• 제목/요약/키워드: relaxation effect

검색결과 1,022건 처리시간 0.026초

Solvent Effect on Stress Relaxation of PET Filament Fibers and Self Diffusion of Crystallites

  • Nam Jeong Kim;Eung Ryul Kim;Sang Joon Hahn
    • Bulletin of the Korean Chemical Society
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    • 제12권5호
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    • pp.468-473
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    • 1991
  • Viscoelastic properties of PET filament fibers on stress relaxation were investigated in the solvents of $H_2$O, 0.05% NaOH and 50% DMF using an Instron (UTM4-100 Tensilon) with solvent chamber. The theoretical stress relaxation equation derived by applying the Ree-Eyring's hyperbolic sine law to dashpot of three element non-Newtonian model was applied to the experimental stress relaxation curves, and the model parameters $G_1,G_2$, ${\alpha}$ and ${\beta}$ were obtained. By analyzing temperature dependency of the relaxation time, the values of activation entropy, activation enthalpy and activation free energy for flow in PET filament fiber were evaluated, the activation free energy being about 25.7 kcal/mol. The self diffusion coefficient and hole distance were obtained from parameters ${\alpha}$, ${\beta}$ and crystallite size in order to study the self diffusion and the orientation of crystallites in amorphous region and the effect of solvent.

Stress relaxation of ABS polymer melts. 1. Effect of weight fraction of rubber particle

  • Cho, Kwang-Soo;Park, Joong-Hwan;Kim, Sang-Yong;Youngdon Kwon
    • Korea-Australia Rheology Journal
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    • 제12권3_4호
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    • pp.157-163
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    • 2000
  • We develop a simple model which can describe and explain abnormal stress relaxation of ABS melt for which stress dose not exponentially decay. The relaxation behavior of ABS melt consists of two distinct relaxation modes. One is the relaxation of the matrix phase similar to the case of homopolymer melt. The other is manifested by the collection of butadiene rubber particles, named as the cluster, where the particles are connected through the interaction between grafted SAN and matrix SAN. The second mode of the relaxation is characterized by the relaxation time, which is a function of the average size and the microscopic state of the cluster. Experimental results reveal that it can be represented as the product of the average size of the clusters by a function of internal variable that represents the fraction of strained SAN chains inside the cluster.

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흰쥐의 대동맥 이완반응에 대한 재수축효과 (The Reversible Contraction on Relaxation of Isolated Rat Aorta)

  • 김진학;신창열;박조영;민영실;최경범;염지현;이남인;김학림;손의동
    • Biomolecules & Therapeutics
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    • 제8권2호
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    • pp.113-118
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    • 2000
  • TEA, glibenclamide, L-NAME and SKF 525A-induced reversible contraction were investigated using acetylcholine, sodium nitroprusside (SNP) and pinacidil in rat abdominal and thoracic aorta. Acetylcho-line, SNP or pinacidil produced in a dose dependent manner relaxation on phenylephrine-induced contraction In rat aorta. TEA, SKF 525A, and L-NAME produced reversible contractions on acetylcholine-induced relaxation, but not on SNP- or pinacidil-induced relaxation. Glibenclamide significantly produced reversible con- traction on pinacidll-induced relaxation. The reversible effect of TEA on the acetylcholine-induced relaxation was reduced by SKF 525A. These results indicate that the acetylcholine-induced relaxation may be mediated by NO, cytochrome P$_{450}$-dependent epoxygenase pathway, or $Ca^{2+}$ activated $K^{+}$ channel, and the pinacidil-induced relaxation may be mediated by ATP-sensitive $K^{+}$ channel.annel.

