• Title/Summary/Keyword: residual oxygen

검색결과 203건 처리시간 0.027초

Borax 및 Boric Acid에 의한 면직물의 일시적 방염 가공 (Non-durable Flame Retardant Finish of Cotton Fabric by Borax and Boric Acid)

  • 남상우
    • 대한가정학회지
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    • 제25권1호
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    • pp.43-50
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    • 1987
  • Non-durable flame retardant finish, borax/boric acid mixed solution, was applied to cotton fabric with pad-dry method. The LOI(limited oxygen index) was measured as the measare of the flame retardant effect. The TGA was investigated to know the thermal behavior of the samples. In addition, the solubility of the solutions was investigated. The results were as follows: 1) There was a synergism of flame retardant effect in the borax/boric acid mixed solution treatment and the maximum synergism was shown around the ratio of 7 : 3 2) After the borax/boric acid solution treatment, the degradation temperature was lowered and degraded at the larger temp range with slower rate. The residual char length also increased. 3) The solubility of borax/boric acid become higher when the ratio of borax/boric acid became similar. Compositions from 80/20 to 40/60 borax/boric acid mixtures were solubilized well in room temperatuare or warmwater therefor there was no problem for home use.

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Laccase를 이용한 Chlorophene 산화전이에 관한 연구 (Laccase-Catalyzed Transformation of Chlorophene)

  • 김종오;김영진
    • 한국환경보건학회지
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    • 제33권1호
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    • pp.63-67
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    • 2007
  • Laccase catalyzes the oxidation and polymerization of aromatic compounds in the presence of molecular oxygen. The oxidative transformation of chlorophene with laccase was conducted in a closed, temperature controlled system. The optimal pH for transformation of chlorophene was proven to be about 5-6. As the temperature rose up to $55^{\circ}C$, the transformation of chlorophene increased. The chlorophene transformation was not enhanced in the presence of soluble polymers. The toxicity of the reaction mixture was increased two times than that of initial reaction mixture after the enzymatic treatment. ABTS has enhanced chlorophene transformation at 0.1 mM and showed negative linear relationship with residual chlorophene by the reaction.

$ZrO_2$와 NiTi 합금의 반응접합 : 분석투과전자현미경을 이용한 $ZrO_2/NiTi$ 접합층 반응생성물 분석 (Reaction Bonding of $ZrO_2$ and NiTi : Reaction Products Analyses on $ZrO_2/NiTi$ Bonding Interface with AEM)

  • 김영정;김환
    • 한국세라믹학회지
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    • 제30권11호
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    • pp.949-954
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    • 1993
  • Microstructural development at the ZrO2/NiTi bonding interface and reaction products were examined and identified with SEM and AEM. Ti-oxide, Ti2Ni and Ni2Ti layer were observed whose thickness depends on bonding temperature typically. The development of Ti-oxide layer is related with oxygen ion in ZrO2 and liquid phase Ti2Ni. It is considered that compositional deviation from homogeneity and residual stress caused by thermal expansion mismatch are closely related with the formation of the Ti2Ni phase.

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관상 정맥동 천정 결손증의 수술치험 1례 (Unroofed Coronary Sinus Syndrome in TOF (Report of one case))

  • 이만복
    • Journal of Chest Surgery
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    • 제23권3호
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    • pp.507-513
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    • 1990
  • We experienced an intraatrial baffle repair for unroofed coronary sinus syndrome in TOF. The patient was a 32-month old female, with complaints of cyanosis, exertional dyspnea and growth retardation. Physical examination showed cyanosis of lip, clubbing of finger, growth retardation and systolic murmur[0 /Gr VI] on left sternal border. With an aid of noninvasive and invasive diagnostic procedure, the patient was diagnosed as TOF combined with unroofed coronary sinus syndrome and LSVC connecting to left atrium. After patch closure of VSD, infundibulectomy and pulmonary valvotomy, the intraatrial baffle redirection of anomalous LSVC to right atrium was undertaken. The Dacron baffle was constructed along the roof of the left atrium to the plane of the atrial septum. The intraatrial septum was then reconstructed with Dacron which was sutured to residual septal tissue. After surgery, the systemic oxygen saturation was elevated to 95.5%, as compared with preoperative value 61%. The postoperative course was uneventful.

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Dependence of superconductivity on the crystallinity of Nb films on Si wafers

  • Choi, Joonyoung;Kim, Chang-Duk;Jo, Younjung
    • 한국초전도ㆍ저온공학회논문지
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    • 제23권4호
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    • pp.1-5
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    • 2021
  • Among elemental metals, niobium (Nb) has the highest superconducting transition temperature (Tc) at ambient pressure. Thus, Nb films have been used in superconducting electronics and radio frequency cavity applications. In this study, the depositional factors determining the crystallinity and Tc of Nb films were investigated. An Nb film grown at a sputtering temperature of 240℃ exhibited the maximum crystallinity of Nb and the minimum crystallinity of niobium oxide. X-ray photoelectron spectroscopy confirmed a maximum atomic percent of niobium and a minimum atomic percent of oxygen. A sputtering power of 210 W and a sputtering time of 50 min were the optimal conditions for Nb deposition, and the Tc of the optimized film (9.08 K) was close to that of bulk Nb (9.25 K). Transmission electron microscopy images of the thick film directly confirmed the removal of the typical in-plane compressive strain in the (110) plane caused by residual stress.

