• Title/Summary/Keyword: residual distribution

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Determination of Heavy Metal Concentration in Herbal Medicines by GF-AAS and Automated Mercury Analyzer

  • Kim, Sang-A;Kim, Young-Jun
    • Journal of Food Hygiene and Safety
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    • v.36 no.4
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    • pp.281-288
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    • 2021
  • This study was conducted to analyze and compare the concentrations of heavy metals in 430 different products of 20 types of herbal medicines available in the domestic market in Korea by Graphite Furnace-Atomic Absorption Spectrometry (GF-AAS) and automated mercury analyzer. The accuracy for lead (Pb), arsenic (As), cadmium (Cd), and mercury (Hg) was in the range 92.67-102.56%, and the precision was 0.21-6.00 relative standard deviation (RSD%), which was in compliance with the Codex acceptable range. Furthermore, the Food Analysis Performance Assessment Scheme (FAPAS) quality control (QC) material showed a recovery range of 96.7-102.0% and 0.33-4.93 RSD%. The average contents (㎍/kg) of Pb, As, Cd, and Hg in herbal medicines were 254.9 (not detected (N.D.)-2,515.2), 171.0 (N.D.-2,465.2), 99.2 (N.D.-797.1), and 6.0 (N.D.-83.6), respectively. Based on the quantitative analysis results, the heavy metal contents of 20 types of herbal medicines distributed in Korea are within the acceptable range according to the standards issued by the Ministry of Food and Drug Safety (MFDS). By using the manufacturer of herbal products as the standard for QC, the Pb, As, Cd, and Hg contents were investigated in the packaging process just before distribution to determine the actual conditions of residual heavy metals in herbal medicines. Thus, these result may contribute to monitoring the QC of herbal medicines distributed in Korea and could provide basic data for supplying safe herbal medicines to the public.

Development of Korean Peninsula VS30 Map Based on Proxy Using Linear Regression Analysis (일반선형회귀분석을 이용한 프락시 기반 한반도 VS30지도 개발)

  • Choi, Inhyeok;Yoo, Byeongho;Kwak, Dongyoup
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.42 no.1
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    • pp.35-44
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    • 2022
  • The VS30 map is used as a key variable for site amplification in the ShakeMap, which predicts ground motion at any site. However, no VS30 map considering Korean geology and geomorphology has been developed yet. To develop a proxy-based VS30 map, we used 1,101 VS profiles obtained from a geophysical survey and collected proxy layers of geological and topographical information for the Korean Peninsula. Then, VS30 prediction models were developed using linear regression analysis for each geological age considering the distribution of VS30. As a result, models depending on geomorphology were suggested per each geologic group, including Quaternary, Fill, Ocean, Mesozoic group and Precambrian. Resolution of map is doubled from that of VS30 map by U.S. Geological Survey (USGS). Standard deviation of residual in natural log of proxy-based VS30 map is 0.233, whereas standard deviation of slope-based USGS VS30 map is 0.387. Therefore, the proxy-based VS30 map developed in this study is expected to have less uncertainty and to contribute to predicting more accurately the ground motion amplitude.

Possibility of Using Landfill Coal Ash as CLSM Material for Emergency Restoration of Ground and Road Joint Parts (지반 및 도로 공동부의 긴급복구용 CLSM 재료로 매립 석탄저회 활용 가능성)

  • Jin-Man Kim;Sang-Chul Shin;Kyoung-Nam Min;Ha-Seog Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.55-61
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    • 2023
  • This study aims to develop CLSM fill material for emergency restoration using landfill coal ash. As a result of examining physical properties such as particle size distribution and fines content of landfill coal ash, bottom ash, fly ash, and general soil were mixed, and SP was found to have a density of 2.03 and a residual particle pass rate of 7.8 %. CLSM materials that secure fluidity in unit quantities without using chemical admixtures such as glidants and water reducing agents have a high risk of material separation due to bleeding. As a result of this experiment, it was found that the bleeding ratio did not satisfy the standard in the case of the specimen with a large amount of fly ash and a lot of addition of mixing water. As a result of the compressive strength test, the strength development of 0.5 MPa or more for 4 hours was found to be satisfactory for the specimens using hemihydrate gypsum with a unit binder amount of 200 or more, and the remaining gypsum showed poor strength development. Although it is judged that landfill coal ash can be used as a CLSM material, it is necessary to identify and apply the physical and chemical characteristics of coal ash buried in the ash treatment plant of each power generation company.

