• Title/Summary/Keyword: reduction atmosphere

검색결과 537건 처리시간 0.031초

분위기 가스에 따른 IZO 박막의 구조적 및 전기적 특성 (Structural and electrical characteristics of IZO thin films deposited under different ambient gases)

  • 이유림;이규만
    • 반도체디스플레이기술학회지
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    • 제9권3호
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    • pp.53-58
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    • 2010
  • In this study, we have investigated the effect of the ambient gases on the characteristics of IZO thin films for the OLED (organic light emitting diodes) devices. For this purpose, IZO thin films were deposited by RF magnetron sputtering under various ambient gases (Ar, $Ar+O_2$ and $Ar+H_2$) at $150^{\circ}C$. In order to investigate the influences of the oxygen and hydrogen, the flow rate of oxygen and hydrogen in argon mixing gas has been changed from 0.1sccm to 0.5sccm, respectively. All the samples show amorphous structure regardless of ambient gases. The electrical resistivity of IZO film increased with increasing flow rate of $O_2$ under $Ar+O_2$ while under $Ar+H_2$ atmosphere the electrical resistivity showed minimum value near 0.5sccm of $H_2$. All the films showed the average transmittance over 85% in the visible range. The OLED device was fabricated with different IZO substrates made by configuration of IZO/${\alpha}$-NPD/DPVB/$Alq_3$/LiF/Al to elucidate the performance of IZO substrate. OLED devices with the amorphous-IZO (a-IZO) anode film show better current densityvoltage-luminance characteristics than that of OLED devices with the commercial crystalline-ITO (c-ITO) anode film. It can be explained that very flat surface roughness and high work function of a-IZO anode film lead to more efficient hole injection by reduction of interface barrier height between anode and organic layers. This suggests that a-IZO film is a promising anode materials substituting conventional c-ITO anode in OLED devices.

산림을 이용한 탄소상쇄 프로그램의 해외 사례 고찰 (Study on Forestry-Based Carbon Offset Programs)

  • 이승은
    • 한국기후변화학회지
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    • 제1권2호
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    • pp.97-107
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    • 2010
  • 산림의 조성 및 경영, 목제품 활용, 전용방지 등을 통한 이산화탄소의 고정 사업은 대기 중의 온실가스 농도를 감소시킬 뿐 아니라, 다양한 생태적, 경제적인 부가 편익을 제공하는 것으로 알려져 있다. 이와 같은 산림 관련 활동을 통하여 획득된 이산화탄소의 순흡수량에 대하여 배출권을 발행하고 거래하는 산림 탄소상쇄 프로그램이 전 세계적으로 운영되고 있다. 산림 탄소상쇄 프로그램은 기업의 사회공헌 활동이나 자발적 배출량 감축, 배출규제의 준수 등에 활용되고 있고, 국내에도 그에 대한 관심이 점차 높아지고 있다. 본 연구에서는 해외의 산림 탄소상쇄 프로그램의 주요 특성들을 비교 분석하여, 프로그램의 구성 요소와 기준, 방안 등에 관하여 고찰하였다. 해외의 산림 탄소상쇄 프로그램의 대상 사업 및 기준, 추가성 분석 방법, 배출권의 발행 형태, 이산화탄소 흡수량의 산정 및 모니터링, 비영속성 관리 방법, 부가 편익에 대한 요구사항 등은 프로그램의 목적과 운영기관, 가치 등에 따라 차이가 있다. 해외의 선진사례들을 참조로 국내 산림 탄소상쇄 사업의 활성화에 기여하면서도 국제적 수준의 품질을 가지는 배출권을 생산하기 위한 프로그램을 개발해야 할 것이고, 이를 위한 방향성과 기본 조건 등을 파악하였다.

