant flushing. Even though the residual xylene concentrations of 7 soil sampling locations in the test site were different due to the soil heterogeneity, from the comparison of xylene concentration at 7 locations before/after the feasibility test, 53.9% of the initial xylene in the site was removed from three extraction wells (mainly Ext-N and Ext-M well). The results showed that the in-situ soil flushing by using low concentrated 'Tween 80' solution had a great potential to remediate the xylene contaminated site.

Evidences of in Situ Remediation from Long Term Monitoring Data at a TCE-contaminated Site, Wonju, Korea

  • Lee, Seong-Sun;Kim, Hun-Mi;Lee, Seung Hyun;Yang, Jae-Ha;Koh, Youn Eun;Lee, Kang-Kun
    • Journal of Soil and Groundwater Environment
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    • v.18 no.6
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    • pp.8-17
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    • 2013
  • The contamination of chlorinated ethenes at an industrial complex, Wonju, Korea, was examined based on sixteen rounds of groundwater quality data collected from 2009 to 2013. Remediation technologies such as soil vapor extraction, soil flushing, biostimulation, and pumping-and-treatment have been applied to eliminate the contaminant sources of trichloroethylene (TCE) and to prevent the migration of TCE plume from remediation target zones. At each remediation target zone, temporal monitoring data before and after the application of remediation techniques showed that the aqueous concentrations of TCE plume present at and around the main source areas decreased significantly as a result of remediation technologies. However, the TCE concentration of the plumes at the downstream area remained unchanged in response to the remediation action, but it showed a great fluctuation according to seasonal recharge variation during the monitoring period. Therefore, variations in the contaminant flux across three transects were analyzed. Prior to the remediation action, the concentration and mass discharges of TCE at the transects were affected by seasonal recharge variation and residual DNAPLs sources. After the remediation, the effect of remediation took place clearly at the transects. By tracing a time-series of plume evolution, a greater variation in the TCE concentrations was detected at the plumes near the source zones compared to the relatively stable plumes in the downstream. The difference in the temporal profiles of TCE concentrations between the plumes in the source zone and those in the downstream could have resulted from remedial actions taken at the source zones. This study demonstrates that long term monitoring data are useful in assessing the effectiveness of remediation practices.

Application of the French Codes to the Pressurized Thermal Shocks Assessment

  • Chen, Mingya;Qian, Guian;Shi, Jinhua;Wang, Rongshan;Yu, Weiwei;Lu, Feng;Zhang, Guodong;Xue, Fei;Chen, Zhilin
    • Nuclear Engineering and Technology
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    • v.48 no.6
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    • pp.1423-1432
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    • 2016
  • The integrity of a reactor pressure vessel (RPV) related to pressurized thermal shocks (PTSs) has been extensively studied. This paper introduces an integrity assessment of an RPV subjected to a PTS transient based on the French codes. In the USA, the "screening criterion" for maximum allowable embrittlement of RPV material is developed based on the probabilistic fracture mechanics. However, in the French RCC-M and RSE-M codes, which are developed based on the deterministic fracture mechanics, there is no "screening criterion". In this paper, the methodology in the RCC-M and RSE-M codes, which are used for PTS analysis, are firstly discussed. The bases of the French codes are compared with ASME and FAVOR codes. A case study is also presented. The results show that the method in the RCC-M code that accounts for the influence of cladding on the stress intensity factor (SIF) may be nonconservative. The SIF almost doubles if the weld residual stress is considered. The approaches included in the codes differ in many aspects, which may result in significant differences in the assessment results. Therefore, homogenization of the codes in the long time operation of nuclear power plants is needed.

Thoracoscopic Sympathectomy in Hyperhidrosis (비디오 흉강경을 이용한 다한증의 교감신경 절제술)

