• Title/Summary/Keyword: reduction atmosphere

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The Effects of Second Phases on the Photocatalytic Characteristics of the TiO2 base Nano Composite (TiO2계 나노 복합촉매 특성에 미치는 생성상의 영향)

  • 안인섭;고봉석;배승열
    • Journal of Powder Materials
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    • v.11 no.2
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    • pp.143-148
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    • 2004
  • In the present study, $TiO_2$ imbedded composite powders have been successfully prepared from the (Cu. Zn)/$TiO_2$ composite salt solution. The composite (Cu, Zn)/$TiO_2$ powders were formed by drying the solution at 200~$600^{\circ}C$ in the hydrogen atmosphere. Photocatalytic characteristics was evaluated by detecting the decomposition ratio of aniline blue with UV-visible spectrophotometer(Shimazu Co., UV-1601). Phase analysis of (Cu, Zn)/$TiO_2$ composite powders was carried out by XRD and DSC, and powder size was measured with TEM. The mean particle size of composite powders was about 100mm. As the reduction temperature increases, a few zinc sulfide and oxide phases was formed and copper oxide phase was reduced. The decomposition ratio of aniline blue was about 80% under the UV irradiation by the TiO$_2$ phase in the composite (Cu, Zn)/$TiO_2$ powders and similar decomposition ratio of 80% was obtained at the UV lightless condition by virtue of Cu and Zn compounds.

Effect of Aluminum, Manganese, and Zirconium on the Content of Nickel in Molten Magnesium (마그네슘용탕의 니켈 함량에 미치는 알루미늄, 망간 및 지르코늄의 영향)

  • Jeong, Dae-Yeong;Moon, Young-Hoon;Moon, Byoung-Gi;Park, Won-Wook;Sohn, Keun-Yong
    • Journal of Korea Foundry Society
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    • v.35 no.1
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    • pp.8-14
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    • 2015
  • Variations of nickel contents and microstructures in molten magnesium alloys on the addition of aluminum, zirconium, and manganese have been investigated. Specimens were prepared by melting under $SF_6$ and $CO_2$ atmosphere and casting into a disc of 29 mm diameter with 7~10 mm thickness from the melt acquired at the top of crucible. Before casting, the molten metal was stirred for 3 minutes after each addition of alloying elements and maintained for 30 minutes for settling down. Results showed that zirconium did not significantly affect the content of nickel while aluminum remarkably reduced it by forming $Al_3Ni_2$ phase. When manganese are added to Mg-1wt%Ni alloy along with aluminum, both elements remarkably reduced the content of nickel. The addition of 1.5 wt% manganese to Mg-1wt%Ni alloy containing aluminum further reduced the content of nickel by more than 30%, during which an additional intermetallic phase $Al_{10}Mn_3Ni$ was precipitated in the molten magnesium.

Surface-energy -induced Selective Growth and Magnetic Induction in 3%Si-Fe Strip (극박 3%규소강에서 표면에너지 유기 선택적 결정성장 현상과 자성특성)

  • 조성수
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.15 no.4
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    • pp.57-61
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    • 2001
  • The {111}<112> deformation torture, which originated from the {110}<00l> texture near the surface of hot bands, is not prerequisite for the recrystallized {110}<001> Goss texture. During final annealing, surface-energy-induced selective growth of grains urn at the strip surface of 3%Si-Fe alloys containing 6ppm bulk content of sulfur. With decreasing final reduction, the probability that Goss grains survive under the highly segregated sulfur atmosphere and have a chance for later surface-energy-induced selective growth becomes higher, resulting in high magnetic induction.

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The Thermal Behavior and Removal of Chloride in EAF Dust (EAF Dust중 염화물의 거동과 제거에 관한 연구)

  • 김영환;김종학;고인용;문석민;이대열;신형기;오재현
    • Resources Recycling
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    • v.6 no.1
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    • pp.35-39
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    • 1997
  • This study was carried out to find the existing forms of chlorlnc in EM dust and to understand the valaliliratian behavior and the removal of chlorine from EAF dust with lemperalure and heating almosphere The chemical compositions of dust A are 27.3%Fe. 21.8%3Zn, 3 15%Pb, 3 51%C1 and that of dust B BE 33.92%Fe, 15.94%Zn, 2.73% Pb, 3.98%Cl. The XRD analysis and water leaching test shows that chlorlne in EM dust exist mainly as NaCI, KCI, Pb (0H)Cl. Above 99% of chlorine was volatilized when dust was hentcd in alr atmosphere at 1100$^{\circ}$C h r 1 hour and that was 96% when heated in reduction atmosnherc at 1100$^{\circ}$C for 1 hour.

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Effect of Mg content on the density and critical properties of in-situ reacted MgB2 bulk superconductor

  • Jun, Byung-Hyuk;Kim, Dan-Bi;Park, Soon-Dong;Kim, Chan-Joong
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.1
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    • pp.19-22
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    • 2014
  • The effects of Mg content on the pore formation, density and critical properties were investigated in in-situ reacted $MgB_2$ superconductors. The $Mg_{1+x}B_2$, (x=-0.2, 0.0, 0.05, 0.3, 1.0) bulk samples with different Mg contents were heat-treated at $900^{\circ}C$ for 1 h in an Ar atmosphere. The dimensional changes of a pellet's mass and volume after heat-treatment were measured. After heat-treatment process, the sample mass was decreased by Mg evaporation, but the sample volume was expanded by pore formation at the Mg site; therefore, the apparent density was decreased. Spherical pores the same as Mg particles were developed after heat-treatment in all samples, and the pore density was increased with increasing Mg content. As the x of Mg content was increased to 1.0, the apparent density of $Mg_{1+x}B_2$ samples was decreased due to a relatively larger reduction in a mass change. The critical current density of Mg excessive sample of x=0.05 showed the highest values over the applied magnetic fields because the excessive Mg may compensate Mg loss and enhance grain connectivity.