KIAPS 자료동화 시스템에서 AMSU-A의 품질검사 및 편향보정 반복기법에 관한 연구 (A Study of Iterative QC-BC Method for AMSU-A in the KIAPS Data Assimilation System)

  • 정한별;전형욱;이시혜
    • 대기
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    • 제29권3호
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    • pp.241-255
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    • 2019
  • Bias correction (BC) and quality control (QC) are essential steps for the proper use of satellite observations in data assimilation (DA) system. BC should be calculated over quality controlled observation. And also QC should be performed for bias corrected observation. In the Korea Institute of Atmospheric Prediction Systems (KIAPS) Package for Observation Processing (KPOP), we adopted an adaptive BC method that calculates the BC coefficients with background at the analysis time rather than using static BC coefficients. In this study, we have developed an iterative QC-BC method for Advanced Microwave Sounding Unit-A (AMSU-A) to reduce the negative feedback from the interaction between BC and QC. The new iterative QC-BC is evaluated in the KIAPS 3-dimensional variational (3DVAR) DA cycle for January 2016. The iterative QC-BC method for AMSU-A shows globally significant benefits for error reduction of the temperature. The positive impacts for the temperature were predominant at latitudes of $30^{\circ}{\sim}90^{\circ}$ of both hemispheres. Moreover, the background warm bias across the troposphere is decreased. Even though AMSU-A is mainly designed for atmospheric temperature sounding, the improvement of AMSU-A pre-processing module has a positive impact on the wind component over latitudes of $30^{\circ}S$ near upper-troposphere, respectively. Consequently, the 3-day-forecast-accuracy is improved about 1% for temperature and zonal wind in the troposphere.

다축대각단조(MADF) 가공횟수에 따른 AA1100의 미세조직 변화 (Microstructural Changes of AA1100 According to the Processing Number of Multi-Axial Diagonal Forging (MADF))

  • 권상철;김순태;김다빈;김민성;이성;최시훈;정효태
    • 소성∙가공
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    • 제28권2호
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    • pp.63-70
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    • 2019
  • This study investigates the effects of multi-axial diagonal forging (MADF) processing number on the microstructures of AA1100 fabricated using MADF processes. The cast AA1100 was annealed at $400^{\circ}C$ for 3hrs in $N_2$ atmosphere and cut into $25mm^3$ cubes for the MADF processes. The MADF process consist of plane forging with a thickness reduction of 30% and a diagonal forging with a diagonal forging angle of 135 degrees. In order to analyze the microstructural variations based on the number of repetitions, 1, 2, 3 and 4 cycles of the MADF process were performed. AA1100 specimens were successfully deformed without cracking of the surface for up to 4 cycles of MADF. The grain size, average misorientation and average grain orientation spread (GOS) of MADF processed materials were analyzed using EBSD technique. The results showed that MADF process effectively refined the microstructure of AA1100 with an initial average grain size of $337.4{\mu}m$. The average grain sizes of specimens which were MADF processed for 2, 3, 4 cycles were refined to be $1.9{\mu}m$, $1.6{\mu}m$, $1.4{\mu}m$, respectively. The grain refinement appeared saturated when AA1100 got MADF processed over 2 cycles. When the specimen was subjected to two or more cycles of MADF, the degree of decrease in the average grain size drastically decreased with an increase in the number of cycle due to the softening phenomena such as dynamic recovery or dynamic recrystallization during processing.

Thrust force and base bending moment acting on a horizontal axis wind turbine with a high tip speed ratio at high yaw angles

  • Bosnar, Danijel;Kozmar, Hrvoje;Pospisil, Stanislav;Machacek, Michael
    • Wind and Structures
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    • 제32권5호
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    • pp.471-485
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    • 2021
  • Onshore wind turbines may experience substantially different wind loads depending on their working conditions, i.e. rotation velocity of rotor blades, incoming freestream wind velocity, pitch angle of rotor blades, and yaw angle of the wind-turbine tower. In the present study, aerodynamic loads acting on a horizontal axis wind turbine were accordingly quantified for the high tip speed ratio (TSR) at high yaw angles because these conditions have previously not been adequately addressed. This was analyzed experimentally on a small-scale wind-turbine model in a boundary layer wind tunnel. The wind-tunnel simulation of the neutrally stratified atmospheric boundary layer (ABL) developing above a flat terrain was generated using the Counihan approach. The ABL was simulated to achieve the conditions of a wind-turbine model operating in similar inflow conditions to those of a prototype wind turbine situated in the lower atmosphere, which is another important aspect of the present work. The ABL and wind-turbine simulation length scale factors were the same (S=300) in order to satisfy the Jensen similarity criterion. Aerodynamic loads experienced by the wind-turbine model subjected to the ABL simulation were studied based on the high frequency force balance (HFFB) measurements. Emphasis was put on the thrust force and the bending moment because these two load components have previously proven to be dominant compared to other load components. The results indicate several important findings. The loads were substantially higher for TSR=10 compared to TSR=5.6. In these conditions, a considerable load reduction was achieved by pitching the rotor blades. For the blade pitch angle at 90°, the loads were ten times lower than the loads of the rotating wind-turbine model. For the blade pitch angle at 12°, the loads were at 50% of the rotating wind-turbine model. The loads were reduced by up to 40% through the yawing of the wind-turbine model, which was observed both for the rotating and the parked wind-turbine model.