  • Sung, Sook-whan;Lim, Cheong;Kim, Joo-Hyun
    • Journal of Chest Surgery
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    • v.28 no.7
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    • pp.684-688
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    • 1995
  • Hyperhidrosis, one of the abnormalities in autonomic nervous system, has been treated with dermatologic principles or thoracic sympathectomy via conventional axillary thoracotomy or dorsal spinal approach. But these techniques were rather ineffective or invasive. Recently, VATS is widely applied in thoracic surgical area, and hyperhidrosis is not the exception of these cases.From May 1993 to August 1994, 30 patients with bilateral palmar hyperhidrosis underwent bilateral thoracic [T2, T3 sympathectomy with thoracoscopic surgery at Seoul National University Hospital. There were 20 men and 10 women and the mean age was 23.0 years.Mean operating time was 115 min and there was no thoracotomy conversion. Operative complications were anesthetic overdose in 1, Horner`s syndrome in 1, and small amount of residual pneumothorax in 6. Mean postoperative hospital stay was 2.3 days [range from 1 to 4 days and postoperative analgesics were required in 17 cases with a single dose.Sweating amount was measured in 12 patients, showing significantly decreased amount from 284.5 mg preoperatively to 18.9 mg postoperatively in 5 minutes [p=0.004 . There was no recurrence during mean 6 months follow up. Twenty two patients [73.3 % complained moderate compensatory hyperhidrosis on the trunk.In conclusion, all patients were greatly satisfied with those results including no more palmar sweating, less pain, better cosmetics, short hospital stay. In addition, recent use of sweating amount measurement and intraoperative temperature monitoring could make this technique more accurate, so we easily applied thoracoscopic sympathectomy with minimal risk.

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Tribological Behaviors on nano-structured surface of the diamond-like carbon (DLC) coated soft polymer

  • No, Geon-Ho;Mun, Myeong-Un;Ahmed, Sk.Faruque;Cha, Tae-Gon;Kim, Ho-Yeong;Lee, Gwang-Ryeol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.356-356
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    • 2010
  • Tribological behaviors of the hard film on soft substrate system were explored using the hard thin film of diamond-like carbon (DLC) coated the soft polymer of polydimethysiloxane (PDMS). A DLC film with the Young's modulus of 100 GPa was coated on PDMS substrate with Young's modulus of 10 MPa using plasma enhanced chemical vapor deposition (PECVD) technique. The deposition time was varied from 10 sec to 10 min, resulting in nanoscale roughness of wrinkle patterns with the thickness of 20 nm to 510 nm, respectively, at a bias voltage of $400\;V_b$, working pressure 10 mTorr. Nanoscale wrinkle patterns with 20-100 nm in width and 10-30 nm height were formed on DLC coating due to the residual stress in compression and difference in Young's modulus. Nanoscale roughness effect on tribological behaviors was observed by performing a tribo-experiment using the ball-on-disk type tribometer with a steel ball of 6 mm in diameter at the sliding speed of 220 rpm, normal load of 1N and 25% humidity at ambient temperature of $25^{\circ}C$. Friction force were measured with respect to thickness change of coated DLC thin film on PDMS. It was found that with increases the thickness of DLC coating on PDMS, the coefficient of friction decreased by comparison to that of the uncoated PDMS. The wear tracks before and after tribo-test were analyzed using SEM and AFM.

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NAPL Removal from Contaminated Soil Using Steam Injection (스팀주입에 의한 토양내 NAPL 제거 실험)

  • Lee, Sang-Il;Jang, Yeon-Su;Kim, Seon-Gi
    • Journal of Korea Water Resources Association
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    • v.30 no.5
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    • pp.459-465
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    • 1997
  • The possibility of NAPL removal from contaminated soil was studied using the steam injection technique. Both single (octane, toluene and xylene) and composite NAPL (gasoline) were used as contaminant. Soils used in this study were Chumunjin fine sand and weathered granitic soil, both of which are commonly found in Korea. Experimental results showed that with 1 pore volume steam injection, the NAPL removal rate was in the range of 66∼78% for sand and 45∼73% for weathered granitic soil. The steam injection technique seems to have high potential for soil remediation with advantages of relatively short operating time and no side-effect. Rise in the background temperature led to the delay of steam condensation and the increase of NAPL mobility, which resulted in the improvement of removal efficiency. In addition, water flooding after steam injection turned out to be a very efficient way of removing NAPL residual in the soil pores.

