• 제목/요약/키워드: reference electrode

검색결과 282건 처리시간 0.043초

심타접지와 천타병렬접지에 관한 이론적해석 (Theoretical Analysis of Earth Deep-Driven Rod and Earth Slight-Driven Parallel Rods in the Earth)

  • 김주찬;최종규;이충식;고희석
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2004년도 춘계학술대회 논문집
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    • pp.358-360
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    • 2004
  • To reduce the earth resistance, earth electrode are installed horizontally or vertically in the earth. There are two kinds of vertical earth electrode methods, one is a deep-driven rod and another is slight-driven parallel rods. Bibliography have so far analyzed the earth resistance calcalation of a rod type electrode and parallel rods type for the multi-layered earth. Befor long, We are going to study earth resistance of deep-driven rod and slight-driven parallel rods in the multi-layered earth with reference to bibliography.

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포도당 산화효소를 고정화한 Polypyrrole 효소전극의 배위자 변화에 따른 전기화학적 특성 (Electrochemical Properties of Polypyrrole Enzyme Electrode Immobilized Glucose Oxidase with Different Ligand)

  • 김현철;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.529-532
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    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-75, the redox potential was about -0.3 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-TS Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a tent of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

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Nanotube Morphology Change of Ti-Ta-Zr Alloy as Zr Content

  • Kim, Won-Gi;Choe, Han-Cheol;Ko, Yeong-Mu
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2008년도 추계학술대회 초록집
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    • pp.105-106
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    • 2008
  • Nanotube morphology change of Ti-Ta-Zr alloy as Zr content increase has been researched using various experimental methods. Ti-Ta-Zr(3, 7 and 15 wt%) alloys were prepared by arc melting and nano-structure controlled for 24 hr at $1000^{\circ}C$ in argon atmosphere. Formation of oxide nanotubes are conducted by anodizing a Ti-Ta-Zr alloy in $H_3PO_4$ electrolytes with small amounts of fluoride ions at room temperature. Electrochemical experiments were carried out with conventional three-electrode configuration with a platinum counter electrode and a saturated calomel reference electrode. The samples were embedded with epoxy resin, leaving a square surface area of $10mm^2$ exposed to the anodizing electrolyte, 1.0M $H_3PO_4$ containing 0.8wt% NaF.

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GIS내 금속이물 존재시 절연특성 (The Insulation Characteristics by Conducting Particle in GIS)

  • 조국희;김재철;곽희로
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 춘계학술대회 논문집 전기설비전문위원
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    • pp.105-108
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    • 2004
  • This paper describes the influence of conducting particle in the coaxial cylindrical electrodes under alternating voltage condition investigated using breakdown electric field and electro magnetics simulation method. Simulated particle-location in GIS chamber were the particle on electrode, the particle on enclosure and free moving particle. As results, it was founded that in case of breakdown electric field of the GIS chamber, breakdown electric field of particle on electrode was the lowest, that of free moving particle was middle and that of particle on enclosure was the highest. And in case of the electric field analysis with particle locations, electric field of particle on electrode was the highest that of lifted particle was middle and that of particle on enclosure was the lowest. This results can offer a practical reference ra the insulation design of domestic GIS.

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Diagnostic ex vivo assay of glucose in live cell using voltammetry

  • Ly, Suw Young;Leea, Chang Hyun
    • 한국응용과학기술학회지
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    • 제35권4호
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    • pp.1379-1385
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    • 2018
  • The hand held voltammetry systems searched diabetic assay using glucose sensor of fluorine nafion doped carbon nanotube electrode (FCNE). An inexpensive graphite carbon pencil was used as an Ag/AgCl reference and Pt counter electrode. Upon combining and using three electrode systems, optimum square wave (SW) stripping results were attained to 1.0-9.0 ug/L with 8 points. Statistic RSD precision was of 6.02 % with n=15 in 0.1 mg/L glucose. After a total of 200 second accumulation times, analytical detection limit of 0.8 ug/L was obtained. This developed technique was applied to urine samples from diabetic patients urine for fluid analysis, it was determined that the sensor can be used with a diagnostics in the ex vivo of live cells and non treated biological fluid.

