• Title/Summary/Keyword: reflection energy

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Atomic layer deposited $Al_2O_3$ for the surface passivation of crystalline silicon solar cells ($Al_2O_3$ 부동화 막의 태양전지 응용)

  • Kim, Sun Hee;Shin, Jeong Hyun;Lee, Jun Hyeok;Lee, Hong Jae;Kim, Bum Sung;Lee, Don Hee
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.73.1-73.1
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    • 2010
  • 태양광 시장은 세계적인 금융 위기 속에서도 점점 그 규모가 확대되고 있다. 시장의 규모가 확대되고 있음에도 불구하고 금융 위기를 겪으면서 생산자 중심의 시장에서 수요자 중심의 시장으로 바뀌게 되었다. 이에 따라 더 적은 비용으로 높은 출력의 제품만이 경쟁력을 가지게 됨으로써 효율이 더욱 이슈화되었다. 여러 태양전지 중 가장 점유율이 높은 결정질 태양전지는 일반적인 양산 공정만으로 효율을 높이는데 한계가 있으므로 selective emitter, back contact, light induced plating 등의 새로운 공정을 도입하여 효율을 높이려는 경향이 나타나고 있다. 본 연구에서는, ALD 장치를 사용하여 결정질 태양전지의 후면을 passivation 함으로써 효율을 높이는 방법을 모색하였다. 부동화 층으로는 $Al_2O_3$를 사용하였으며 셀을 제조하여 평가하였다. 실험방법은 p-type의 웨이퍼를 이용하여 습식으로 texturing 후 $POCl_3$ 용액으로 p-n junction을 형성하였고 anti-reflection 막인 SiNx는 PECVD를 사용하여 R.I 2.05, 80nm 두께로 증착하였다. 그런 다음 후면의 n+ layer를 제거하기 위하여 SiNx에 영향을 미치지 않는 용액을 사용하여 후면을 식각하였다. BSF 층은 screen printer로 Al paste를 printing하여 형성하였고 Al etching용액으로 여분의 Al제거한 후 ALD 장치를 이용하여 $Al_2O_3$를 증착하였다. 마지막으로 전극을 형성한 후 laser로 isolation하여 효율을 평가하였다.

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Study on SiNx double layer anti-reflection coating for crystalline solar cell application (결정질 태양전지 적용을 위한 SiNx 이중구조 반사방지막에 관한 연구)

  • Gong, Daeyeong;Park, Seungman;Yi, Junsin
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.93.1-93.1
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    • 2010
  • 반사방지막은 태양전지 표면에서의 광 반사를 낮춰주며, Si wafer 표면에서의 carrier의 재결합을 줄이는 passivation 역할을 한다. 이를 위한 다양한 물질이 반사방지막으로 사용된다. 단일박막은 passivation 효과가 미미하여 최근 passivation 향상에 도움이 되는 이중구조 반사방지막이 널리 연구되어지고 있다. 하지만 물질이 다양해짐에 따라 공정시간 및 비용이 늘어나고, passivation에 최적화된 물질사용이 필수적으로 요구되는 단점이 있다. 따라서 본 연구에서는 기존에 passivation 효과가 뛰어나다고 알려진 SiNx의 굴절률 가변을 통하여 이중구조를 갖는 박막을 반사방지막으로 이용하여 그 특성을 비교, 분석하였다. SiNx 이중반사방지막은 0.8 Torr~1 Torr의 압력에서 $450^{\circ}C$의 기판온도로 PECVD를 이용하여 증착되었으며 이때의 plasma power는 180mW/$cm^2$으로 고정 하였다. 굴절률 1.9 및 2.3을 갖는 가스 조성비를 이용하여 각 layer의 두께를 20/60nm, 30/50nm, 40/40nm로 가변하였다. 샘플 제작 후 Sun-Voc 측정을 통하여 implied Voc 및 효율을 측정하였다. 단일반사방지막을 사용한 샘플의 경우 608mV의 implied Voc가 측정되었으며, FF는 82.8%, 효율은 17.6%로 측정되었다. 가장 우수한 특성을 나타낸 20/60nm의 두께로 증착된 샘플의 경우 implied Voc는 625mV, FF는 84.1%, 효율은 18.3%로 우수한 결과를 나타내었다. 반사도 측정 결과 단일반사방지막은 2.27%로 높았으나 SiNx 이중구조를 이용한 반사방지막은 1.67%로 낮은 값을 확인 하여 이중구조의 반사방지막이 반사도 저감 및 passivation 효과 향상에 도움이 되는 것을 확인할 수 있었다.

