• Nuclear Engineering and Technology
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• 제17권1호
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• pp.45-52
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• 1985

가압 경수로의 소형 냉각재 사고시 증기 발생기 U-자관 내에서의 억류 응축 현상(reflux condensation phenomena)은 주요한 열제거 수단이 된다. 열제거 Mechanism이 순수히 역류 응축 현상에 의 할 때, 증기 발생기의 열제거 능력을 평가하기 위하여 원자로 증기 발생기의 U-자관을 모사하는 두개의 U-자 관을 가진 증기응축 장치를 제작하여 다음 두 가지의 실험을 수행하였다. 첫째로, U-자관속에서 역류 응축 현상이 일어날 때 증기의 유입량을 증가시켜 가면서 역류 응축이 일어나는 액체 막 길이 (filmwise reflux condensation length)를 측정하였다. 둘째로는 길이가 다른 두 개의 U-자관에 증기만을 유입시킬 때와 증기와 공기를 동시에 유입시킬 때에 대한 Flooding Point를 측정하여 U-자관의 길이와 비응축성 가스가 Flooding Point에 미치는 영향을 조사하였다. 그리고 수학적 모델을 이용한 이론적 측정값과 실험 Data를 비교하였다.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1995년도 추계학술발표회논문집(1)
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• pp.383-388
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• 1995

Two-phase transient phenomena in the noncondensable gas-filled closed loop was investigated numerically using the RELAP5/MOD3 version 3.1 computer code. The condensation heat transfer correlation for noncondensable gases was studied in detail. Two modes of the reflux condensation which can be characterized by countercurrent flow of steam and its condensed water and the oscillatory between reflux condensation and natural circulation were predicted well. However, the natural circulation mode which the condensed water carried over the U-bend concurrently with steam was failed to predict.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1999년도 춘계학술발표회요약집
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• pp.109-109
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• 1999

The standard RELAP5/MOD3.2 code was modified using the non-iterative modeling. which is developed to simulate steam condensation in the presence of noncondensable gases ill a vertical tube. The modified RELAP5/MOD3.2 code was used to simulate two kinds of vertical in-tube experiments involving the condensation phenomenon in the presence of noncondensable gases. The modeling capabilities of the modified RELAP5/MOD3.2 codc as well as the standard code for the condensation in the presence of noncondensable gases are assessed using two PCCS condensation experiments and four reflux condensation experimcnts. The modified RELAP5/MOD3.2 code gives good prediction over the data of both PCCS condensation and reflux condensation experiments

• Nuclear Engineering and Technology
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• 제31권5호
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• pp.486-497
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• 1999

The local heat transfer coefficient is experimentally investigated for the reflux condensation in a countercurrent flow between the steam-air mixture and the condensate, A single vertical tube has a geometry which is a length of 2.4m, inner diameter of 16.56mm and outer diameter of 19.05mm and is made of stainless steel. Air is used as a noncondensible gas. The secondary side has a shape of annulus around vertical tube and the lost heat by primary condensation is transferred to the coolant water. The local temperatures are measured at 11 locations in the vertical direction and each location has 3 measurement points in the radial direction, which are installed at the tube center, at the outer wall and at the coolant side. In three different pressures, the 27 sets of data are obtained in the range of inlet steam flow rate 1.348∼3.282kg/hr, of inlet air mass fraction 11.8∼55.0%. The investigation of the flooding is preceded to find the upper limit of the reflux condensation. Onset of flooding is lower than that of Wallis' correlation. The local heat transfer coefficient increases as the increase of inlet steam flow rate and decreases as the increase of inlet air mass fraction. As an increase of the system pressure, the active condensing region is contracted and the heat transfer capability in this region is magnified. The empirical correlation is developed by 165 data of the local heat transfer. As a result, the Jacob number and film Reynolds number are dominant parameters to govern the local heat transfer coefficient. The rms error is 17.7% between the results by the experiment and by the correlation.

