• 제목/요약/키워드: relative $_pL^*-order$

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염화에텐의 환원성 탈염소화 모텔을 이용한 수소 경쟁에 대한 평가

  • 이일수;배재호
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2002년도 추계학술발표회
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    • pp.117-121
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    • 2002
  • A numerical model that describes the reductive dechlorination of tetrachloroethene(PCE) to ethene via cis-dichloroethene(CDCE) was developed. The model included two separated dehalogenator groups : one for PCE transformation to cDCE via TCE and the other for cDCE dehalogenation to ethene via VC, competitive inhibition between different chloroethene electron accepters, and competition for H$_2$ between dechlorination and methanogens. Model simulations suggest first, that PCE dechlorinators are better competitive with methanogens than cDCE dechlorinators. Second, not only the initial relative population size of dehalogenators and H$_2$-utilizing methanogens but also electron donor delivery strategies used greatly affects the degree of dehalogenation. As a result, all of factors in the above must be considered in order to achieve economical and successful bioremediation of contaminated soil and groundwater with chlorinated solvents.

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고체상미량추출법을 이용한 BTEX와 MTBE의 경쟁적 추출효과 및 미량분석에 관한 연구 (Competitive Extraction and Trace Analysis of BTEX and MTBE by Solid-Phase Microextraction (SPME))

  • 안상우;천석영;이시진;박재우;장순웅
    • 한국물환경학회지
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    • 제26권4호
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    • pp.622-628
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    • 2010
  • In this study, Solid-phase microextraction (SPME) with GC/FID was studied as a possible alternative to liquid-liquid extraction for the analysis of BTEX and MTBE. Experimental parameters affecting the SPME process (such as kind of fibers, adsorption time, desorption time, volume ratio of sample to headspace, salt addition, and magnetic stirring) were optimized. Experimental parameters such as CAR/PDMS, adsorption time of 20 min, desorption time of 5 min at $250^{\circ}C$, headspace volume of 50 mL, sodium chloride (NaCl) concentration of 25% combined with magnetic stirring were selected in optimal experimental conditions for analysis of BTEX and MTBE. The general affinity of analytes to CAR/PDMS fiber was high in the order p-Xylene>Toluene>Ethylbenzene>MTBE>Benzene. The linearity of $R^2$ for BTEX and MTBE was from 0.970 to 0.999 when analyte concentration ranges from $30{\mu}g/L$ to $500{\mu}g/L$, respectively. The relative standard deviation (% RSD) were from 2.5% to 3.2% for concentration of $100{\mu}g/L$ (n=5), respectively. Finally, the limited of detection (LOD) observed in our study for BTEX and MTBE were from $7.5{\mu}g/L$ to $15{\mu}g/L$, respectively.

수종의 귀화식물 수용성추출물의 제초 및 항균 활성 탐색 (Herbicidal and Antifungal Activities of the aqueous extracts of Several Naturalized Plants)

