• 한국환경보건학회지
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• 제32권1호
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• pp.71-76
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• 2006

Treatment performance and microbial community structure were investigated in water-soluble cutting oil treatment process using biological activated carbon. DOC removal in BACI column at $15^{\circ}C$ was higher than at $25^{\circ}C$, but those of BAC3 column after 60days was high at$25^{\circ}C$. Also, quinone content of first-step reactors at $25^{\circ}C$ and $15^{\circ}C$ was much the same, but those of the third-step reactor at $25^{\circ}C$ was higher than at $15^{\circ}C$. The dominant type of two apparatus was ubquinone (UQ)-l 0 followed by UQ-8. Menaquinones were detected from $25^{\circ}C$ apparatus and effluent. This suggested that DOC removal at $25^{\circ}C$ was advanced degradation by attached microorganisms on the activated carbon surface. The DOC removal in long-term activated carbon apparatus increased with going in BAC3 column. This indicated the influent of POC was a result of DOC removal efficiency decrease. Integrated DOC removal from start point in experiment to break point and quinone content were showed a tendency of increasing with going last-step activated carbon apparatus. Therefore, the biological activated carbon apparatus used by this study was effective treatment process in contaminated groundwater by water-soluble cutting oil.

• 한국수소및신에너지학회논문집
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• 제13권4호
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• pp.304-312
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• 2002

In this study, the performance of the $5Nm^3/hr$ compact type steam reformer which was developed for application of fuel cell or hydrogen station was evaluated in terms of gas process efficiency. For these purposes, reforming efficiency and total efficiency with system load change were analyzed. The reforming efficiency was calculated from the total molar flow of hydrogen output over total fuel flow input to the reformer and the burner on the higher heating value(HHV). In the case of the total efficiency, recovered heat at the heat recovery exchanger was considered. From the results, it was known that system performance was stable, because methane conversion showed the a slight decline which is about 2% though increasing system load to full. Reforming efficiency was increased from 20% to 58%, respectively as increasing system load from 10% to 90%. It was found that total efficiency was higher then reforming efficiency because of terms of heat recovered. As a results, it was known that total efficiency was increased form 75% to 83% at the 10% and 90% system load, respectively. From these results, it is concluded that compact steam reformer which is composed of stacking plate-type reactors is suitable to on-site hydrogen generator or to fuel cell application because of quick start within 1 hr and good performance.

• 한국수소및신에너지학회논문집
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• 제25권3호
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• pp.247-254
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• 2014

The synthesis of Fischer-Tropsch oil is the catalytic hydrogenation of CO to give a range of products, which can be used for the production of high-quality diesel fuel, gasoline and linear chemicals. Our cobalt based catalyst was prepared Co/alumina, silica and titania by the incipient wet impregnation of the nitrates of cobalt and promoter with supports. Cobalt catalysts was calcined at $350^{\circ}C$ before being loaded into the FT reactors. After the reduction of catalyst has been carried out under $450^{\circ}C$ for 24hrs, FT reaction of the catalyst has been carried out at GHSV of 4,000/hr under $200^{\circ}C$ and 20atm. From these test results, we have obtained the results as following ; in case of 12wt% Co-supported $Al_2O_3$, $SiO_2$ and $TiO_2$ catalysts, maximum activities of the catalysts were appeared at the promoters of Mn, Mo and Ce respectively. The activity of 12wt% $Co/Al_2O_3$ added a Mn promoter was about 3 times as high as that of 12wt% $Co/Al_2O_3$ catalyst without promoters. When it has been the experiment at the range of reaction temperature of $200{\sim}220^{\circ}C$ and GHSV of 1,546~5,000/hr, the results have shown generally increasing the activities with the increase of reaction temperature and GHSV.

• 대한기계학회논문집A
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• 제38권11호
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• pp.1257-1264
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• 2014

최근 제4세대 원자로의 기기 최적설계를 위해 목표파손확률 기반 설계기법에 대한 연구가 활발히 진행되고 있다. 시스템기반코드(System-Based Code, SBC)가 대표적인 예로 설계 혹은 평가 결과는 부분안전계수(Partial Safety Factor, PSF)의 형태로 도출된다. 따라서 부분안전계수는 가동 기간 중 목표파손확률 기반 설계 및 평가를 위한 핵심 요소 가운데 하나이다. 본 연구에서는 특정 목표파손확률 하에서 원주방향 관통균열이 존재하는 배관의 탄소성 균열개시 조건에 대한 부분안전계수 계산 기법을 정립하고 각 평가 인자가 균열개시에 미치는 중요도를 정량적으로 평가하였다. 균열 배관의 J-적분은 GE/EPRI법과 참조응력법으로 계산하였으며, 부분안전계수는 일차 및 이차신뢰도지수법으로 계산하였다. 또한 재료물성치의 통계적 분포 특성이 미치는 영향도 함께 평가하였다.

