• Bulletin of the Korean Chemical Society
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• v.33 no.4
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• pp.1279-1284
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• 2012

Silica supported $Cs_{2.5}H_{0.5}PMo_{12}O_{40}$ catalyst was prepared through sol-gel method with ethyl silicate-40 as silicon resource and characterized by X-ray diffraction, infrared spectroscopy, scanning electron microscopy, nitrogen adsorption-desorption and potentiometric titration methods. The $Cs_{2.5}H_{0.5}PMo_{12}O_{40}$ particles with Keggin-type structure well dispersed on the surface of silica, and the catalyst exhibited high surface area and acidity. The catalytic performance of the catalysts for benzene liquid-phase nitration was examined with 65% nitric acid as nitrating agent, and the effects of various parameters were tested, which including temperature, time and amount of catalyst, reactants ratio, especially the recycle of catalyst was emphasized. Benzene was effectively nitrated to mononitro-benzene with high conversion (95%) in optimized conditions. Most importantly, the supported catalyst was proved has excellent stability in the nitration progress, and there were no any other organic solvent and sulfuric acid were used in the reaction system, so the liquid-phase nitration of benzene that we developed was an eco-friendly and attractive alternative for the commercial technology.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.1
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• pp.49-62
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• 2016

In this study, a solid oxide fuel cell (SOFC) system model including balance of plant (BOP) for building electric power generation is developed to study the effect of operating conditions on the system efficiency and power output. SOFC system modeled in this study consists of three heat-exchangers, an external reformer, burner, and two blowers. A detailed computational cell model including internal reforming reaction is developed for a planer SOFC stack which is operated at intermediate temperature (IT). The BOP models including an external reformer, heat-exchangers, a burner, blowers, pipes are developed to predict the gas temperature, pressure drops and flow rate at every component in the system. The SOFC stack model and BOP models are integrate to estimate the effect of operating parameters on the performance of the system. In this study, the design of experiment (DOE) is used to compare the effects of fuel flow rate, air flow rate, air temperature, current density, and recycle ratio of anode off gas on the system efficiency and power output.

• Journal of the Korean GEO-environmental Society
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• v.11 no.11
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• pp.27-36
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• 2010

This study was conducted to evaluate physicochemical parameters; temperature, pH, C/N ratio, water content, organic contents and volume in a pilot-scale(capacity : $100m^3$) ultra thermophilic aerobic composting. There were three types input: municipal wasted sludge, livestock manure and slurry, and food waste produced in Jung-Eb city. Each target material was carried out by the first fermentation(organic waste + seed culture) and the second one(organic waste + seed culture + recycle compost), respectively. During composting, only with supply of air and mixing, the temperature increased $90{\sim}105^{\circ}C$ after every mixing in both periods. The changes of pH, $O_2$, $CO_2$ and $NH_3$ represented typical organic decomposition pattern by microorganisms. Also, all other physicochemical parameters of ultra thermophilic aerobic composting process showed similar or better performance than these of general aerobic composting. Heavy metal concentration of fermented compost adapted to compost fertilizer regulation standard in the heavy metal and hazardous analysis.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.6
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• pp.1139-1148
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• 2000

To treat and recycle a large quantity of converter slag. the milling properties of -14/ +24 mesh-sized slag has been considered. The optimal conditions in milling process were investigated for producing powder-type slag and the required consumption was derived for the economical grinding. The characteristics of milling processes were studied in the variation of the rotational speed, milling time, filling ratio of ball, and size and amount of feed. The grinding efficiency was also examined. The optimal rotational speed in this experimental condition was observed to be the value of 79% of critical speed. The extent of grinding was increased with increasing the grinding time. but the efficiency of milling was decreased with the time. 50% ball filling was shown to have the optimal grinding effect, and less amount and small-sized feed made the milling efficiency high. As the result, using Bond's equation, power required for efficient milling was considered and the highest value was observed in the condition of high grinding time and optimal rotational speed.

• Journal of the Korean Society for Marine Environment & Energy
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• v.13 no.1
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• pp.43-46
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• 2010

As one of the methods for recycling the FRP used for the small and medium-sized waste ships, separation of the roving layer from the mat has some merit in a sense of the recycling energy and the environmental effects. Similar characteristics between the roving and the mat make the mechanically automatic differentiation difficult. They, however, contain different ratio of the resin and the glass and the thickness. In this study photo physical differentiation between the two layers has been made using (1) boiling concentrated sulfuric acid which can dissolve the resin in the FRP layer and (2) hydrogen fluoride(HF) solution which can reacts with $SiO_2$ fragments of the glass. Furthermore coloring the FRP sample with water-soluble dye following the HF treatment makes the roving layer more distinguishable photophysically. The implementation of HF treatment has been successfully tested in this study.