Development of a Site Productivity Index and Yield Prediction Model for a Tilia amurensis Stand (피나무의 임지생산력지수 및 임분수확모델 개발)

  • Sora Kim;Jongsu Yim;Sunjung Lee;Jungeun Song;Hyelim Lee;Yeongmo Son
    • Journal of Korean Society of Forest Science
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    • v.112 no.2
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    • pp.209-216
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    • 2023
  • This study aimed to use national forest inventory data to develop a forest productivity index and yield prediction model of a Tilia amurensis stand. The site index displaying the forest productivity of the Tilia amurensis stand was developed as a Schumacher model, and the site index classification curve was generated from the model results; its distribution growth in Korea ranged from 8-16. The growth model using age as an independent variable for breast height and height diameter estimation was derived from the Chapman-Richards and Weibull model. The Fitness Indices of the estimation models were 0.32 and 0.11, respectively, which were generally low values, but the estimation-equation residuals were evenly distributed around 0, so we judged that there would be no issue in applying the equation. The stand basal area and site index of the Tilia amurensis stand had the greatest effect on the stand-volume change. These two factors were used to derive the Tilia amurensis stand yield model, and the model's determination coefficient was approximately 94%. After verifying the residual normality of the equation and autocorrelation of the growth factors in the yield model, no particular problems were observed. Finally, the growth and yield models of the Tilia amurensis stand were used to produce the makeshift stand yield table. According to this table, when the Tilia amurensis stand is 70 years old, the estimated stand-volume per hectare would be approximately 208 m3 . It is expected that these study results will be helpful for decision-making of Tilia amurensis stands management, which have high value as a forest resource for honey and timber.

Determination of volatile and residual iodine during the dissolution of spent nuclear fuel (사용 후 핵연료 용해 중 휘발 및 잔류 요오드 분석)

  • Kim, Jung Suk;Park, Soon Dal;Jeon, Young Shin;Ha, Young Keong;Song, Kyuseok
    • Analytical Science and Technology
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    • v.22 no.5
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    • pp.395-406
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    • 2009
  • The determination of iodine in the spent nuclear fuel and the volatile behavior during its acid dissolution have been studied by NAA(neutron activation analysis) and electron probe microanalysis (EPMA). Simulated spent fuels (SIMFUELs) were dissolved in $HNO_3$(1+1) at $90^{\circ}C$ for 8 hours. The iodine remained in a dissolver solution after dissolution, and that condensed in dissolution apparatus and trapped in the adsorbent by volatilization during the dissolution were determined, respectively. The condensed iodine was recovered by the redistillation with $HNO_3$(1+1) after transfer of the dissolver solution. The iodines in the dissolver and redistilled solution were separated by solvent extraction followed by ion exchange or precipitation method and determined by RNAA (radiochemical neutron activation analysis). The ion exchange column and filtration kit used for the isolation of iodine, which were prepared with a polyethylene tube, were used as an insert in the pneumatic tube for neutron irradiation. The iodine volatilized during the dissolution of SIMFUELs was collected in a trapping tube containing Ag-silica gel (Ag-impregnated silica gel) adsorbent, and the distribution of iodine trapped in the adsorbents were determined by EPMA. The adsorbing characteristics shown with the SIMFUELs were compared with those shown with a real spent fuel from the nuclear power plant.

Synthesis and characterization of Li3V2(PO4)3/C composite cathode materials using direct co-precipitation method (직접 공침법을 이용한 Li3V2(PO4)3/C 복합체 양극 활물질 합성 및 특성)

  • Jeong-Hwan Song
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.5
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    • pp.167-173
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    • 2023
  • Li3V2(PO4)3 and Li3V2(PO4)3/C composite with single phase monoclinic structure for the cathode materials are successfully synthesized by direct co-precipitation method using N2H4·H2O as the reducing agent and alginic acid as the carbon source, and their electrochemical properties were compared. The particles with approximately 1~2 ㎛ size and the uniform spherical-like morphology of the narrow particle size distribution were obtained. In addition, the residual carbon can also improve the electrical conductivity. The Li3V2(PO4)3/C composite has improved initial specific discharge capacity and excellent cycle characteristics to maintain capacity stably than Li3V2(PO4)3. The results indicate that the reducing agent and carbon composite can affect the good crystallinity and electrochemical performance of the cathode materials.