  • 현도경;송진영;김태근;정대천;송상철;강영식;차진우;이희선;양영환;김현철;송창길
    • 한국유기농업학회지
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    • 제22권2호
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    • pp.303-319
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    • 2014
  • 본 연구는 귀화식물인 Solidago altissima, Amaranthus retroflexus, Sida spinosa 등을 이용하여 친환경 농자재로 개발하기 위한 기초자료를 제공하기 위해 수용성 추출액의 농도에 따른 수용체 식물의 발아 및 유식물 생장과 실험 병원균의 생장을 조사하였다. 공여체식물에 따른 수용성 추출액 농도가 증가됨에 따라 대부분 검정식물의 상대발아율은 감소하는 경향을 보이는데 S. spinosa(r=-0.540, p<0.01), Physalis wrightii(r=-0.693, p<0.01), A. retroflexus(r=-0.724, p<0.01), S. altissima(r=-0.728, p<0.01), Eclipta prostrata(r=-0.779, p<0.01) 순으로 감소하는 경향이 큰 것으로 조사되었고 평균발아일수도 처리구 농도가 증가함에 따라 발아하는데 소요되는 시간이 증가 되었으며(r=0.769, p<0.01) 공여체식물과 검정식물에 따라 약간의 정도 차이를 보였다. 또한 공여체식물의 수용성 추출액 농도가 증가함에 따라 유식물의 지상부의 길이(r=-0.587, p<0.01), 지하부의 길이(r=-0.741, p<0.01), 생체량(r=-0.574, p<0.01)과 뿌리털의 발생도 감소하였다. 한편 공여체식물의 수용성추출액 농도 증가에 따른 검정 병원균의 생장은 Botrytis cinerea(r=-0.266, p<0.05), Diaporthe citri(r=-0.323 p<0.01), Colletotrichum gloeosporioides(r=-0.512, p<0.01), Pythium ultimum(r=-0.581, p<0.01), Rhizoctonia solani(r=-0.806, p<0.01) 순으로 생장이 억제되었다. 제초 및 항균활성을 보이는 수용체식물의 총 페놀 함량은 S. altissima $17.3{\pm}0.5mg/g$, A. retroflexus $13.1{\pm}0.3mg/g$, P. wrightii $12.0{\pm}0.4mg/g$, S. spinosa $9.5{\pm}0.1mg/g$, E. prostrata $4.1{\pm}0.1mg/g$ 순으로 분석되었다. 이들 결과를 종합하면 귀화식물인 수용체식물들은 자생식물과의 경쟁을 함에 있어 알레로패시 효과를 나타내는 페놀 화합물 등이 수관 내 토양으로 방출하여 하부식생에 대한 발아 및 생장과 토양미생물 생장 등에 영향을 주기 때문에 경쟁적 우위를 점하고 있으며, 천연제초제 살균제로서의 활용 가능성을 가지고 있는 것으로 판단된다.

품종 및 반전횟수가 추계수확 연맥건초의 사료가치에 미치는 영향 (Effect of Cultivar and Tedding Frequency on the Quality of Fall Harvest Oat Hay)

  • 한건준;김동암
    • 한국초지조사료학회지
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    • 제16권2호
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    • pp.169-176
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    • 1996
  • An experiment was carried out to determine the effect of cultivar and tedding frequency on changes of moisture content of oat(Avena sativa L.) hay during field drying and on quality of baled oat hay after storage. The experimental design was a split-plot with the four oat cultivm such as 'Magnum', 'Cayuse', 'West' and 'Murray' as main plots and the two tedding frequencies such as 1 or 3 times a day as subplots in three replications. Moisture content of fresh cut oat cultivar was higher in the order of 'Magnum', 'Cayuse', 'West', and 'Murray' and the moisture content difference among the cultivm was maintained to the final curing day(P< 0.05). Moisture loss from the oat hay during the last 3 curing days was greater with 3 tedding a day than I tedding a day. Temperature of baled oat hay began to rise critically from the 6th day of storage and wa5 highest in 'Magnum' oat cultivar($45.3^{\circ}C$). Total nitrogen and ADIN contents of late maturing oat hay 'Magnum' and 'Cayuse' were higher than those of early maturing 'Murray' and 'West'. Tedding frequency did not influence total nitrogen and ADIN contents. ADF and NDF contents of early maturing oat hay were higher than those of late maturing oat hay. Relative feed value (RFV) of 'Magnum' oat hay was the highest(l06) and classified as Grade 2 in forage quality standard. Quality grade difference between early and late maturing oat cultivan was only 1 or 2.