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Study on Direct Dipolar Effect of Neighboring Protons in Proton Coupled $^{13}C$ Relaxation Experiment

  • 남궁현;이임표;이조웅
    • Bulletin of the Korean Chemical Society
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    • 제21권11호
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    • pp.1077-1084
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    • 2000
  • The dipolar effect of neighboring protons that are not directly bonded to the carbon of interest on coupled carbon-13 relaxation in a simple organic molecule has been studied by comparing the relaxation behaviors of labeled carbon-13 in $Br13CH_2COOH$ with those in $BrCH_213COOH.$ Various pulse sequences, such as coupled inversion recovery pulse sequence, J-negative and J-positive pulse sequence, and nonselective and selective proton ${\pi}pulse$ sequence, were employed to perform the required coupled spin relaxation experiments. To gain information on various spectral densities, including that of dipolar-CSA cross correlation, the experiments were performed on two different spectrometers, operating, respectively, at 50.31 and 125.51MHz for 13C. The magnitude of CH dipolar spectral densities for $BrCH_213COOH$ was found to be about 8% of those for $Br13CH_2COOH$, which means the effect due to the protons not directly bonded to the carbon of interest is small but not completely negligible.

넙다리뒤근육의 유지-이완기법이 무릎관절 각도 증가에 미치는 효과 (Effects of Hamstring HR Technique on Knee Joint Angle Increase)

  • 정은호;김지혁
    • 대한정형도수물리치료학회지
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    • 제24권2호
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    • pp.75-81
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    • 2018
  • Background: The purpose of this study was to investigate the effect of various relaxation techniques on various dysfunction problems caused by shortening of the sagittal muscles. Method: The subjects were 44(18 males, 26 females). The subjects were composed of 3 groups. The experimental group consisted of 14 patients with proprioceptive neuromuscular facilitation stretching (PNF) technique, control group A 15 patients with self myofacial release (SMR) ball exercise, and control group B with 15 patients with Sling exercise. After 3 weeks of relaxation on the hamstring muscle, the length of the hamstring muscle before and after the intervention was compared. Results: The results of relaxation exercise of the snake muscles applied to passive PNF group, SMR ball group, and Sling relaxation group are as follows. 1. In the passive PNF group, the muscle length of the hamstring muscle was significantly increased after the intervention. 2. The muscle length of the hamstring muscle was significantly increased after the intervention in the SMR ball group. 3. Sling relaxation group significantly increased the muscle length of the hamstring muscle after sling exercise intervention. 4. Passive PNF group showed the greatest change in muscle length before and after intervention than SMR ball group and Sling relaxation group. Conclusion: Passive PNF relaxation therapy, SMR ball relaxation therapy, and Sling relaxation therapy applied to the hamstring muscle were effective in increasing muscle length of the hamstring muscle. PNF relaxation therapy showed the most significant effect after 3 weeks intervention.

고강도강(POSTEN60, POSTEN80) 용접접합부의 잔류응력 (Residual Stress in Welds of High Strength Steel( POSTEN60, POSTEN80))

  • 장경호;이진형
    • 한국강구조학회 논문집
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    • 제16권5호통권72호
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    • pp.519-528
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    • 2004
  • 대부분의 용접재는 용접 후 빠른 속도로 냉각하는 과정에서 재료조직의 변화, 즉 상변태(마르텐사이트변태)가 일어난다. 그리고 이러한 상변태에 의한 체적의 팽창은 특히 고강도강재의 용접시 용접부의 잔류응력완화에 기여한다. 따라서 고강도강을 적용한 강구조물 접합부의 잔류응력 특징을 파악하기 위해서는 고강도강 용접시 상변태가 잔류응력완화에 미치는 효과를 정량적으로 평가할 수 있는 수치적 모델을 확립해야 한다. 본 연구에서는 고강도강 용접시 상변태에 의한 체적의 팽창이 잔류응력 완화에 미치는 영향을 잔류응력 측정 실험을 통하여 조사하였고, 이를 바탕으로 상변태에 의한 잔류응력완화를 고려한 고강도강 및 이종강재 용접접합부의 잔류응력 특징을 3차원 열탄소성 해석기법 개발을 통하여 재현하였다.

