• Title/Summary/Keyword: relative difference

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Applicability of the HPLC Method for the Estimation of Octanol/water Partition Coefficient to Pesticides of Domestic Use (국내 사용 농약을 대상으로 한 HPLC 방법에 의한 옥탄올/물 분배계수 추정법의 적용성 검토)

  • Kim, Kyun;Kwon, Jin-Wook;Kim, Yong-Hwa
    • Environmental Analysis Health and Toxicology
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    • v.16 no.4
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    • pp.189-196
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    • 2001
  • Octanol/water partition coefficients of 52 chemicals were calculated using RP-HPLC estimation method and predicted by computer program, PCHEM. The result showed relationship between literature values and RP-HPLC observed values (relative coefficient r$^2$=0.916), but the relationship of PCHEM values with literature values was lower than RP-HPLC value (relative coefficient r$^2$=0.795). The average difference in partition coefficient between the RP-HPLC method and flask-shaking method was log Kow=0.54, while the average difference between the values predicted form the computer program and flask- shaking method was log Kow = 0.36 Compared to octanol/water partition coefficients by 3 methods (Flask-shaking, RP-HPLC, computer prediction), the octanol/water partition coefficient values based on the flask-shaking method were very similar to the literature values, while the octanol/water partition coefficient values by RP-HPLC method without to consider the dead time, and computer prediction values did not significantly differ with the literature values.

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Geminate and singleton contrast in English affixed words

  • Yu, Hye Jeong
    • Phonetics and Speech Sciences
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    • v.14 no.3
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    • pp.67-76
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    • 2022
  • This paper presents two experiments examining different gemination behavior of English affixes. Experiment 1 focused on geminates through affixation with im-, un-, -ness, and -ly. The English group articulated geminates with longer absolute and relative durations than singletons for im-, un-, and -ness, but there was no difference for -ly. This suggests that -ly words are more likely to be perceived as whole words, and that -ly is less decomposable. Furthermore, un- geminates exhibited longer absolute and preceding vowel durations than im- geminates, suggesting that im- is more decomposable than un-. However, the Korean group produced geminates with longer absolute and relative durations than singletons for all im-, un-, -ness, and -ly, and produced comparable absolute durations of im- and un- geminates. Experiment 2 investigated different gemination behaviors of locative and negative im- prefixes. The English group showed durational contrast between geminates and singletons only for negative im-, indicating that locative im- is not easily separated from stem. However, the Korean group produced longer absolute and relative durations for geminates than for singletons for both locative and negative im-. According to the findings of Experiments 1 and 2, affix decomposability is less likely to influence Korean speakers' English affix gemination, and spellings may have a greater influence.

Relationship between Climate Factors and Relative Growth of Pinus rigida and Castanea crenata in the Cheongju Area of Chungbuk (충북 청주지역 리기다소나무와 밤나무의 상대 생장률과 기후인자와의 관계)

  • Kim, Kee Dae
    • Journal of Environmental Science International
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    • v.26 no.5
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    • pp.585-590
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    • 2017
  • The Diameter at Breast Height (DBH) provides information about the volume growth of a tree. In this study, we estimated the relative growth rates of Castanea crenata and Pinus rigida as 4.07% and 3.73%, respectively. Although the difference was low, we demonstrated that the growth rate of C. crenata is slightly faster than that of P. rigida. After calculating the relative growth rate for each section, we found that the relative growth of C. crenata decreased with time. However, the relative growth rate of P. rigida showed an overall increase. The gap widths of both species showed an increasing trend. However, the gradient of the two species was different. The gradient of C. crenata was approximately 12.0, but that of P. rigida was approximately 4.7. This means that the volume growth of C. crenata was faster than that of P. rigida during 4 years. However, this was relatively a short period for measuring the volume growth pattern, and we believe that additional useful information can be obtained by conducting long-term ecological monitoring. Results of canonical correspondence analysis showed that among the climate variables, temperature was significantly related to the gap widths for both species.