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The Effect of Annealing Temperature and Zn contents on Transparent Conducting Indium Zinc Tin Oxide Thin Films

  • Lee, Seon-Yeong;Denny, Yus Rama;Park, Su-Jeong;Gang, Hui-Jae;Heo, Seong;Jeong, Jae-Gwan;Lee, Jae-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.227-227
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    • 2012
  • 본 연구에서는 RF스퍼터링법에 의하여 glass substrate에 In-Zn-Sn-O (IZTO)를 Zn 성분에 변화를 주면서 $350{\AA}$ 만큼 증착시키고, 1시간 동안 $350^{\circ}C$로 열처리 하였다. In:Zn:Sn의 성분 비율은 20:48:32 (IZTO1), 13:60:27 (IZTO2)이다. 박막의 전자적, 광학적 특성은 XPS (X-ray Photoelectron Spectroscopy), REELS(Reflection Electron Energy Loss Spectroscopy), UV-Spectrometer를 이용하여 연구하였고, 박막의 전기적 특성은 van der Pauw 법을 이용하여 측정하였다. XPS측정결과, IZTO박막은 In-O, Sn-O and Zn-O의 결합을 가진다. REELS를 이용해 Ep=1,500 eV에서의 밴드갭을 얻어보면, $350^{\circ}C$로 열처리 한 박막은 열처리를 하지 않은 것에 비해 밴드갭이 IZTO1는 3.36 eV에서 3.54 eV로, IZTO2는 3.15 eV에서 3.31 eV로 증가하였다. 반면에 Zn 함량이 증가할수록 밴드갭이 감소하는 것을 확인할 수 있었다. 이 값은 UV-Spectrometer를 이용한 광학적 밴드갭과 일치하였다. 또한 van der Pauw method를 이용한 전기적 특성 분석 결과, 열처리를 하기 전에 비하여 carrier concentration이 IZTO1는 $-4.4822{\times}10^{18}cm^{-3}$에서 $-2.714{\times}10^{19}cm^{-3}$로, IZTO2는 $-3.6931{\times}10^{17}cm^{-3}$에서 $-1.7679{\times}10^{19}cm^{-3}$로 증가하였다. 반면에 Resistivity는 IZTO1의 경우 $1.7122{\times}10^{-1}{\Omega}{\cdot}cm$에서 $5.5496{\times}10^{-3}{\Omega}{\cdot}cm$로, IZTO2는 $1.3290 {\Omega}{\cdot}cm$에서 $1.3395{\times}10^{-2}{\Omega}{\cdot}cm$로 감소하였다. 그리고 UV-Spectrometer를 이용한 광학적 특성을 측정해본 결과, 가시광선영역인 380~780 nm에서의 투과율이 83%이상으로 투명전자소자로의 응용이 가능하다는 것을 보여주었다.

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A study of internal reflectance enhancement for crystalline silicon solar cell adopted with Bragg mirror structure using TCAD simulation

  • Jeong, Sujeong;Kim, Soo Min;Lee, Kyung Dong;Kim, Jae eun;Park, Hyomin;Kang, Yoonmook;Lee, Hae-seok;Kim, Donghwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.421.2-421.2
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    • 2016
  • 고효율 태양전지에서 후면 반사 방지막은 장파장대(900nm~1200nm) 빛의 내부 반사를 증가시켜 광흡수도를 개선한다. 태양전지 후면에 박형 절연층 구조를 구성함으로써 특정 파장에서 높은 반사도를 얻을 수 있는 Bragg mirror 구조를 이론적으로 계산할 수 있다. Bragg mirror 구조를 이용하여 태양전지의 후면 반사층(Rear reflector layer)을 형성함으로써 태양전지 내부의 광흡수도를 개선할 수 있다. 후면 반사 방지막(Rear anti-reflection coating)으로 사용되는 Al2O3와 SiOxNy 또는 이러한 두 가지 물질의 겹층 구조를 구성하여 장파장대 빛의 반사도 차이에 의한 광흡수도 개선 정도를 광학 시뮬레이션을 통해 계산하였다. 광학 시뮬레이션은 TCAD를 이용하였으며 두 가지 겹층 구조에서 각 반사 방지막의 두께에 따른 단락 전류(Jsc)의 개선 정도, 후면 반사층 두께의 최적화 조건을 계산하였다. 후면 반사방지막을 제외한 기본적인 태양전지 구조는 n-type PERC 구조를 사용하였으며, 후면 반사방지막만의 광학적 특성을 살펴보기 위해 전극은 광학적으로 투명하다고 가정하였다. 반사방지막 두께의 범위는 Al2O3(5-30nm), SiNx(150-300nm), SiOxNy(150-300nm)에서 수행하였으며, 각각 1nm, 2nm 간격으로 진행하였다. Al2O3/SiOxNy 구조에서는 단락 전류가 32.45-32.87mA/cm2 값을 가진다. Al2O3/SiNx 구조에서는 단락 전류가 32.59-32.87mA/cm2 값을 가진다. 결론적으로, 후면 반사방지막의 겹층 구조를 통해 광흡수도를 증가 시킬 수 있으며, TCAD 시뮬레이션을 통하여 입사되는 태양광 스펙트럼에 최적화된 구조를 설계할 수 있다.