A Study on the Effect of Initial Strength of Cement Paste Containing Fly Ash or Blast Furnace Slag on CO2 Curing Period (플라이 애쉬 및 고로슬래그 혼입 시멘트 페이스트의 CO2 양생 기간에 따른 초기강도의 영향에 대한 연구)

  • Han, Jae-Do;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.83-84
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    • 2018
  • As the concentration of greenhouse gases in the atmosphere increases, the reduction of CO2 is gaining worldwide attention. In the construction industry, cement replacement materials such as fly ash and blast furnace slag were investigated to reduce CO2 emissions in cement production process. Precast concrete is used in the field after manufacturing in the factory in the form of pipes and bricks because of shortening construction period and cutting construction cost. According to the results of previous research, it is known that early CO2 curing in concrete using OPC or fly ash has an initial strength enhancement effect and can be used for precast concrete production. Therefore, the purpose of this study is to evaluate the strength improvement effect by confirming the initial strength improvement effect when blast furnace slag is mixed.

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Evaluation of Corrosion Properties of Several Metals in Waters for Reference Standard on Corrosion Rate - I. Andong Area (부식속도에 대한 참조 표준 작성을 위한 수환경에 따른 각종 금속의 부식특성 평가 - I. 안동지역)

  • Shim, G.T.;Kwon, Y.H.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.8 no.6
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    • pp.238-242
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    • 2009
  • Corrosion of metallic materials occurs by the reaction with corrosive environment. In general, corrosive environments are classified as atmospheric, marine, soil etc. and regardless of any corrosive environments, reduction of thickness and cracking and degradation are induced by corrosion. Among several corrosive environments, knowing the atmospheric corrosiveness of a region, city, or country is considered of ultimate importance for major industrialists and investors who require knowledge of the corrosive impact of the atmosphere on everyday materials such as carbon steel, weathering steel, zinc, copper, and aluminium. This is why the atmospheric corrosiveness map is needed. This paper dealt with corrosion properties between several waters in the region and carbon steel, weathering steel, galvanized steel, pure copper, and pure aluminium at the representative rural area of Korea - Andong.

Analysis of organic rankine cycle for designing evaporator of engine exhaust heat recovery system (엔진 배기열 회수 증발기 설계를 위한 유기랭킨사이클 분석)

  • Ko, Jea-Hyun;Choi, Byung-Chul;Park, Kweon-Ha
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.5
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    • pp.446-452
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    • 2013
  • Interest in the energy efficiency and carbon reduction technology is increasing. Many studies have done on the technologies of heat recovery systems, because over 30% of the total energy is released into the atmosphere with the exhaust gas flow. In this study, the Rankine cycle is analyzed in the optimum conditions given through the previous work. The result shows that the exergy efficiency is 0.53 and the output is 1.43 kW at the condition of the pressure ratio of 0.6 and the mass flow rate of 0.7.

The Chinese Performance-based Code for Fire-resistance of Steel Structures

  • Li, Guo-Qiang;Zhang, Chao
    • International Journal of High-Rise Buildings
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    • v.2 no.2
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    • pp.123-130
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    • 2013
  • In the past two decades, researchers from different countries have conducted series of experimental and theoretical studies to investigate the behaviour of structures in fire. Many new insights, data and calculation methods have been reported, which form the basis for modern interdisciplinary structural fire engineering. Some of those methods are now adopted in quantitative performance-based codes and have been migrated into practice. Mainly based on the achievements in structural fire research at China, the Chinese national code for fire safety of steel structures in buildings has been drafted and approved, and will be released in this year. The code is developed to prevent steel structures subjected to fire from collapsing, ensure safe evacuation of building occupants, and reduce the cost for repairing the damages of the structure caused by fire. This paper presents the main contents of the code, which includes the fire duration requirements of structural components, fundamental requirements on fire safety design of steel components, temperature increasing of atmosphere and structural components in fire, loading effect and capacity of various components in fire, and procedure for fire-resistant check and design of steel components. The analytical approaches employed in the code and their validation works are also presented.

Synthesis and Luminescent Characteristics of (Sr,Ba)2Ga2SiO7:Eu2+ Green Phosphor for LEDs (LED용 (Sr,Ba)2Ga2SiO7:Eu2+ 녹색 형광체의 합성 및 발광특성)

  • Park, Jeong-Gyu;Lee, Seung-Jae;Yeon, Jeong-Ho
    • Journal of the Korean Chemical Society
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    • v.50 no.2
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    • pp.137-140
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    • 2006
  • In this report, Europium doped strontium barium gallium silicate ((Sr,Ba)2Ga2SiO7:Eu2+) phosphor has been synthesized by conventional solid-state method and investigated luminescent characteristic. Appropriate proportions of the raw materials were mixed in an agate mortar with acetone to obtain starting mixtures. Also, this phosphor was prepared by simple process under the reduction atmosphere (25% H2/75% N2). This phosphor can be applicated to the green phosphor for white LED because it has green emission band (513 nm), which emits efficiently under the 405nm excitation energy.