• Nuclear Engineering and Technology
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• 제30권5호
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• pp.424-434
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• 1998

RELAP5/Mod3.1 code was assessed with the semiscale experiment S-NC-3, and S-NC-4, which simulated the two-phase natural circulation and reflux condensation for the SBLOCA of PWR, respectively . Test S-NC-3 and S-NC-4 calculation results showed that RELAP5/Mod3.1 quite well describes the influence of steam generator secondary side heat transfer degradation on both two-phase natural circulation and reflux condensation. A comparison between the calculated and measured two-phase mass flow rate in test S-NC-3 shows good agreement for primary mass inventory more than 92%. And RELAP5/Mod3.1 have a good mass flow rate prediction capability for the transient such as S-NC-4 except some flow oscillations. The reflux flow rate for S-NC-4 test is under predicted, and the overall results verify that the correct prediction of the reduced liquid level appears to be required for the correct calculation of the overall phenomena.

• Nuclear Engineering and Technology
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• 제33권6호
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• pp.638-651
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• 2001

The present study is to assess the applicability of the best-estimate thermal-hydraulic code, MARS 1.4, for the analysis of thermal-hydraulic behavior in PWRs during natural circulation conditions. The code simulates a natural circulation test, BETHSY test 4. la, which was conducted on the integral test facility of BETHSY. The test represented the cooling states of the primary cooling system under single-phase natural circulation, two-phase natural circulation and the reflux condensation mode with conditions corresponding to the residual power, 2% of the rated core power value and 6.8 MPa at the secondary system. Based on MARS 1.4 calculations, the major thermal-hydraulic behaviors during natural circulation are evaluated and the differences between the experimental data and calculated results are identified. The calculated results show generally good behavior with regard to the experimental results; the region of single-phase natural circulation is 100-92% of the initial mass inventory, two-phase natural circulation is 84-63 %, and the reflux condensation mode occurred below 58 %. U-tubes empty and the core uncovery are obtained at 39 % and 34 % of the initial mass inventory, respectively.

• 약학회지
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• 제26권2호
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• pp.111-116
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• 1982

The behavior of the 5-phenylhydantoin (5-phenyl-2, 4-imidazolidinedione) ring in the aminomethylation reaction was studied in order to determine the orientation of this substitution. In case of monoaminomethylation, 3-morpholinomethyl-5-phenylhydantoin (or 3-piperidinomethyl-5- phenylhydantoin) was synthesized by the condensation of 5-phenylhydantoin with one mole of morpholine (or piperidine) and one mole of formaldehyde. 1, 3-Dimorpholinomethyl- 5-phenylhydantoin was obtained in the attempted condensation of 5-phenylhydantoin with two moles of morpholine and two moles of formaldehyde. Despite the close resemblance to morpholine the attempted condensation of 5-phenylhydantoin with piperidine and formaldehyde under reflux gave no expected 1, 3-dipiperidinomethyl -5-phenylhydantoin. In case of diaminomethylation using piperidine and formaldehyde, only 3, 5-dipiperidinomethyl-5-phenylhydantoin was formed.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2001년도 춘계학술발표회요약집
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• pp.177-177
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• 2001

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1999년도 춘계학술발표회요약집
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• pp.108-108
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• 1999

• Bulletin of the Korean Chemical Society
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• 제31권5호
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• pp.1301-1304
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• 2010

The Indium modified mesoporous zeolite AlMCM-41 were synthesized by hydrothermal method and characterized by powder X-ray diffraction (XRD), fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) techniques. The Knoevenagel condensation of aldehyde with malononitrile or ethyl cyanoacetate was carried out at reflux condition in ethanol by using heterogeneous In/AlMCM-41 catalyst. This method is fast, efficient, easy work-up and eco-friendly to afford the corresponding Knoevenagel adducts. The catalyst was recovered and reused for several cycles with consistent activity.