• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2001.11a
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• pp.3-11
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• 2001

Fundamental studies at the CSIRO division of Wool technology and ICI on the diffusion of dyes into wool〔1,2〕have let to development of a new approach to wool dyeing. In this method, the cell membrane complex of wool is modified before dyeing by treatment under mildly alkaline conditions with a special chemicals. Wool pretreated with ethoxylated quaternary ammonium salt has an increased rate of dyebath exhaustion and dye penetration early in the dyeing cycle. This enables the treated material to be dyed below the boil for a similar time to the conventional cycle. This technique can be used on untreated and shrinkresist-treated wool and wool/nylon blends. In addition to good macro-levelness and excellent coverage of tippiness, the low temperature dyeing process give higher exhaustion levels of dyestuffs and insect-resist agent and hence cleaner effluent liquors, compared with conventional dyeing process. Low Temperature Dyeing process cause significantly less fiber damage than conventional way. The reduction in damage is reflected in improved processing performance of the dyed wool.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09b
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• pp.1187-1188
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• 2006

This paper compares the effect of using different types of iron powders for the preparation of $Sm_2Fe_{17}$ by calciothermic reduction-diffusion (CRD). Three types of iron powder were used: carbonyl, sponge and water atomized. The results show that, when immediately nitrogenated after the CRD process, $Sm_2Fe_{17}$ prepared from sponge and water atomized iron powders yield $Sm_2Fe_{17}N_3$-magnets with a high degree of texture. However, after a suitable treatment with hydrogen followed by nitrogenation, $Sm_2Fe_{17}$-powders made from Carbonyl iron produce magnets with the best quality regarding coercivity, remanence and degree of texture.

• Transactions of Materials Processing
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• v.12 no.1
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• pp.60-65
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• 2003

HIP diffusion bonding of Ni-based superalloys, cast Mar-M247 (MM247) and Udimet 720 (U720) powder, was experimentally and numerically studied. Subsolvus HIP treatment was optimized by investigating the variations of high temperature tensile properties of HIP-bonded specimens with powder size, HIP'ing time, etc. While the tensile strength at high temperatures showed no detectable changes, the tensile elongation and reduction in area were slightly increased as the powder size decreased from -140 mesh to -270 mesh. While as-HIP'ed U720 showed a high tensile strength comparable to that of lorded U720 alloy, the HIP diffusion-bonded specimen showed a strength lower than the forged U720 alloy and the cast MM247 alloy The increase of HIP'ing tune from 2 hours to 3 hours resulted in a rapid risc of tensile strength and elongation due to the disappearence of microvoids in the cast MM247. FEM simulation for HIP process was conducted by applying the McMeeking micromechanical model, which uses power-law creep model as constitutive equations. ABAQUS user subroutine CREEP with an implemented microscopic model was used for the simulation. Numerical simulation was shown to be essential for the near-net shape manufacturing as well as the HIP process optimization.

• Korean Journal of Metals and Materials
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• v.48 no.4
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• pp.315-319
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• 2010

In this study, the hydrogen reduction behavior of ball-milled NiO nanopowder was investigated depending on the partial pressure of water vapor. The hydrogen reduction behavior was analyzed by thermogravimetry and hygrometry under heating to 873 K in hydrogen. In order to change the partial pressure of the water vapor, the dew point of hydrogen was controlled in the range of 248 K~293 K by passing high-purity hydrogen through a saturator that contained water. Interestingly, with the increase in the dew point of the hydrogen atmosphere, the first step of the hydrogen reduction process decreased and the second step gradually increased. After the first step, a pore volume analysis revealed that the pore size distribution in the condition with a higher water vapor pressure shifted to a larger size, whereas the opposite appearedat a lower pressure. Thus, it was found that the decrease in the pore volume during the chemical reaction controlled process at a dew point of 248 K caused a reduction in retardation in the diffusion controlled process.

• Analytical Science and Technology
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• v.8 no.2
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• pp.205-213
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• 1995

Counter-diffusion of coronene desorbed from alumina with addition of tetra-phenylporphine was studied by spectrophotometry. The counter-diffusion processes of adsorbing and desorbing materials in liquid phase were simulated by counter-diffusion model based on Fritz's binary component isotherm under an assumption of equimass diffusion. The counter-diffusivities of desorbed coronene with addition of tetra-phenylporphine were as ${\sim}10^{-15}m^2/sec$ and that of adsorbed tetra-phenylporphine as ${\sim}10^{-11}m^2/sec$. The counter-diffusivity of coronene determined from desorption process was smaller by ${\sim}10^5$ times than the diffusivity determined from adsorption process of a single species. The reduction of the determined counter-diffusivity of coronene in desorption process was explained by the cross of diffusion fluxes and build-up of high gradient of coronene in pore.