• 에너지공학
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• 제14권4호
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• pp.232-240
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• 2005

경수 및 중수로 원자로계통에 대한 열수력 안전해석을 위해 개발된 MARS 코드가 고온가스로에 적용될 수 있을지 화인하기 위하여 IAEA TECDOC-1163에서 제시된 고온가스로 원자로공동냉각계통에 대한 Benchmark problem을 평가계산 하였다. HTR-10과 HTTR의 MARS 코드 계산결과는 기 보고된 THERMIX 코드와 THANPACST2 코드의 계산결과 그리고 가용한 실험결과와 비교한 바, 최대 오차범위 $4.5\%$ 정도로 전반적으로 일치하는 것으로 나타났다. 오차의 주요 원인은 복잡한 기하학적 구조를 단순하게 모델링한 부분과 MARS 코드에서 모사하기 어려운 냉각기 , 공기냉각기와 같은 고온가스로. Component에서 발생하였다. 경수형 원자로에서는 중요하게 고려하지 않았던 복사열전달이 고온가스로 원자로공동에서는 붕괴열 제거에 중요한 역할을 수행하는 것으로 나타났다. 결론적으로, 본 연구를 종합하여 볼 때 MARS 코드는 고온가스로 원자로공동냉각계통의 냉각능력을 잘 모사하고 있으며 향후 수소생산용 고온가스로 개발에 있어서 안전해석 코드로서의 역할을 충분히 수행할 수 있을 것으로 판단된다.

• 대한기계학회논문집
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• 제14권1호
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• pp.13-22
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• 1990

본 연구에서는 일반적인 셸 요소에 대해 von Mises의 항복조건에 입각한 탄소 성 구성방정식과 total Lagrangian식을 바탕으로한 비선형 해석이론에 Lagrange Mult- iplier식을 이용한 구속조건(constraints)을 도입하여, 중첩된 비선형 구조물이 갖고 있는 제반 비선형성을 고려할 수 있도록 수식화하였으며, 이를 엄밀해를 구할 수 있는 두개의 외팔보가 중첩된 경우에 적용하여 엄밀해와 비교하였으며, 또한 실제적으로 국 산 핵연료 집합체에 사용되는 각 홀드다운 스프링 집합체에 대한 특성 해석을 수행하 여 그 결과를 실험치와 비교하여 그 비교치가 근사함을 보임으로써 본 방법의 신뢰성 과 효용성을 보였다.

• 한국자동차공학회논문집
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• 제18권5호
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• pp.85-90
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• 2010

As the environmental regulation of vehicle emission is strengthened, investigations for $NO_x$ and PM reduction strategies are popularly conducted. Two current available technologies for continuous $NO_x$ reduction onboard diesel vehicles are Selective Catalytic Reduction (SCR) using aqueous urea and lean $NO_x$ trap (LNT) catalysts. The experiments were conducted to investigate the $NO_x$ reduction performance of SCR system which can control the ratio of $NO/NO_2$, temperature and SV(space velocity), and the model gas was used which is similar to a diesel exhaust gas. The maximum reduction efficiency is indicated when the $NO:NO_2$ ratio is 1:1 and the SV is 30,000 $h^{-1}$ in $300^{\circ}C$. Generally, ammonia slip from SCR reactors are rooted to incomplete conversion of $NH_3$ over the SCR. In this research, slip was occurred in 6cases (except low SV and $NO:NO_2$ ratio is 1:1) after SCR. Among 6 case of slip occurrence, the maximum conversion efficiency is observed when SV is 60,000 $h^{-1}$ in $400^{\circ}C$.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.210-213
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• 2008