Evaluation of ammonia (NH3) emissions from soil amended with rice hull biochar

  • Park, Seong-Yong;Choi, Ha-Yeon;Kang, Yun-Gu;Park, Seong-Jin;Luyima, Deogratius;Lee, Jae-Han;Oh, Taek-Keun
    • 농업과학연구
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    • 제47권4호
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    • pp.1049-1056
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    • 2020
  • Ultrafine dust causes asthma and respiratory and cardiovascular diseases when inhaled. Ammonia (NH3) plays a big role in ultrafine dust formation in the atmosphere by reacting with nitrogen oxides (NOx) and sulfur oxides (SOx) emitted from various sources. The agricultural sector is the single largest contributor of NH3, with the vast majority of emissions ensuing from fertilizers and livestock sector. Interest in using biochar to attenuate these NH3 emissions has grown. This experiment was conducted to study the effects of using rice hull biochar pyrolyzed at three different temperatures of 250℃ (BP 4.6, biochar pH 4.6), 350℃ (BP 6.8), and 450℃ (BP 10.3) on the emission of ammonia from soil fertilized with urea. The emissions of NH3 initially increased as the experiment progressed but decreased after peaking at the 84th hour. The amount of emitted NH3 was lower in soil with biochar amendments than in that without biochar. Emissions amongst biochar-amended soils were lowest for the BP 6.8 treatment, followed in an ascending order by BP 10.3 and BP 4.6. Since BP 6.8 biochar with neutral pH resulted in the lowest amount of NH3 emitted, it can be concluded that biochar's pH has an effect on the emissions of NH3. The results of this study, therefore, indicate that biochar can abate NH3 emissions and that a neutral pH biochar is more effective at reducing gaseous emissions than either alkaline or acidic biochar.

Seismic performance of low-rise reinforced concrete moment frames under carbonation corrosion

  • Vaezi, Hossein;Karimi, Amir;Shayanfar, Mohsenali;Safiey, Amir
    • Earthquakes and Structures
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    • 제20권2호
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    • pp.215-224
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    • 2021
  • The carbon dioxide present in the atmosphere is one of the main reasons for the corrosion of bridges, buildings, tunnels, and other reinforced concrete (RC) structures in most industrialized countries. With the growing use of fossil fuels in the world since the Industrial Revolution, the amount of carbon dioxide in urban and industrial areas of the world has grown significantly, which increases the chance of corrosion caused by carbonation. The process of corrosion leads to a change in mechanical properties of rebars and concrete, and consequently, detrimentally impacting load-bearing capacity and seismic behavior of RC structures. Neglecting this phenomenon can trigger misleading results in the form of underestimating the seismic performance metrics. Therefore, studying the carbonation corrosion influence on the seismic behavior of RC structures in urban and industrial areas is of great significance. In this study, a 2D modern RC moment frame is developed to study and assess the effect of carbonation corrosion, in 5-year intervals, for a 50 years lifetime under two different environmental conditions. This is achieved using the nonlinear static and incremental dynamic analysis (IDA) to evaluate the reinforcement corrosion effects. The reduction in the seismic capacity and performance of the reinforced concrete frame, as well as the collapse probability over the lifetime for different corrosion scenarios, is examined through the capacity curves obtained from nonlinear static analysis and the fragility curves obtained from IDA.