반응성 이온 식각법에 의해 제작된 탄소나노튜브 전극의 전기화학적 특성 (Electrochemical Properties of Individual Carbon Nanotube Fabricated by Reactive Ion Etching)

  • 황숙현;최현광;김상효;한영문;전민현
    • 한국재료학회지
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    • 제21권2호
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    • pp.89-94
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    • 2011
  • In this work, fabrication and electrochemical analysis of an individual multi-walled carbon nanotube (MWNT) electrode are carried out to confirm the applicability of electrochemical sensing. The reactive ion etching (RIE) process is performed to obtain sensitive MWNT electrodes. In order to characterize the electrochemical properties, an individual MWNT is cut by RIE under oxygen atmosphere into two segments with a small gap: one segment is applied to the working electrode and the other is used as a counter electrode. Electrical contacts are provided by nanolithography to the two MWNT electrodes. Dopamine is specially selected as an analytical molecule for electrochemical detection using the MWNT electrode. Using a quasi-Ag/AgCl reference electrode, which was fabricated by us, the nanoelectrodes are subjected to cyclic voltammetry inside a $2{\mu}L$ droplet of dopamine solution. In the experiment, RIE power is found to be a more effective parameter to cut an individual MWNT and to generate "broken" open state, which shows good electrochemical performance, at the end of the MWNT segments. It is found that the pico-molar level concentration of analytical molecules can be determined by an MWNT electrode. We believe that the MWNT electrode fabricated and treated by RIE has the potential for use in high-sensitivity electrochemical measurement and that the proposed scheme can contribute to device miniaturization.

국소의치용 티타늄 합금의 부식 특성 (Corrosion Characteristics of Ti alloy for Removable Partial Denture)

  • 김정재;김원기
    • 한국콘텐츠학회논문지
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    • 제14권4호
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    • pp.237-242
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    • 2014
  • 본 연구의 목적은 저탄성계수 Ti-30Ta 합금에 Zr 원소를 첨가하여 표면 특성 및 부식 거동을 조사하였다. 저탄성계수 Ti-30Ta-xZr(x : 3, 7, 15 wt %)합금은 아크 멜팅기로 제조하였고, 아르곤 분위기에서 $1000^{\circ}C$ 24시간 동안 열처리하였다. 합금의 미세구조는 FE-SEM 그리고 XRD를 이용하여 조사하였다. 전기화학적 특성은 시편 작업전극, 고밀도 탄소 보조전극 그리고 포화칼로멜 기준전극의 통상적인 3상을 이용하여 수행하였다. Ti-30Ta-xZr 합금의 분극 거동 결과, 균질화 처리된 Ti-30Ta-15Zr 합금의 부동태 전류밀도가 다른 합금에 비해 낮았다.

Poly-${\gamma}$ Benzyl $_D$-Glutamate 유기박막의 전자이동특성에 관한 연구 (A Study on the Electronic Properties of Poly-$\gamma$ Benzyl $_D$-Glutamate Organic Thin Films)

  • 송진원;이경섭;이봉주;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 센서 박막재료 반도체재료 기술교육
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    • pp.86-89
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    • 2002
  • We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 10[mN/m]. In processing of a device manufacture, we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/Poly-${\gamma}$ Benzyl $_D$-Glutamate/Al and Au/Poly-${\gamma}$ Benzyl $_D$-Glutamate/Au; the number of accumulated layers is 1, 3, 5 and 7. Also, we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from 0 to +2[V]. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system. LB film accumulated by monolayer on an ITO. In the cyclicvoltammetry, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in $LiBF_4$ solution, stable up to 0.9V vs. Ag/AgCl.

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브롬화 알킬화합물 LB막의 전기화학적 특성 (Electrochemical Properties of Langmuir-Blodgett(LB) Film of Alkyl Bromides)

  • 박근호;손태철;민창훈
    • 한국응용과학기술학회지
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    • 제26권4호
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    • pp.451-456
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    • 2009
  • We carried out this experiment to observe an electrochemical properties for LB films of alkyl compounds by the cyclic voltammetry. Alkyl bromides was deposited by using the Langmuir- Blodgett method on the ITO glass. We measured to an electrochemical measurement by using cyclic voltammetry with a three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) in 0.5, 1.0, 1.5 and 2.0 N $NaClO_4$ solution. A measuring range was reduced from initial potential to -1350 mV, continuously oxidized to 1650 mV. The scan rate were 100 mV/s. As a result, an electrochemical properties of the LB films of alkyl bromides appeared irreversible process caused by only the oxidation current from the cyclic voltammogram. The diffusivity(D) effect of LB films decreased with increasing of alkyl compounds amount.