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파종시기가 테오신트 [Zea mays L. subsp. mexicana (Schrad.) H. H. Iltis] 신품종 "극동 6호"의 생육 특성, 수량 및 사료가치에 미치는 영향 (Effects of Seeding Dates on the Growth Characteristics, Dry Matter Yield and Feed Value of Teosinte New Variety, "Geukdong 6" [Zea mays L. subsp. mexicana (Schrad.) H. H. Iltis])

  • 김경숙;이상무
    • 한국초지조사료학회지
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    • 제39권1호
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    • pp.9-16
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    • 2019
  • 본 연구는 최근 개발되어 국내에 보급하고 있는 Teosinte [Zea mays L. subsp. mexicana (Schrad.) H. H. Iltis] 품종인 극동 6호의 파종시기가 생육특성, 수량성 및 사료가치에 미치는 영향을 평가하기 위하여 실시하였다. 파종 시기는 각각 5월 10일(T1), 5월 25일(T2), 6월 10일(T3), 6월 25일(T4) 및 7월 10일(T5)로 하고 수확은 10월 22일 동일 날짜에 하였다. 따라서 재배기간은 T1, T2, T3, T4 및 T5구가 각각 164, 149, 134, 119, 103일로 난괴법 5처리 3반복으로 실시하였다. 초장과 고사엽은 T1구에서(p<0.05), 엽폭과 엽수는 T2구에서 유의적으로 높게 나타났다(p<0.05). 그러나 엽장, 경의 굵기 및 분얼수는 처리 간 유의적인 차이를 보이지 않았다. 경경도는 T1(2.0)> T2(1.9) > T3, T4(1.7) > T5($1.2kg/cm^2$) 순으로 높게 나타났다(p<0.05). 생초 및 건물수량은 파종시기가 빠르고 재배 기간이 길었던 T1 > T2 > T3 > T4 > T5 순으로 높게 나타났다(p<0.05). 조단백질, 조지방 및 TDN 함량은 T5가 다른 구에 비하여 유의적으로 높게 나타났다(p<0.05). 그러나 ADF 및 NDF 함량은 T1구에서 높게 나타났다 (p<0.05). 조단백질 수량은 T1, T2 및 T3구 사이에는 유의적인 차이가 없었지만, T4 및 T5구에서는 유의적으로 낮게 나타났다(p<0.05). TDN 수량은 T1 > T2 > T3 > T4 > T5구 순으로 높게 나타났다(p<0.05). 그러나 사료가치는 T5 > T4 > T3 >T2 > T1 구 순으로, 파종시기가 늦고 재배기간이 짧을수록 유의적으로 높게 나타났다(p<0.05). 당 성분들에 있어서는 당도, Fructose, Glucose, Isomerose, Inverted sugar 성분에서는 처리 간에 유의적인 차이가 없었다. 그러나 Dextran 성분은 T5구에서 만유의적으로 낮은 수치를 보였다. 이상의 결과를 종합해 볼 때, 극동 6호의 파종 시기는 5월 상순에서 하순사이에 파종하여 약 150일 이상 재배한 후 수확하는 것이 건물수량과 영양수량 생산에 유리한 것으로 판단된다.

Effect of Cutting Height on the Feed Value and Drying Rate of Rye (Secale cereale L.) Hay

  • Li, Yu Wei;Kim, Jong Geun
    • 한국초지조사료학회지
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    • 제37권3호
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    • pp.201-207
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    • 2017
  • Hay-making is one of the most common forage preservation practices in livestock operations. The objective of hay-making is to minimize nutrient loss by shortening field drying time. Measuring the impacts of cutting height of forage crop is necessary to optimize hay production balancing yield and quality, in order to obtain substantial biomass increase through harvest of regrowth. This experiment was conducted to investigate the impact of cutting height of rye (Secale cereale L.) on drying rate and hay quality. Heading stage rye was harvested at 8cm or 15cm stubble heights. Hay was daily tedded at 09:00 and sampled at 09:00, 13:00 and 17:00 to determine moisture content (MC). After two month of preservation, CP (crude protein), ADF (acid detergent fiber), NDF (neutral detergent fiber), IVDMD (in vitro dry matter disappearance), TDN (total digestible nutrient), RFV (relative feed value), DM (dry matter) loss, visual scores and total fungi count were determined for estimation of hay quality. Cutting height at 15cm could enhance the drying rate and CP content (p<0.05), but also increases DM loss (p<0.05) compared to cutting at 8cm. Cutting heights did not affect ADF, NDF, IVDMD, TDN and RFV value (p>0.05). Visual scores of rye hays cutting at 8cm and 15cm, ranged from 83 to 85. Cutting at 8cm tended to maintain higher core bale temperature and fungal count than cutting at 15cm during preservation, but there was no significant difference.