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Provenance and Concept of 10 Symptoms of Para-cold Damage(類傷寒) from Yixuerumen(醫學入門) (『의학입문(醫學入門)·상한편(傷寒篇)』 유상한(類傷寒) 병증(病症) 10종의 유래와 개념에 대한 연구)

  • Jo, Hak-jun
    • Journal of Korean Medical classics
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    • v.29 no.4
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    • pp.17-36
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    • 2016
  • Objectives : This paper seeks to study the provenances of 10 Symptoms of Para-cold damage from Yixuerumen, and discovers the rationality and originality of para-cold damages recognized by Li Chan. Methods : The paper looks through the books referenced by Yixuerumen to investigate the source text for Yixuerumen's Para-cold Damage chapter, and the contents of the referenced books will be compared to that of Yixuerumen. Results : The sources of the 10 symptoms of para-cold damage from Yixuerumen Chapter of Cold Damage can be traced to Leizhenghuorenshu (expectoration, indigestion, rising temperature due to lack of energy, and beriberi), Wang Zhen's Shanghanzhengzhimingtiao Xinzengxuleishanghansizheng(the infection in a boil, blood sattis, caused overexertion, and pox), and Liu Chun's Yujiweiyi's chapter on Common Cold. Here, Li Chan made his own addition of internal damage and damage of overworking. Li Chan seems to have considered para-cold damage not as a type of cold damage but as a "concept relative to the broader range of cold damage." In reflection of this understanding, Li Chan limited the number of categories to ten in accordance with the developmental trace leading from Leizhenghuorenshu to Shanghanzhengzhimingtiao. When we understand para-cold damage as a "concept relative to the narrower range of cold damage," it could be used as a mean as for "Wenbin diagnosis," but Yixuerumen's para-cold damage is only utilized for the "diagnosis of a broader concept of cold damage." Conclusions : Li Chan deserves credits for his academic rationality and originality displayed by the method he used to form para-cold damages where he used real cold damage and para-cold damage as principles, by the division of para-cold damage symptoms into ten provenances, by the creation of the concept of para-cold damage, and by his broad collection of prescription and treatment corresponding to each type.

A Study on the healing factors of Forest Sound

  • Yi, Eun-Young;Bae, Myung-Jin
    • International Journal of Internet, Broadcasting and Communication
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    • v.9 no.2
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    • pp.70-77
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    • 2017
  • Where there are all the flowers, the songs of all kinds of insects and birds are put in, the sunshine and shadows flicker The forest through which the water sound flows is an optimum resting space. All living creatures in these spaces will awaken the five senses of humans and perhaps turn the sensibility index (EQ). The forest meditation in the forest, which can be an optimal shelter for the people who need it, needs to feel the reverence of nature, to refine emotions, to be a self-reflection, to have a mind to respect, Have an important meaning. In this paper, we tried to consider the cause of the influence of forest sounds on human hearing from the acoustical aspect. The type of sound source of forest was divided into four seasons of spring, summer, autumn, winter. And the change in the duration of the sound during the four seasons, so that the general characteristics of the sounds of the four seasons are as follows: It can be seen that the change in the ratio of sub-band energy is almost equal to the change in dB in frequency of the equal-light curve. To compare this phenomenon, the criterion for changing the sound duration of each forest is natural The main forms of the luminance curve, such as the change in the duration of the white signal in the sound, are determined by the minimum, maximum audible frequency and the most sensitive frequency band, and the auditory characteristics of the other three inflection points Determines the overall shape of the equal-light curve.

Effect of oxygen deficiency on electronic properties and local structure of amorphous tantalum oxide thin films

  • Denny, Yus Rama;Firmansyah, Teguh;Park, Chanae;Kang, Hee Jae;Yang, Dong-Seok;Heo, Sung;Chung, Jae Gwan;Lee, Jae Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.122.1-122.1
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    • 2015
  • The dependence of electronic properties and local structure of tantalum oxide thin film on oxygen deficiency have been investigated by means of X-ray photoelectron spectroscopy (XPS), Reflection Electron Energy Loss Spectroscopy (REELS), and X-ray absorption spectroscopy (XAS). The XPS results showed that the oxygen flow rate change results in the appearance of features in the Ta 4f at the binding energies of 23.2 eV, 24.4 eV, 25.8, and 27.3 eV whose peaks are attributed to Ta1+, Ta2+, Ta3+, Ta4+, and Ta5+, respectively. The presence of nonstoichiometric state from tantalum oxide (TaOx) thin films could be generated by the oxygen vacancies. The REELS spectra suggested the decrease of band gap for tantalum oxide thin films with increasing oxygen deficiency. In addition, XAS spectra manifested both the increase of coordination number of the first Ta-O shell and a considerable reduction of the Ta-O bond distance with the decrease of oxygen deficiency.