Genesis and Characteristics of the Soil Clay Minerals Derived from Major Parent Rocks in Korea II. Physical and Chemical Properties of the Whole Soils (한국(韓國)의 주요(主要) 모암(母岩)에서 발달(發達)된 토양점토광물(土壤粘土鑛物)의 특성(特性)과 생성학적(生成學的) 연구(硏究) II. 토양(土壤)의 이화학적(理化學的) 특성(特性))

  • Um, Myung-Ho;Kim, Tai-Soon
    • Korean Journal of Soil Science and Fertilizer
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    • v.24 no.2
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    • pp.79-85
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    • 1991
  • This study reports on the physical and chemical properties of the whole soils (<2mm) derived from five major rocks of granite, granite-gneiss, limestone, shale, and basalt in Korea. The properties were considered from the kind and frequency distribution of rock-forming minerals in the parent rocks. In particle size distribution, sand fractions were high in the soils from granite-gneiss, silt fractions mainly, in the residual soils from limestone, shale, and basalt. And clay fractions were particularly high in the colluvial soil from limestone and the old alluvial soil from basalt. pH, extractable Ca and Mg, and cation exchange capacity of the soils derived from limestone might be considered to be high due to the presence of sand and/or silt-sized calcite and dolomite inherited from the parent rocks. However, the soils derived from granite and granite-gneiss, being abundant in feldspars, quartz, and micas, showed a tendency to the contrary. A soil from shale composing of high quartz tended to have pH. extractable Ca, base saturation, and low exchangeable Al. In total element analysis, the soils derived from parent rocks with high contents of (i) orthoclase and micas, (ii) biotite, primary chlorite, and augite, and (iii) carbonate minerals and plagioclase as a rock-forming mineral showed a tendency to decrease the contents of $K_2O$, $Fe_2O_3$ and MgO, and CaO in comparison with those of their parent rocks.

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Trends and Refractive Status of Cataract Surgery - An Optometry Clinic-Based Survey in Chungbuk (백내장 수술 경향과 굴절상태 - 충북 지역의 안경원 중심으로 조사)

  • Kim, Hyeong-Su;Son, Jeong-Sik;Yu, Dong-Sik
    • Journal of Korean Ophthalmic Optics Society
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    • v.18 no.2
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    • pp.143-148
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    • 2013
  • Purpose: The aim of this study was to investigate the distribution of age and gender, types of intraocular lens (IOL), and refractive errors in subjects who had cataract surgery. Methods: 2,217 subjects who had cataract surgery were surveyed at an optometry clinic in Chungbuk from 2010 to 2012. Information about IOL was obtained from case history, reflective and retroillumination images IOL by auto refracto-keratometer. Refractive errors were determined by objective and subjective refraction. Results: The mean age of the subjects was $71.74{\pm}10.62$ years. The number of cataract surgeries increased from 524 persons in 2010 to 888 persons in 2012. Of the subjects surveyed, 52 persons (2.3%) were under the 40 years of age, 144 persons (6.5%) were in 50s, 404 persons (18.2%) were in 60s, 1,132 persons (51.1%) were in 70s, 485 persons (21.9%) were in above 80s. Cataract surgery was significantly prevalent in more female (1,338 persons, 60.4%) than in male (879 persons, 39.6%). Types of IOL were 2,141 persons (96.6%) for monofocal lens, special IOLs such as multifocal, accommodative and toric lens were 76 persons (3.4%). The distribution of refractive errors after cataract operation were 1,588 eyes (38.5%) for simple myopic astigmatism, 327 eyes (7.9%) for simple hyperopic astigmatism, 601 eyes (14.6%) for mixed astigmatism, 1,240 eyes (30.0%) for myopia, 136 eyes (3.3%) for hyperopia, and 234 eyes (5.7%) for emmetropia. The uncorrected and best corrected visual acuity of the subjects were $0.55{\pm}0.25$ and $0.80{\pm}0.23$, respectively. Conclusions: The prevalence of cataract surgery increased with age until 70s years of age, it was more prevalent in men than women over 60s, and frequency of special types of IOL were low. Most cataract surgeries left residual refractive errors. Therefore even after cataract surgery it may need spectacles for better vision at either distance or near.