The Second-order Scattering of the Interaction of Pd Nanoparticles with Protein and Its Analytical Application

  • Guo, Xiaoyan;He, Baolin;Sun, Chuntao;Zhao, Yanxi;Huang, Tao;Liew, Kongyong;Liu, Hanfan
    • Bulletin of the Korean Chemical Society
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    • 제28권10호
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    • pp.1746-1750
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    • 2007
  • The second-order scattering (SOS) phenomenon of the interaction of Pd nanoparticles with protein was reported and a simple, sensitive, palladium nanoparticle-based assay for trace amount of protein with SOS technique was developed. The SOS intensities were significantly enhanced due to the interaction of Pd nanoparticles with bovine serum albumin (BSA) or human serum albumin (HSA) at pH 3.5 or 4.0, respectively. The maximum SOS peak appeared at 260/520 nm (λex/λem). The optimal experiment conditions, affecting factors and the influence of some coexisting substances were checked. The SOS intensity increased proportionally with the increase of Pd concentration below 3.0 × 10?5 mol·L?1, while declined gradually above 4.0 × 10?5 mol·L?1. BSA within the range of 0.01-2.6 μg·mL?1 and HSA of 0.01-1.7 μg·mL?1 can be detected with this method and the detection limits were 2.3 and 11.2 ng·mL?1, respectively. The method was successfully applied to the quantitative detection of total protein content in human serum samples with the maximum relative standard deviation (RSD) lower than 2.6% and the recoveries over the range of 99.5-100.5%.

Kinetics of Removing Nitrogenous and Phosphorus Compounds from Swine Waste by Growth of Microalga, Spirulina platensis

  • Kim, Min-Hoe;Chung, Woo-Taek;Lee, Mi-Kyung;Lee, Jun-Yeup;Ohh, Sang-Jip;Lee, Jin-Ha;Park, Don-Hee;Kim, Dong-Jin;Lee, Hyeon-Yong
    • Journal of Microbiology and Biotechnology
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    • 제10권4호
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    • pp.455-461
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    • 2000
  • Abstract Spirulina platensis was grown in SWlUe waste to reduce inorganic compowlds and simultaneously produce feed resources. Spirulina platensis prefers nitrogenous compounds in Ibe order: $NH_4^{+}-N>NO_3^{-}-N>simple-N$ such as urea and simple amino acids. It even consumes $NH_4^{+}-N$ first when urea or nitrate are present. Therefore, the content of residual $NH_4^{+}-N$ in Spimlina platensis cultures can be determined by the relative extent of the following processes: (i) algal uptake and assimilation; (ii) ammonia stripping; and (iii) decomposition of urea to NH;-N by urease-positive bacteria. The removal rates of total nitrogen ffild total phosphorus were estimated as an indicator of the treatment effIciency. It was found that Spirulina platensis was able to reduce 70-93% of $P_4^{3-}-P$, 67-93% of inorganic nitrogen, 80-90% of COD, and 37-56% of organic nitrogen in various concentrations of swine waste over 12 days of batch cultivation. The removal of inorganic compounds from swine waste was mainly used for cell growth, however, the organic nitrogen removal was not related to cell growlb. A maximum cell density of 1.52 dry-g/l was maintained with a dilution rate of 0.2l/day in continuous cultivation by adding 30% swine waste. The nitrogen and phosphorus removal rates were correlated to the dilution rates. Based on the amino acid profile, the quality of the proteins in the Spirulina platensis grown in the waste was the same as that in a clean culture.ulture.