Effect of Arsenic on Acetylcholine-Induced Relaxation in Blood Vessels in vitro cad in vivo

  • Lee, M.Y.;Chung, S.M.;Bae, O.N.;Chung, J.H.
    • 한국식품위생안전성학회:학술대회논문집
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    • 한국식품위생안전성학회 2002년도 춘계학술발표대회 및 심포지움
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    • pp.137-137
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    • 2002
  • Several epidemiologidal studies suggested that arsenic exposure was strongly correlated with the development of cardiovascular disease such as hypertension. In order to examine whether arsenic affects vasomotor tone in blood vessels, we investigated the effect of arsenic on agonist-induced vasorelaxation using the isolated rat aortic ring in in vitro organ bath system. Treatment with arsenite inhibited acetylcholine-induced relaxation of aortic rings in a concentration- dependent manner. The inhibitory effects by arsenic were also observed in the relaxation induced by sodium nitroprusside, a NO-donor. Consistent with these findings, the cGMP levels stimulated by acetylcholine in blood vessels were reduced significantly by arsenite treatment. In addition, higher concentration of arsenite decreased the relaxation by 8-Br-cGMP, a cGMP analog, in aortic rings without endothelium. These in vitro results indicated that arsenite that arsenite was capable of suppressing acetylcholine-induced relaxation in blood vessels by inhibiting production of nitric oxide in endothelial cells and by impairing the relaxation machinary in smooth muscle cells. In vivo studies revealed that the reduction of blood pressure by acetylcholine infusion was signigicantly suppressed after arsenite was administered intravenously to rate. These data suggest that vasomotor tone impaired by arsenite exposure may be one of the contrbuting factors in development of cardiovascular disease.

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Debye Screening Effect on Scaling Behavior of Longest Relaxation Time of Biological Polyelectrolyte Chain

  • Lee, Jeong Yong;Sung, Jung Mun;Yoon, Kyu;Chun, Myung-Suk;Jung, Hyun Wook
    • Bulletin of the Korean Chemical Society
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    • 제34권12호
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    • pp.3703-3708
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    • 2013
  • The scaling relationship of the longest relaxation time of a single chain of semiflexible biological polyelectrolyte has been investigated by performing well-established coarse-grained Brownian dynamics simulations. Two kinds of longest relaxation times were estimated from time-sequences of chain trajectories, and their behaviors were interpreted by applying the scaling law for different molecular weights of polyelectrolyte and Debye lengths. The scaling exponents for longest stress relaxation and rotational relaxation are found in the ranges of 1.67-1.79 and 1.65-1.81, respectively, depending on the physicochemical interaction of electrostatic Debye screening. The scaling exponent increases with decreasing screening effect, which is a special feature of polyelectrolytes differing from neutral polymers. It revealed that the weak screening allows a polyelectrolyte chain to follow the behavior in good solvent due to the strong electrostatic repulsion between beads.

희렴이 가토(家兎)의 혈관내피세포성(血管內皮細胞性) 이완인자(弛緩因子)에 미치는 영향(影響) (The Effects of Siegesbeckiae Herba on EDRF in the Carotid Artery of the Rabbit)

  • 김호현;김길훤
    • 대한한의학회지
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    • 제18권2호
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    • pp.15-32
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    • 1997
  • This study was undertaken to define the mechanism of Siegesbeckiae Herba-induced relaxation in rabbit common carotid artery contracted by agonists. In order to investigate the effect of Siegesbeckiae Herba on contracted rabbit carotid arterial strips, transverse strips with intact or damaged endothelium were used for the experiment using organ bath. To analyze the mechanism of Siegesbeckiae Herba-induced relaxation, Siegesbeckiae Herba extract infused into contracted arterial strips induced by agonists after treatment of lanthanum chloride, indomethacin, atropine, $N\omega-nitro-{_L}-arginine$, cobalt chloride or methylene blue. The relaxation effect of Siegesbeckiae Herba was dependent on the presence of endothelium, showing that Siegesbeckiae Herba-induced relaxation was not observed in the strips without endothelium. The endothelium-dependent relaxation induced by Siegesbeckiae Herba was suppressed by the pretreatment of lanthanum chloride, $N\omega-nitro-{_L}-arginine$, cobalt chloride or methylene blue, but it was not observed in the strips pretreated with indomethacin or atropine. These results demonstrated that Siegesbeckiae Herba may inhibit agonist-induced contraction through an increase in the cyclic GMP by the production of nitric oxide in the vascular endothelial cells.

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