The purpose of this study is to investigate the performances of organic removal and methane recovery in the full scale two-phase anaerobic system. The full scale two-phase anaerobic system was consists of an acidogenic ABR (Anaerobic Baffled Reactor) and a methanognic UASB (Upflow Anaerobic Sludge Blanket) reactor. The volume of acidogenic and methanogenic reactors is designed to 28.3 $m^3$ and 75.3 $m^3$. The two-phase anaerobic system represented 60-82% of COD removal efficiency when the influent COD concentration was in the range of 7,150 to 16,270 mg/L after screening (average concentration is 10,280 mg/L). After steady-state, the effluent COD concentration in the methanogenic reactor showed 2,740 $\pm$ 330 mg/L by representing average COD removal efficiency was 71.4 $\pm$ 8.1% when the operating temperature was in the range of 19-32$^{\circ}C$. The effluent SCOD concentration was in the range of 2,000-3,000 mg/L at the steady state while the volatile fatty concentration was not detected in the effluent. Meanwhile, the COD removal efficiency in the acidogenic reactor showed less than 5%. The acidogenic reactor played key roles to reduce a shock-loading when periodic shock loading was applied and to acidify influent organics. Due to the high concentration of alkalinity and high pH in the effluent of the methanogenic reactor, over 80% of methane in the biogas was produced consistently. More than 70 % of methane was recovered from theoretical methane production of TCOD removed in this research. The produced gas can be directly used as a heat source to increase the reactor temperature.

• 한국지하수토양환경학회지:지하수토양환경
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• 제20권6호
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• pp.85-94
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• 2015

RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) is the most important explosive contaminant, both in concentration and in frequency, at military shooting ranges in which green technologies such as phytoremediation or constructed wetlands are the best option for mitigation of explosive compounds discharge to the environment. A study was conducted with two identical lab-scale plug flow constructed wetlands planted with Amur silver grass to treat water artificially contaminated with 40 mg/L of toxic explosive compound, RDX. The reactor was inoculated with or without RDX degrading mixed culture to evaluate plant-microorganism interactions in RDX removal, transformation products distribution, and kinetic constants. RDX and its metabolites in water, plant, and sediment were analyzed by HPLC to determine mass balance and kinetic constants. After 30 days of operation, the reactor reached steady-state at which more than 99% of RDX was removed with or without the mixed culture inoculation. The major transformation product was TNX (Trinitroso-RDX) that comprised approximately 50% in the mass balance of both reactors. It was also the major compound in the plant root and shoot system. Acute toxicity analysis of the water samples showed more than 30% of toxicity reduction in the effluent than that of influent containing 40 mg/L of RDX. In the Amur silver grass mesocosm seeded with the mixed culture, the specific RDX removal rate, that is 1st order removal rate normalized to plant fresh weight, was estimated to be 0.84 kg⁻¹ day⁻¹ which is 16.7% higher than that in the planted only mesocosm. Therefore, the results of this study proved that Amur silver grass is an effective plant for RDX removal in constructed wetlands and the efficiency can be increased even more when applied with RDX degrading microbial consortia.

• 한국물환경학회지
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• 제26권5호
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• pp.754-760
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• 2010

This study was carried out not only to evaluate optimal operating condition to increase biogas production, but also to estimate feasibility of renewable energy from anaerobic digester of sewage sludge. Semi- continuous Fed and Mixed Reactors (SCFMRs) were operated in various condition to quantify the reactor variables. The result of SCFMR operation showed that the biogas productivity and total volatile solids (TVS) removal of total solids (TS) 4% reactor at hydraulic retention time (HRT) 20 days with Organic Loading Rate (OLR) of $1.45kg/m^3-d$ were $0.39m^3/m^3-d$ and 26.7%, respectively which was two times higher than that of TS 2.5% reactor. Consequently the daily biogas production of $20,000m^3$ would be possible from the total volume of $52,000m^3$ of anaerobic digesters of the municipal wastewater treatment plant in D city. In feasibility study for the Biogas utilization, combined heat and power system (CHP) and CNG gasification were examined. In case of CHP, the withdrawal period of capital cost for gas-engine (GE) and micro gas-turbine (MGT) were 7.7 years and 9.1 years respectively. biogas utilization as Clean Natural Gas (CNG) shows lower capital cost and higher profit than that of CHP system. CNG gasificaion after biogas purification is likely the best alternative for Biogas utilization which have more economic potential than CHP system. The withdrawal period of capital cost appeared to be 2.3 years.