• Nuclear Engineering and Technology
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• v.42 no.2
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• pp.183-192
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• 2010

An electrochemical reduction of a mixture of metal oxides was conducted in a LiCl molten salt containing 3 wt% $Li_2O$ at $650^{\circ}C$. The oxide reduction was carried out by applying a current to an electrolysis cell, and the $Li_2O$ concentration was analyzed during each run. The concentration of $Li_2O$ in the electrolyte bulk phase gradually decreases according to Faraday's law due to a slow diffusion of the $O^{2-}$ ions. A hindrance effect of the unreduced metal oxides was observed for the reduction of the uranium oxide. Cs, Sr, and Ba of high heat-load fission products were diffused into and accumulated in the salt phase as predicted with thermodynamic consideration.

• Journal of the Korean Chemical Society
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• v.37 no.8
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• pp.730-734
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• 1993

The electrochemical reduction behavior or Biliverdin (BV) in N,N-dimethylformamide solvent was studied by DC polarography, cyclic voltammetry and the controlled potential coulometry. The reduced product was indentified by UV-Vis spectroscopy. In DC polarogram, two reduction waves of BV were founded. The half wave potentials of two reduction waves were -0.71 and -0.91 V vs. Ag/Ag$^+$ respectively. The current type of the 1st reduction wave was diffusion-controlled and the 2nd was diffusion current containing a little kinetic current. The 1st electrochemical reduction process was irreversible and BV reduced to Bilirubin.

• Journal of the Korean Geographical Society
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• v.28 no.2
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• pp.123-136
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• 1993

The growth of radidly improving computer and information technology has a profound impact upon economical, social and cultural sectors. With the progress of information technology, information-telecommunication services are produced. This service is used in sending the information to order service-users, and search the need information. This case study considers information-telecommunication service as a consumer-innovation. Information telecommunication services are provided by firms involved in collection. HiTEL(High-Telecommunication) service represents a subset of this group in that the collection, processing and transmission is primarily in an electronic from. The purpose of this paper is concerned with examining the spatial diffusion process, the issues, and behavior to used in HiTEL service one of the information-telecommunication services in Kwangju. HiTEL service is one of the typical information-telecommunication services, and is begun in Seoul and Kwangju area from October 1991, and diffusing several cities and regions now. Diffusion process of HiTEL services in Kwangju showed the irregular pattern in major residential areas, particularly Daewei-dong, Dongun-dong present higher adoption rate than other area, and where functioned as a diffusion center, the social and economic characteristics of residential area have a critical effect on diffusion process. The major adoption areas are recently built residential area, apartment districts, and diffusion direction shows two directions according to development of residental area; one is to south, another is from northeast to southwest. In order to understand the use-behavior of HiTEL service, questionary survey was carried out. Most adopters have a concern to actual life, as HiTEL, information of telephonenumber, and Daewoo Dial-Van compared with other information service. But the actual use-frequency of service is very low. In use of Kwangju regional information service, the use-frequency of operator is very low because of the lack of advertisement, the lack of providing information, and the low-concerns for regional information. But most of adopters need the providing of various regional information as regional news, education, medical and cultural events, housing, city-transportation, and job market. Thus, in order to increase and diffuse the HiTEL service, the establishment of diffusion strategies and the scheme for solution of related issues are very important. The direct diffusion strategies are the diffusion of information-mind, establishment of diffusion and education center, providing of regional information. The scheme for solution of related issues revealed in operating process are reduction of rental fee, development of the related technology and services.

• Journal of Powder Materials
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• v.20 no.5
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• pp.359-365
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• 2013

In this study, we fabricated $Nd_2Fe_{14}B$ hard magnetic powders with various sizes via spray drying combined with reduction-diffusion process. Spray drying is widely used to produce nearly spherical particles that are relatively homogeneous. Thus, the precursor particles were prepared by spray drying using the aqueous solution containing Nd salts, Fe salts and boric acid with the target stoichiometric composition of $Nd_2Fe_{14}B$. The mean particle sizes of the spray-dried powders are in the range from one to seven micrometer, which are adjusted by controlling the concentrations of precursor solutions. After debinding the as-prepared precursor particles, ball milling was also conducted to control the particle sizes of Nd-Fe-B oxide powders. The resulting particles with different sizes were subjected to subsequent treatments including hydrogen reduction, Ca reduction and washing for CaO removal. The size effect of Nd-Fe-B oxide particles on the formation of $Nd_2Fe_{14}B$ phase and magnetic properties was investigated.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.11 s.242
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• pp.1277-1284
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• 2005

The combustion characteristics of methane oxygen diffusion flames have been investigated to give basic information for designing industrial oxyfuel combustors. NOx reduction has become one of the most determining factors in the combustor design since the small amount of nitrogen is included from the current low cost oxygen production process. Flame lengths decreased with increasing fuel or oxygen velocity because of the enhancement of mixing effect. Correlation equation between flame length and turbulent kinetic energy was proposed. NOx concentration was reduced with increasing fuel or oxygen velocity because of the enhanced entrainment of the product gas into flame zone as well as the reduction of residence time in combustion zone.