Selectivity of between K+ and Na+ Ions to 12-Crown-4: QSPR Analysis by a Monte Carlo Simulation Study

  • Kim, Hag-Sung
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.431-437
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    • 2008
  • The solvent effects on the relative free energies of binding of K+ and Na+ ions to 12-crown-4 and Dlog Ks (the difference of stability constant of binding) have been investigated by a Monte Carlo simulation of statistical perturbation theory (SPT) in several solvents. Comparing the relative free energies of binding of K+ and Na+ ions to 12-crown-4, in CH3OH of this study with experimental works, there is a good agreement among the studies. We have reported here the quantitative solvent-polarity relationships (QSPR) studied on the solvent effects the relative free energies of binding of K+ and Na+ ions to 12-crown-4. We noted that DN(donor number) dominates the differences in relative solvation Gibbs free energies of K+ and Na+ ions and DN dominates the negative values in differences in the stability constant (Dlog Ks) as well as the relative free energies of binding of K+ and Na+ ions to 12-crown-4 and p* (Kamlet-Tafts solvatochromic parameters) dominates the positive values in differences in the stability constant (Dlog Ks) as well as the relative free energies of binding of K+ and Na+ ions to 12-crown-4.

Estimation of the Relative Density and Internal Friction Angle for Sand using Cone-tip Resistance of the PCPT (휴대용콘의 선단저항값을 이용한 모래의 상대밀도 및 내부마찰각 추정)

  • Park, Jae-Sung;Son, Young-Hwan;Noh, Soo-Kack;Bong, Tae-Ho
    • Journal of The Korean Society of Agricultural Engineers
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    • v.54 no.4
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    • pp.137-145
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    • 2012
  • Sand is one of the essential materials used for social infrastructure construction such as embankment, landfill and backfill. It was known that mechanical properties and shear strength of sand are closely related to relative density. Therefore it is very important to determine accurate relative density. In this study, Portable Cone Penetration Tester (PCPT) was used to estimate the relative density and the internal friction angle of sand. PCPT cone-tip resistance ($q_c$) was measured changing the relative density of the two soil samples.Standard sand (JMJ) and Busan sand (BS). Also, a direct shear test was performed to investigate relationship between relative density and internal friction angle. The size and shape of soil particles were confirmed by using Scanning Electron Microscope (SEM). As a result, the log value of $q_c$ was linearly correlated with relative density and internal friction angle. In particular, the internal friction angle of BS sample was greater than that of JMJ, which was due to difference of the shape and mean size of particles. This result shows that it is important to determine the shape and size of particles as well as relative density to define mechanical property of sand. Through this study, it can be more effectively and conveniently to investigate relative density and shear strength of sand by using PCPT in situ.

A Heat Loss Comparison Between the Two Parabolic Fin Models Using Two Different Numerical Methods

  • Kim, K.T.;Kang, H.S.
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.2 no.2
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    • pp.97-109
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    • 1998
  • A comparison of the two dimensional heat loss, computed using the analytical method and the finite difference method in two models(i.e. one is a parabolic fin whose parabolic curves meet at the fin center line and the other is a transformed parabolic fin whose tip cuts vertically), is made assuming the analytical method is correct. For these methods, the root temperature and surrounding convection coefficients of these fins are assumed as constants. The results show that the relative errors of the heat loss between the two methods for the parabolic fin whose tip cuts vertically are smaller than those for the one whose tip does not cut. In case of Bi=0.01, the values of the heat loss obtained using a finite difference method are close to those values obtained using the analytical method for both models. The values of the heat loss from both models calculated by using the analytical method are almost the same for given range of non-dimensional fin length in case of Bi = 0.01 and 0.1.