Clay Mineralogy of the Soils Derived from Gray Shale (회색혈암(灰色頁岩)에서 유래(由來)된 토양점토(土壤粘土) 광물(鑛物)의 특성(特性))

  • Um, Myung-Ho;Jung, Pil-Kyun;Um, Ki-Tae;Lim, Hyung-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.26 no.1
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    • pp.1-9
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    • 1993
  • A study was carried out to investigate the genesis and mineralogical characteristics of clay minerals in three different types of soil derived from the gray shale distributed in Kyeongbuk Province in Korea. The soils have been developed from parent materials of residuum (Daegu series, Sirye series), colluvium(Banho series), and alluvium (Bigog series) of the same origin of parent rock with a topographical sequence. The investigation mainly focussed on the mineralogical aspects of primary minerals of asnd and silt fractions, identification and quantification of clay minerals, and characterization of hydroxy-interlayered mineral (HIM) along with their chemical composition. The identification was done through analyses of chemical, X-ray diffraction, and thermal methods. The major clay minerals in the soils are illite, vermiculite, kaolin and HIM, while chlorite and mixed layer minerals such as illite/chlorite and illite/vermiculite were coexisted as a subsidiary minerals. The distribution of clay minerals, however, varies according to the location and types of parent material. In the soils derived from the parent material of residuum, the upper soil (Daegu series) shows higher of 2:1 type minerals such as illite, vermiculite, and HIM than 1:1 type mineral rich in the lower soil(Sirye series). Soils developed from the parent material of colluvium and alluvium were high in illlte and mixed layer minerals, but low in HIM compared with the residual soils. The predominant weathering sequence of the clay minerals in each soil could be inferred as follows according to the minerlogical distribution and quantification of clay minerals : Daegu series, illite ${\rightarrow}$ vermiculite ${\rightarrow}$ HIM ; Sirye series, vermiculite ${\rightarrow}$ kaolin minerals ; Banho sereies and Bigog series, illite ${\rightarrow}$ illlte/vermiculite and/or illite/chlorlte mixed layer ${\rightarrow}$ vermiculite.

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PHOTOELASTIC ANALYSIS OF STRESS INDUCED BY FIXED PROSTHESES WITH RIGID OF NONRIGID CONNECTION BETWEEN NATURAL TOOTH AND OSSEOINTEGRATED IMPLANT (골육착성 보철 치료시 임플랜트와 자연 지대치와의 연결 방법에 따른 관탄성 응력 분석)

  • Kim, Young-Il;Chung, Chae-Heon;Cho, Kyu-Zong
    • The Journal of Korean Academy of Prosthodontics
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    • v.31 no.2
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    • pp.271-300
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    • 1993
  • The purpose of this study was to analyze the stress distribution at supporting bone according to the types of connection modality between implant and tooth in the superstrcture. This investigation evaluated the stress patterns in a photoelastic model produced by three different types of dental implants such as Branemark, Steri-Oss, IMZ and resin tooth using the techniques of quasi three dimensional photoelasticity. The teeth-supported bridge had a first molar pontic supported by second premolar and second molar as a control group. The implant and toothsupported bridge had a first molar pontic supported by second premolar and implant posterior retainer as an experimental group. Prostheses were mechanically connected to an adjacent second premolar by the rigid of nonrigid connection, Nonrigid connection used an attachment placed between the tooth-supported and fixture-supported component. The female(keyway) of attachment was placed on the distal end of the retainer supported by the tooth ; the male(Key) of attachment connected to the osseointegrated bridge was engaged into the keyway. All prostheses were casted in the same nonprecious alloy and were cemented and screwed on their respective abutments and implants. 16㎏ of vertical loads on central fossae of second premolar, first molar pontic, implant of second molar were applied respectively and 6.5㎏ of inclined load on middle buccal surface of first molar pontic was applied. The results were as follows : 1. Under the vertical load on the central fossa of first mloar pontic, the stress developed at the apex of tooth of implat was more uniformly distributed in the case of nonrigid connection than in the case of rigid connection. 2. Under the vertical load on the central fossa of first molar pontic, the stress developed around the cervical area of tooth of implant was larger in the case of rigid connection than in the case of nonrigid connection because the bending moment was more occured in the case of rigid connection than in the case of nonrigid connection. 3. Stress was more restricted to the loaded side of nonrigid connection than to that of rigid connection 4. Under the inclined load. The set screw loosening of implant was more easily occured in the case of nonrigid connection than in the case of rigid connection due to torque moment. 5. In the case of Branemark implant, the stress concentration in second premolar was larger and the stress developed around the cervical area of implant was lower than any other cases under the vertical load, because Branemark implant with the flexible gold screw was showed in incline toward second premolar by a bending moment. 6. The stress developed around the apex of tooth or implant was more uniformly distributed in the case of Steri-Oss implant with stiff screw than in the case of Branemark implant under the vertical load. But, the stress developed around the cervical area of the Steri-Oss implant was larger than that of any other implants because bending moment was occured by vertical migration of second premolar. 7. The stress distribution in the case of IMZ implant was similar to the case of natural teeth under small vertical load. But, the residual stress around the implant was showed to occurdue to deformation of IMC and sinking of screw under larger vertical load.

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