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fiber Orientation Effects on the Acoustic Emission Characteristics of Class fiber-Reinforced Composite Materials (유리섬유강화 복합재의 AR특성에 대한 섬유배향 효과)

  • Kim, Jung-Hyun;Woo, Sung-Choong;Choi, Nak-Sam
    • Journal of the Korean Society for Nondestructive Testing
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    • v.23 no.5
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    • pp.429-438
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    • 2003
  • The effects of fiber orientation on acoustic emission(AE) characteristics have been studied for the unidirectional and satin-weave, continuous glass-fiber reinforced plastic(UD-GFRP and SW-GFRP) tensile specimens. Reflection and transmission optical microscopy was used for investigation of the damage zone of specimens. AE signals were classified as different types by using short time fourier transform(STFT) : AE signals with high intensity and high frequency band were due to fiber fracture, while weak AE signals with low frequency band were due to matrix and interfacial cracking. The feature in the rate of hit-events having high amplitudes showed a process of fiber breakages, which expressed the characteristic fracture processes of individual fiber-reinforced plastics with different fiber orientations and with different notching directions. As a consequence, the fracture behavior of the continuous GFRP could be monitored as nondestructive evaluation(NDE) through the AE technique.

Seismic Pre-processing and AVO analysis for understanding the gas-hydrate structure (가스 하이드레이트 부존층의 구조 파악을 위한 탄성파 전산처리 및 AVO 분석)

  • Chung Bu-Heung
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.634-637
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    • 2005
  • Multichannel seismic data acquired in Ulleung Basin of East Sea for gas hydrate exploration. The seismic sections of this area show strong BSR(bottom simulating reflections) associated with methane hydrate occurrence in deep marine sediments. Very limited information is available from deep sea drilling as the risk of heating and destabilizing the initial hydrate conditions during the processing of drilling is considerably high. Not so many advanced status of gas hydrate exploration in Korea, the most of information of gas hydrate characteristics and properties are inferred from seismic reflection data. In this study, The AVO analysis using the long offset seismic data acquired in Ulleung Basin used to explain the characteristics and structure of gas hydrate. It is used primarily P-wave velocity accessible from seismic data. To make a good quality of AVO analysis input data, seismic preprocessing including 'true gain correction', 'source signature deconvolution', twice velocity analysis and some kinds of multiple rejection and enhancing the signal to noise ratio processes is carried out very carefully. The results of AVO analysis, the eight kinds of AVO attributes are estimated basically and some others of AVO attributes are evaluated for interpretation of AVO analysis additionally. The impedance variation at the boundary of gas hydrate and free gas is estimated for investing the BSR characteristics and properties. The complex analysis is performed also to verifying the amplitude variation and phase shift occurrence at BSR. Type III AVO anomaly appearance at saturated free gas area is detected on BSR. It can be an important evidence of gas hydrate deposition upper the BSR.

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Elastic Modulus of Magnetic Fluids Evaluated by Ultrasonic Test (초음파 시험에 의한 자기유체의 탄성율 산정)

  • Kim, Jong-Hee;Kim, Kun-Woo;Kim, Cheol-Gi;Lee, Seung-Goo;Koo, Man-Hoi
    • Korean Journal of Materials Research
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    • v.22 no.3
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    • pp.136-139
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    • 2012
  • Magnetic nanoparticles for ferromagnetic fluids and magnetorheological fluids were prepared by chemical coprecipitation and mechanical milling, respectively. The surface-treated particles were dispersed at various weight ratios into a medium of polyethylene glycol. In order to evaluate the elastic modulus of the fluids, ultrasonic pulse velocities were measured with an ultrasonic test using transducers of 5MHz and 2.25MHz. The ultrasonic signals were only available with a transducer of 2.25 MHz at fluid concentrations of 5 mg/ml and lower. In the case of applying transducers over 2.25 MHz and concentrations over 5 mg/ml to the fluids, it was impossible to observe effective ultrasonic signals due to an excessive scattering of the pulses by the dispersed particles. Elastic moduli of the magnetorheological fluids were 5.44 GPa and 6.13 GPa with concentrations of 25 mg/ml and 50 mg/ml, respectively; these values were higher by 40% than the values of 4.04 GPa and 4.28 GPa of ferromagnetic fluids at the same concentrations. As for the effect of an external magnetic field on these dilute fluids, the ultrasonic signals were positioned in a very similar way, which was probably due to insufficient arrangement of the particles even though the reflection energy of the ultrasonic waves apparently increased.