Application of magnetic activated sludge process for a milking parlor wastewater treatment with nitrogen and phosphorus recovery

  • Onodera, Toshihito;Sakai, Yasuzo;Kashiwazaki, Masaru;Ihara, Ikko;Lal, Saha Mihir
    • 한국초전도ㆍ저온공학회논문지
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    • 제23권3호
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    • pp.20-25
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    • 2021
  • Milking parlor wastewater contains high concentration suspended solid (SS), nitrogen, and/or phosphate as well as organic compounds. A new biological wastewater process by magnetic separation, magnetic activated sludge (MAS) process, was applied to milking parlor wastewater treatment process. A three step wastewater treatment process of coagulation sedimentation / ammonia stripping (C/S), magnetic activated sludge process and contact oxidation (CO) was proposed for removal of these pollutants. First step, C/S process recovered 96% TN and 96% PO43--P as resource for fertilizer from the wastewater. 81% biochemical oxygen demand (BOD) in wastewater was removed after MAS process. As a results, all pollutant concentrations satisfied Japanese effluent standards. Most of residual BOD and SS were removed by the CO process. It was estimated that the proposed process could reduce the process space to 1/7.

UNS G41400 강의 인산염 표면 처리에 따른 국부 부식 저항성 (Effect of Phosphate Surface Treatment on the Localized Corrosion Resistance of UNS G41400 Steel)

  • 이준섭;박시욱
    • Corrosion Science and Technology
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    • 제22권6호
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    • pp.429-434
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    • 2023
  • This study investigated the localized corrosion behavior of a UNS G41400 steel surface treated with manganese phosphate. The phosphate coating, primarily composed of oxygen (O), phosphorus (P), and manganese (Mn) elements, had an approximate thickness of 6 ㎛. The particles comprising the coating varied in size by several micrometers; smaller particles were mainly composed of O, P, Mn, and iron (Fe) elements, indicating incomplete formation of the manganese phosphate film. Potentiodynamic polarization curves revealed a decrease in anodic current after surface treatment and a shift in corrosion potential toward the noble direction after treatment. After immersion in a 3.5 wt% NaCl solution for 96 hours, localized corrosion was observed, with some regions retaining residual phosphate film. Even though localized corrosion occurred on the treated surface, it was less severe than that on the untreated UNS G41400 steel surface. These findings suggest that manganese phosphate coating improved resistance to localized corrosion.

육수 충진 포장온도 차이에 따른 레토르트 삼계탕의 저장 중 품질변화 (Quality Changes of Retorted Samgyetang during Storage depending on the Different Filling and Packaging Temperatures of Meat Broth)

  • 장민준;이근택
    • 한국포장학회지
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    • 제18권1_2호
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    • pp.21-25
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    • 2012
  • 본 연구는 레토르트 삼계탕 제품에서 육수의 충진 포장온도가 저장 중 품질과 저장 수명에 미치는 영향을 조사하기 위하여 수행되었다. 공시 레토르트 삼계탕은 육수 충진 온도를 $50^{\circ}C$(T1)와 $85^{\circ}C$(T2)로 달리하여 포장한 후 $120^{\circ}C$에서 65분간 F값 약 8.0의 조건으로 멸균하여 제조되었다. 시료들은 $25^{\circ}C$에서 6개월간 저장하며 0, 1, 3과 6개월차에 pH, 육수 내 용존산소량, 포장의 헤드스페이스 내 산소농도 비율, 산가, VBN, 점도, 관능검사와 퍼짐성에 대하여 분석되었다. 저장기간 중 T2는 T1에 비하여 VBN, 육수 내 용존산소량과 산가가 서서히 증가하는 경향을 보였다. 즉, pH와 육수 내 용존산소는 저장 초기부터, VBN값, 그리고 헤드스페이스 산소농도 비율과 산가는 3개월 후부터 양 처리구간 간에 유의적인 차이를 보였다(p<0.05). 반면, 저장기간 중 두 시료 간 점도, 퍼짐성과 관능검사 결과에서는 유의적 차이를 보이지 않았다(p>0.05). 본 연구결과, 레토르트 삼계탕에서 육수의 충진온도 차이는 관능적 변화에 미치는 영향은 6개월까지 저장하는 동안 통계학적으로 인정되지 않는 수준이었다. 그러나 본 실험이 6개월간 비교적 단기간 이루어진 동안에도 T2에서 T1보다 산가와 VBN값의 증가를 지연시키고 용존산소량을 낮추는 효과가 확인되었다(p<0.05). 결론적으로 레토르트 삼계탕의 품질 변화 최소화 및 장기 저장을 위해서는 육수 충진 시 $85^{\circ}C$ 이상 높여 포장하는 것이 바람직하겠다.