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A Study on Dissolve and Remove Analysis of Pollutants in Drinking Water by Suspected Cancer Causing Organic Chemicals using AOPs (Advanced Oxidation Processes) & M/F Hybird Process (고도산화와 정밀여과막 혼성공정을 이용한 먹는 물에 존재하는 발암원인으로 의심되는 유기화학성분의 분해 및 제거분석에 관한 연구)

  • An, Tai-Young;Park, Mi-young;Hur, Jang-hyun;Jun, Sang-ho;Han, Mi-Ae;An, Yoon-Hee
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.193-200
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    • 2007
  • The AOPs research defined by creating a sufficient amount of OH radicals from the dissolution of organic materials through photoxidation and research for a complete elimination of residual organic materials by membrane are actively ongoing. This research focuses on the hybrid processing of AOPs and M/F membrane to dissolve and eliminate organic chemicals in drinking water which are suspected of carcinogens. For this purpose, underground water was used as a source of drinking water for the hybrid processing of AOPs oxidation and M/F membrane, and a pilot plant test device was installed indoor. Carcinogenic chemicals of VOCs and pesticide were artificially mixed with the drinking water, which was then diluted close to natural water in order to examine treatment efficiency and draw optimal operation conditions. The samples used for this experiment include four chemicals phenol, chloroform, in VOCs and parathion, carbaryl in pesticide. As a result of the experiments conducted with simple, and compound solutions, the conditions to sufficiently dissolve and eliminate carcinogenic chemicals from the hybrid processing of where carcinogens were artificially added are : (hydrogen peroxide) prescribed solution 100 mg/L under pH 5.5~6.0, and the temperature $12{\sim}16^{\circ}C$, at the normal temperature and pressure. $d-O_3$ volume of 5.0 ppm and above and 30-40 minutes of reaction time are most appropriate and using MF/UF for membrane was ideal.

The Study for Cell Morphology with Gas Cocktail in Microcellular Foaming Process (초미세 발포 공법 시 가스 혼합에 따른 셀 형상 연구)

  • Cha Sung Woon;Yoon Jae Dong;Lee Yoon Sung;Kim Hak Bin
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.6 s.171
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    • pp.168-174
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    • 2005
  • Nowadays, the companies use polymer materials for many purposes fur they have many advantages. The costs of these materials take up too high a proportion of the overall cost of products that use these materials as their major material. It is advantage for polymer industries to reduce these costs. The microcellular foaming process was developed in the early 1980s to solve this problem and proved to be quite successful. Microcellular foaming process uses inert gases such as $CO_2,\;N_2$. As these gases solve into polymer matrices, many properties are changed. The microcellular foaming process makes the glass transition temperature of polymers to low, and diminish the residual stress of polymer matrices. Besides, the microcellular foaming process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. In previous research, many facts of microcellular foaming process are founded its characteristics. But previous researcher found the characteristics of microcellular foaming process with pure gas, for example $CO_2,\;N_2$ and so on, they did not found the characteristics of microcellular foaming process with one more gases. If one more gases inlet the resin, the characteristics of microcellular foaming process is changed very amazingly. In this paper, discuss on the characteristics of microcellular foaming process wi th gas cocktail about cell morphology.

Applying Vinegar as a Disinfectant for Lettuce in Foodservice Operations;A Focused Evaluation of Its Physiological and Sensory Characteristics Effects (단체급식 및 외식업체에서 이용되는 양상추의 식초수 소독의 적용을 위한 연구;이화학적 특성 및 관능적 특성 분석을 중심으로)

  • Kim, Heh-Young;Kim, Hyun-Jung
    • Korean journal of food and cookery science
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    • v.24 no.2
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    • pp.228-235
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    • 2008
  • In this study, vinegar disinfection was evaluated as a novel method for the preparation of raw food ingredients used in foodservice operations. The test materials were washed and disinfected using three different methods, and were then stored at temperatures of $3^{\circ}C\;and\;10^{\circ}$ for 7 days; Following storage, physicochemical and sensory characteristic comparisons were performed. Temperature for all test materials ranged between 15.2-20. $9^{\circ}C$, water activity was maintained near 0.96, and the pH levels of the samples were 6.44, 6.29, and 6.35, respectively. Residual chlorine levels were generally low, ranging between 0.01 and 0.02. The physicochemical qualities of the samples were evaluated according to the storage method and temperature. Brightness(L value), redness(a value), and yellowness(b value) tended to increase with increasing storage time. The evaluated sensory characteristics included appearance, color, smell, taste, texture, and overall acceptance. With regard to storage temperature the vinegar-treated samples were evaluated as superior, receiving a score of 7.00, and the ingredients stored at $3^{\circ}C$ were evaluated as significantly (p< 0.001) superior to those stored at $10^{\circ}C$. Overall, vinegar is an effective disinfectant to apply in the preparation of raw vegetables that are typically served without heating, and which can cause serious food safety issues when contaminated.