• Journal of the Korean GEO-environmental Society
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• v.14 no.4
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• pp.29-37
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• 2013

In order to recycle both water sludge and waste fishing net(WFN), it was investigated in this paper the engineering characteristics of mixtures that consisted of different content of water sludge(0%, 10%, 30%, 50%) and reinforced with waste fishing net(unreinforced, untreated WFN, glue treated WFN). WFN or glue treated WFN(1&2 layers) was also added to the mixture to improve the interlocking between the soil particle and WFN. Several series of laboratory tests such as compaction test, triaxial test, oedometer test, permeability test and leaching test were carried out. The experimental test results indicated that, as water sludge content increases, maximum dry unit weight, cohesion, friction angle, and permeability of the mixture decrease, while optimum moisture content, compression index, expansion index and compressibility increase. For the case of reinforced mixture, its cohesion and friction angle are increased due to the inclusion of WFN and glue treated WFN. Leaching result of mixture was satisfied with standard of ministry of environment.

• Journal of the Korea Institute of Building Construction
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• v.19 no.5
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• pp.401-409
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• 2019

This paper aims to recycle red mud from a byproduct in the alumina industry as an alternative raw material for depleted natural resources. In order to apply red mud as a ceramic material, red mud ceramics were prepared according to mixing and temperature in a laboratory environment. Compared with KS L 4201 in terms of compression ratios and absorptions, it is found that two kinds of conditions for one type and three conditions for two types meet the standard. When red mud is used as a clay brick raw material, the substitution ratio of red mud is 10% or less, and the firing temperature is considered to be appropriate at $1200^{\circ}C$. In order to apply red mud to clay brick raw material in actual field, various samples and firing temperature should be considered in the future.

• Journal of Korea Society of Waste Management
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• v.35 no.8
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• pp.785-798
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• 2018

Since the Framework Act on Resource Circulation was enacted in 2018, the government should establish a National Resource Circulation Master Plan every 10 years, which defines mid- to long-term policy goals and directions on the efficient use of resources, prevention of waste generation and recycling of waste. In addition, we must set mid- to long-term and stepwise targets for the final disposal rate, recycling rate (based on sorted recyclable materials and recycled products), and energy recovery rate of wastes, and relevant measures should be taken to achieve these targets. However, the current industrial waste (IW) statistics have limitations in setting these targets because the final disposal rate and recycling rate are calculated as the ratio of the recycling facility input to the IW generation. In this study, the material flow from the collection stage to the final disposal of industrial waste was analyzed based on the generation of 2016, and the actual recycling amount, actual incineration amount, final disposal amount and their rates were calculated. The effect on the recycling, incineration and final disposal rates was examined by changing the treatment method of nonhazardous wastes from the factory and construction and demolition wastes, which were put in landfills in 2016. In addition, the variation of the waste treatment charge was investigated according to the change of treatment methods. The results of this study are expected to be effectively used to establish the National Resource Circulation Master Plan and industrial waste management policy in the future in South Korea.

• Elastomers and Composites
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• v.58 no.1
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• pp.32-43
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• 2023

The worldwide use of polyurethane foam products generates large amounts of waste, which in turn has detrimental effects on the surroundings. Hence, finding an economical and environmentally friendly way to dispose of or recycle foam waste is an utmost priority for researchers to overcome this problem. In that sense, the glycolysis of waste flexible polyurethane foam (WFPF) from automotive seat cushions using different industrial-grade glycols and potassium hydroxide as a catalyst to produce recovered polyol was investigated. The effect of different molecular weight polyols, catalyst concentration, and material ratio (PU foam: Glycols) on the reaction conversion and viscosity of the recovered polyols was determined. The obtained recovered polyols are obtained as single or split-phase reaction products. Besides, the foaming characteristics and physical properties such as cell morphology, thermal stability, and compressive stress-strain nature of the regenerated flexible foams based on the recovered polyols were discussed. It was observed that the regenerated flexible foams displayed good seating comfort properties as a function of hardness, sag factor, and hysteresis loss compared to the reference virgin foam. With the growing demand for a sustainable and circular economy, a global valorization of glycolysis products from polyurethane scraps can be realized by transforming them into profitable substances.

• Journal of the Korean Society of Food Culture
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• v.25 no.6
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• pp.708-718
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• 2010

This study was conducted to examine the effects of a healthy dietary life and purchase of environmental-friendly food materials according to a mother's lifestyles of health and sustainability (LOHAS) attitudes. The subjects consisted of 295 mothers. The findings are summarized as follows. The mother's LOHAS attitude index averaged 3.39 points out of 5 points. High LOHAS attitude items were "I participate actively in separating the trash collection" (4.16 points), and "I recycle dresses that I do not wear by taking them to the recycling center" (4.08 points). In contrast, LOHAS attitude items for "I do community service activity on the weekend" (2.57 points), and "I try to serve in the local community" (2.63 points) scored very low. A high LOHAS behavior index occurred for mothers who were "resource saving", whereas "social welfare" scored low. Mother's intention to purchase environmental-friendly food materials averaged 3.61 points. Mother's health dietary life attitude score averaged 3.52 points. When age, monthly income, and the environmental-friendly food materials purchase ratio of the mother was high, the health dietary life performance was high. The LOHAS attitude index of mothers had an impact on the purchase intention of environmental-friendly food materials in resource saving and environmental-friendly oriented propensity groups. The LOHAS attitude index of mothers impacted healthy dietary life in environmental-friendly, family and health oriented propensity groups.