강원도에서 적설에 의한 일반국도 교통 특성 분석 (Analysis of Traffic Characteristics of General National Roads by Snowfall in Gangwon-do)

  • 조은수;권태영;김현욱;김규랑;김승범
    • 대기
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    • 제31권2호
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    • pp.157-170
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    • 2021
  • To investigate the effect of snowfall on the traffic of general roads in Gangwon-do, case analysis was performed in Gangneung, Pyeongchang, and Chuncheon using ASOS (Automated Synoptic Observing System) snowfall data and VDS (Vehicle Detector System) traffic data. First, we analyzed how much the traffic volume and speed decrease in snowfall cases on regional roads compared to non-snow cases, and the characteristics of monthly reduction due to snowfall were investigated. In addition, Pearson correlation analysis and regression analysis were performed to quantitatively grasp the effect of snowfall on traffic volume and speed, and sensitivity tests for snowfall intensity and cumulative snowfall were performed. The results showed that the amount of snowfall caused decrease both in the traffic volume and speed from usual (non-snowfall) condition. However, the trend was different by region: The decrease rate in traffic volume was in the order of Gangneung (17~22%), Chuncheon (14~17%), and Pyeongchang (11~14%). The decrease rate in traffic speed was in the order of Chuncheon (9~10%), Gangneung (8~9%), Pyeongchang (5~6%). No significant results were found in the monthly decrease rate analysis. In all regions, traffic volume and speed showed a negative correlation with snowfall. It was confirmed that the greater the amount of traffic entering the road, the greater the slope of the trend line indicating the change in snowfall due to the traffic volume. As a result of the sensitivity test for snowfall intensity and cumulative snowfall, the snowfall information at intervals of 6-hours was the most significant.

고온 용융염계에서 Ni-Base 초합금의 부식거동 (Corrosion Behavior of Ni-Base Superalloys in a Hot Molten Salt)

  • 조수행;강대승;홍순석;허진목;이한수
    • 대한금속재료학회지
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    • 제46권9호
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    • pp.577-584
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    • 2008
  • The electrolytic reduction of spent oxide fuel involves the liberation of oxygen in a molten LiCl electrolyte, which results in a chemically aggressive environment that is too corrosive for typical structural materials. So, it is essential to choose the optimum material for the process equipment handling molten salt. In this study, corrosion behavior of Inconel 713LC, Inconel MA 754, Nimonic 80A and Nimonic 90 in the molten salt $LiCl-Li_2O$ under an oxidizing atmosphere was investigated at $650^{\circ}C$ for 72~216 hrs. Inconel 713LC alloy showed the highest corrosion resistance among the examined alloys. Corrosion products of Inconel 713LC were $Cr_2O_3$, $NiCr_2O_4$ and NiO, and those of Inconel MA 754 were $Cr_2O_3$ and $Li_2Ni_8O_{10}$ while $Cr_2O_3$, $LiFeO_2$, $(Cr,Ti)_2O_3$ and $Li_2Ni_8O_{10}$ were produced from Nimonic 80A. Also, corrosion products of Nimonic 90 were found to be $Cr_2O_3$, $(Cr,Ti)_2O_3$, $LiAlO_2$ and $CoCr_2O_4$. Inconel 713LC showed local corrosion behavior and Inconel MA 754, Nimonic 80A, Nimonic 90 showed uniform corrosion behavior.

액체금속(GaInSn)윤활하에서 DLC(ta-C) 코팅된 레이저 표면 텍스쳐링 딤플패턴의 미끄럼 마찰특성평가 (Evaluation of Sliding Friction Properties of Laser Surface Texturing Dimple Pattern with DLC Coating under GaInSn Liquid Metal Lubricant)

  • 권규빈;장영준;채영훈
    • Tribology and Lubricants
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    • 제37권3호
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    • pp.106-111
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    • 2021
  • There are several studies on reducing the friction that occurs on the relative sliding contact surface of moving parts under extreme environments. In particular, a solid lubricated bearing is studied to solve the tribological problem with friction reduction and durability parts using solid lubricants (lead or silver) in a vacuum atmosphere. Galinstan is mainly used as a liquid metal lubricant, but it is inevitable to have limited tribological applications owing to its high coefficient of friction. Many researchers work on surface texturing for surface modification and precision processing methods. To increase durability and low friction, DLC coating with hydrophobicity is applied on the contact surface texture. Therefore, using an untextured specimen, a dimple specimen, and a DLC-coated dimple specimen under liquid metal lubrication, this paper presents the following experimental sliding friction characteristics in the sliding friction test. 1) The average coefficient of friction of the DLC-coated dimple specimen and dimple specimen are lower compared to that of a non-patterned specimen. 2) In the DLC-coated dimple specimens, the average coefficient of friction changes according to the change in the dimple density. 3) DLC-coated dimple specimens with a density of 12.5 have the lowest average coefficient of friction under 41.6 N of normal load and 143.3 RPM.