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인스탄트 라면의 안정성(安定性)에 대한 탈산소제(脫酸素劑)의 효과(效果) (Effects of an In-package Oxygen Scavenger on the Stability of Deep-fried Instant Noodle)

  • 마상조;김동훈
    • 한국식품과학회지
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    • 제12권4호
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    • pp.229-234
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    • 1980
  • 라면을 실험실(實驗室) 규모(規模)로 제조(製造)하여 일부(一部)는 Cellophane-PE필름(40 micron)에 (Control), 일부(一部)는 가스 불투과성(不透過性) Nylon-PVC-PE필름(40 micorn)에 탈산소제(脫酸素劑)(Fe-분말형(粉末型)) 및 150 ml의 공기와 함께, 또다른 일부(一部)는 같은 필름에 진공포제(眞空包製)(74 mmHg)하였다. 이상(以上)의 Control 및 시료(試料)를 항온기(恒溫器)$(45.0{\pm}0.5^{\circ}C)$에서 장기저장(長期貯藏)하여 탈산소제(脫酸素劑)의 산소제거능력(酸素除去能力), 각 시료(試料)의 유지성분(油脂成分)의 과산화물(過酸化物)값과 TBA값의 변화(變化)를 조사(調査)하였다. 그 결과(結果)는 다음과 같다. 1. 탈산소제(脫酸素劑)를 사용한 시료(試料)의 경우, 저장(貯藏) 48시간(時間) 후의 포제내(包製內)의 잔존산소량(殘存酸素量)은 포장직후(包裝直後)의 21%에서 0. 5%로 감소하였다. 2. Control, 탈산소제(脫酸素劑)를 사용한 시료(試料) 및 진공포제(眞空包製)한 시료(試料)들의 저장(貯藏) 45일(日) 후의 과산화물값은 $12.4{\pm}0.4$, $5.7{\pm}0.2$$6.8{\pm}0.1\;meq/㎏$이었으며, TBA값은 $1.31{\pm}0.04$, $0.60{\pm}0.04$$0.72{\pm}0.07$로써 Control과 기타 시료(試料)들의 과산화물값 및 TBA값에는 큰 차이가 있었다. 특히 탈산소제(脫酸素劑)를 사용한 시료(試料)의 과산화물값과 TBA값은 Control은 물론(勿論) 진공포제(眞空包製)한 시료(試料)의 경우보다 낮았으며, 따라서 산패(酸敗)에 대해서 더 큰 안전성(安全性)을 갖았었다고 볼 수 있다.

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팔당호와 팔당호 상류의 난분해성 유기물질 유출 특성 분석 및 상관성 분석 (Analysis of Non-Biodegradable Organic Matter Leakage Characteristics and Correlation Analysis in Paldang Lake and its Upper Reaches)

  • 강채원;길경익
    • 한국습지학회지
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    • 제25권4호
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    • pp.221-229
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    • 2023
  • 수도권에 일 약 8백만톤의 물을 취수하여 공급하는 팔당호는 수질보전정책 시행으로 BOD(Biochemical Oxygen Demand)1.1mg/L를 달성하였으나 난분해성 물질을 포함하는 COD(Chemical Oxygen Demand) 항목은 점점 증가하는 양상을 보였다. 난분해성 유기물질의 상수원 유입은 잠재적인 BOD의 증가, 수돗물의 냄새와 맛 유발, THM(Trihalomethane) 발생 증가, 조류 증식을 일으키며 유해 난분해성 미량오염물질이 잔류할 경우 수생 환경에서 내분비 교란과 항생제 내성과 같은 현상을 유발한다. 본 연구에서는 팔당호의 난분해성 유기물질 관리를 위해 팔당호와 팔당호 상류의 점 오염원과 비점오염원의 난분해성 유기물질 유출 농도를 파악하기 위한 모니터링을 실시하였다. 지역별 난분해성 유기물질 유출 농도를 비교하고 하수처리장에서의 제거율을 파악하였다. 또한 피어슨 상관성 분석 기법을 사용해 유기물질 지표와 선행건기일수, 선·선행건기일수간 상관성 분석을 실시하였다. 하천과 팔당호의 난분해성 유기물질 농도는 유사한 양상을 보였다. 하수처리장 유출수는 하천과 팔당호보다는 높은 농도를 보였으며, 유입수와 유출수 농도의 비교 결과 하수처리장에서 난분해성 유기물질 제거율은 65.73%였다. 난분해성 유기물질 유출 농도와 선행건기일수, 선·선행건기일수 사이에서는 유의미한 상관성이 나타나지 않았다. 이는 데이터 부족으로 판단되며 장기적인 모니터링으로 데이터 축적이 필요하다 사료된다.