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Static impedance functions for monopiles supporting offshore wind turbines in nonhomogeneous soils-emphasis on soil/monopile interface characteristics

  • Abed, Younes;Bouzid, Djillali Amar;Bhattacharya, Subhamoy;Aissa, Mohammed H.
    • Earthquakes and Structures
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    • 제10권5호
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    • pp.1143-1179
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    • 2016
  • Offshore wind turbines are considered as a fundamental part to develop substantial, alternative energy sources. In this highly flexible structures, monopiles are usually used as support foundations. Since the monopiles are large diameter (3.5 to 7 m) deep foundations, they result in extremely stiff short monopiles where the slenderness (length to diameter) may range between 5 and 10. Consequently, their elastic deformation patterns under lateral loading differ from those of small diameter monopiles usually employed for supporting structures in offshore oil and gas industry. For this reason, design recommendations (API and DNV) are not appropriate for designing foundations for offshore wind turbine structures as they have been established on the basis of full-scale load tests on long, slender and flexible piles. Furthermore, as these facilities are very sensitive to rotations and dynamic changes in the soil-pile system, the accurate prediction of monopile head displacement and rotation constitutes a design criterion of paramount importance. In this paper, the Fourier Series Aided Finite Element Method (FSAFEM) is employed for the determination of static impedance functions of monopiles for OWT subjected to horizontal force and/or to an overturning moment, where a non-homogeneous soil profile has been considered. On the basis of an extensive parametric study, and in order to address the problem of head stiffness of short monopiles, approximate analytical formulae are obtained for lateral stiffness $K_L$, rotational stiffness $K_R$ and cross coupling stiffness $K_{LR}$ for both rough and smooth interfaces. Theses expressions which depend only on the values of the monopile slenderness $L/D_p$ rather than the relative soil/monopile rigidity $E_p/E_s$ usually found in the offshore platforms designing codes (DNV code for example) have been incorporated in the expressions of the OWT natural frequency of four wind farm sites. Excellent agreement has been found between the computed and the measured natural frequencies.

폐경 여성의 비타민 D 섭취량, 옥외활동시간, 혈청 25-OH 비타민 D 수준과 계절 및 연령과의 관련성 (Vitamin D intake, Outdoor Activity Time and Serum 25-OH Vitamin D Concentrations of Korean Postmenopausal Women by Season and by Age)

  • 윤진숙;송민경
    • 대한지역사회영양학회지
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    • 제20권2호
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    • pp.120-128
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    • 2015
  • Objectives: The purpose of this study was to examine the relative impact of seasonal differences and age on dietary vitamin D intakes, outdoor activity time and serum vitamin D status among Korean postmenopausal women. Methods: A cross-sectional study was conducted with 164 free-living postmenopausal women (mean age=55.4 years) in Daegu, Korea. Dietary intake, daily physical activity patterns and fasting blood samples were collected during summer and winter. We compared the results from 75 women during summer and 89 women during winter. Dietary intake of vitamin D was assessed by 24-hour recall method. Daily outdoor activity time was derived from physical activity diary. Results: The average dietary intake of vitamin D of the participants was $3.7{\mu}g$ during summer, $3.3{\mu}g$ during winter, showing no significant difference between the two seasons. The average time spent on outdoor activities was not significantly different between summer ($=35.1{\pm}75.0min/d$) and winter ($=48.5{\pm}76.8min/d$). The average serum 25-(OH) vitamin D concentrations of participants was $17.5{\pm}7.5ng/mL$ in the summer and $13.4{\pm}4.3ng/mL$ in the winter, showing no significant differences by season. Dietary intake of vitamin D was not related to age. When total subjects were divided into two groups by age, the average serum 25-(OH) vitamin D concentration was significantly higher in older group (p=0.047) and time spent on outdoor activities was also (p=0.018) significantly higher in the older group. Conclusions: In order to improve the current vitamin D status of Korean postmenopausal women, nutrition education programs should focus more on adequate intake of vitamin D, while maintaining enough outdoor activities over the season.