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The Relationship between Viscosity of Soluble Dietary Fiber and their Hypoglycemic Effects (수용성 식이섬유소의 점도가 혈당강하에 미치는 영향)

  • 김은희
    • Journal of Nutrition and Health
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    • v.29 no.6
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    • pp.615-621
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    • 1996
  • Experiments were carried out in humans to assess the relationship between viscosity and post-prandial glucose response of soluble fibers. Eight(3 male and 5 female) healthy individuals were tested for their glucose response after taking control meals or 3 test fiber meals of different viscosities. Meal viscosity of the test food was adjusted to be between 200 and 70, 000 cps. There was a significant increase in post-prandial glucose response(p=0.01) in control meals by solely increasing the volume of water. Fiber with the highest viscosity konjac mannan demonstrated the lowest relative glucose response(70.1$\pm$6.6), followed by medium viscosity xanthan (79.3$\pm$8.7)and low viscosity psyllium (86.3$\pm$10.5). The difference is significant at the level of p<0.05. However, no significant difference in relative glucose response of the same fiber was found when the 4 levels of water were added to make different meal viscosity of each fiber (p=0.476). This result suggested that hypoglycemic action of soluble dietary fibers is related to fiber viscosity rather than meal viscosity.

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Stacking Durability Analysis of Fruit , Packaging Boxes by Creep (크리이프에 의한 과실 포장입자의 층적 내구성 분석)

  • 박종민;권순홍;권순구;김만수
    • Journal of Biosystems Engineering
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    • v.21 no.2
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    • pp.191-197
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    • 1996
  • Allowable stacking duration of the corrugated fiberboard boxes being widely used for packaging fruits and vegetables was analyzed by the creep behavior and the cumulative load correction factor for the boxes. The stacking boxes were assumed to be stored at a nearly constant temperature and relative humidity condition. When the stacking duration was short period, the stacking height determined by two methods showed a little difference between them, but almost no difference was shown as the stacking duration was longer. Allowable stacking duration was rapidly decreased with the increase of static load applied on the stacking boxes, and allowable stacking duration of Box A was estimated the longer than that of Box B. A model of allowable stacking duration for the corrugated fiberboard box was developed as a function of the stacking load and the ambient relative humidity.

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Characteristics of $CH_4$ Reforming by Rotating Arc (회전 아크를 이용한 메탄 개질 반응에서 플라즈마 모드에 따른 개질 특성)

  • Kim, Dong-Hyun;Lee, Dae-Hoon;Kim, Kwan-Tae;Song, Young-Hoon
    • Journal of the Korean Society of Combustion
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    • v.11 no.2
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    • pp.15-21
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    • 2006
  • Characteristics of a plasma reactor for partial oxidation of methane, especially focused on the role and effectiveness of plasma chemistry, are investigated. Partial oxidation of methane is investigated using a rotating arc which is a three dimensional version of a typical gliding arc. Three different modes of operation were found. Each mode shows different reforming performance. The reason for the difference is due to the difference in relative role of thermal and plasma chemistry in overall process. A mode with high temperature results higher methane conversion and hydrogen selectivity in contrast to the mode with lower temperature where poor methane conversion and higher selectivity of $C_2$ species are observed. In this way, we can confirm that by controlling characteristic of process or controlling relative strength of plasma chemistry and thermal chemistry, it is possible to map an optimal condition of reforming process by rotating arc.

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Familism and Social support network of separated family who came over the border (월남이산가족의 가족주의와 사회적 지원망)

  • 이성희
    • Journal of the Korean Home Economics Association
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    • v.31 no.4
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    • pp.95-113
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    • 1993
  • The goal of this study is to try to grasp the general feature, familism, and social support network of the separated family who came south over the border, on them who are residing inland, as a part of the work to clarify the diverse form and specialty that Korean family have. To summarize the result simply is as follows: 1. The difference is showing, between separated family and non-separated family, in the family preference and the consciousness to respect parents, among the range of familism. That is, in case of the separated family, family preference and the consciousness to respect parents showed higher, in comparison with the non-separated family. 2. Between separated family and non-separated family, the difference showed only in the support network of relative. So, the support network of relative of non-separated family showed higher than that of separated family. Through above conclusion, the situation which is the losing native place and the separated which occurred due to war and the dividing into sections is influencing our family life. But, on the other hand, it can be seen that the influence is becoming void gradually.

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