• Title/Summary/Keyword: reactive type

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Preparation and Properties of Polymer Blends Type Humidity Sensor for Process Safety (공정안전용 Polymer Blend형 습도센서의 특성 연구)

  • Kang Young-Goo;Cho Myoung-Ho
    • Journal of the Korean Society of Safety
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    • v.19 no.3 s.67
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    • pp.51-56
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    • 2004
  • Conductive polymer blends and composites are widely used for different safety application such as electrostatic charge dissipation(ESD), electromagnetic interference(EMI) shielding, electrostatic prevention and safety chemical sensor. In order to prepare a impedance-type humidity sensor that is durable at high humidities and high temperature, electically conductive polymer blends based on diallyldimethylammonium chloride(DADMAC) and epoxy were prepared in this study. The polymer blends type conductive ionomer exhibits reaction each other DADMAC and epoxy in FT-IR and DSC analysis. The blends material was traced by new peak at 1600cm-1 and appeard improvement of thermal resistance by melting point shift. Alumina substrate was deposited a pair of gold electrodes by screen printing. The blend material were spin-coated with a thin film type on the surface of alumina substrate. The polymer bleld type sensor exhibits a linear impedance increasing better than DADMAC coated humidity sensor. Also it shows good sensitivity, low hysteresis and durability against high humidity.

A Kinetic Study on Michael-type Reactions of 1-(X-Substituted Phenyl)-2-propyn-1-ones with Amines: Effect of Amine Nature on Reactivity and Mechanism

  • Um, Ik-Hwan;Hwang, So-Jeong;Lee, Eun-Ju
    • Bulletin of the Korean Chemical Society
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    • v.29 no.4
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    • pp.767-771
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    • 2008
  • Second-order rate constants have been measured spectrophotometrically for the Michael-type reaction of 1-(Xsubstituted phenyl)-2-propyn-1-ones (2a-f) with amines in $H_2O$ at 25.0 ${\pm}$ 0.1 ${^{\circ}C}$. A linear Brønsted-type plot is obtained with ${\beta}_{nuc}$ = 0.25 ${\pm}$ 0.02, a typical $\beta_{nuc}$ value for reactions which proceed through a stepwise mechanism with attack of amine on the electrophilic center being the rate-determining step. Secondary alicyclic amines are found to be more reactive than isobasic primary amines. The Hammett plot for the reactions of 2a-f with morpholine is not linear, i.e., the substrate with a strong electron-donating group (e.g., 4-MeO) exhibits a negative deviation from the Hammett plot. However, the Yukawa-Tsuno plot for the same reactions exhibits an excellent linear correlation with ρ = 0.62 and r = 0.82. Thus, it has been proposed that the nonlinear Hammett plot is not due to a change in the ra te-determining step but due to ground-state stabilization through resonance interactions.

Antioxidant Effect of Monascus koji in Sausage Mixture

  • Rhyu, Mee-Ra
    • Preventive Nutrition and Food Science
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    • v.7 no.3
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    • pp.320-322
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    • 2002
  • The antioxidative capacity of Monascus koji was studied in raw bologna-type sausage by measuring thiobarbituric acid reactive substances (TBARS) and peroxide values (POV) during storage at $25^{\circ}C$ for 7 days. The addition of 2% Monascus koji effectively inhibited lipid oxidation in the mixture without vitamin C and NaNO$_2$, evidenced by its prevention of an increase in TBARS and a significantly reduction in increases in POV. Monascus koji in raw minced processed meat significantly improved the shelf life of the food.

Instrumental Characterization of Dyes and their Inorganic Additives (기기분석에 의한 염료 구조 및 무기배합제 조성에 대한 접근)

  • 최은경;이은경;조영달
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.139-142
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    • 2002
  • Color Index의 염료 분류 방법은 chemical type에 따라 25개 구조 분류(예로, 아조, 안트라퀴논, tryarylmethane 등) 그리고, 염료의 응용 범위에 따라 19개 속명(Acid, Direct, Disperse, Reactive 등)을 사용한다. 상품화되어 있는 수많은 염료는 현재 생산 회사의 상품명과 Color Index generic name을 보편적으로 사용하고 있으나, 체계적인 화학명은 복잡할 뿐 만 아니라, 상업적 이유로 많은 경우 밝히지 않고 있다. (중략)

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A Study on the Signal Anti-reduction Equipment in Power Line Communication (전력선 통신 시스템을 위한 신호 감쇠 저하 장치 연구)

  • 김주환
    • Proceedings of the KIPE Conference
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    • 2000.07a
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    • pp.103-106
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    • 2000
  • In this paper a communication system that is not using the communication line but power line is presented. It will be very useful for an information-oriented society with tele-metering and home automation. Conventional system has a difficulty in transmitting information due to decreasing communication voltage and increasing carrier, current. Proposed idea is a special type switching amplifier system which has a low inner resistance. It can provide reactive power and dose not have low impedance between the transceivers. This new system is proposed to overcome the loss of conductor load in a PLC system.

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Characteristic Analysis and Design Considerations of SLIM for Conveyer System (반송장치용 선형유도전동기의 특성해석 및 설계고찰)

  • 이철직
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.9 no.3
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    • pp.73-79
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    • 1995
  • This paper describes on the design considerations and analysis of moving primary-type linear induction motor for automatic conveyer system. For the study of the designed motor characteristics, calculated values obtained from the analysis using finite element method for various operation conditions are compared with the experimental results. Using the combined interactions of the thrust, the arigap flux density, and the reactive power at standstill as performance criteria, a proper ratio of the pole pitch to the effective airgap is presented for the design criterion.

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Fundamental study on Inverter-type Series and Shunt Compensator for Transmission System (송전계통의 인버터식 직.병렬 보상기에 관한 기초연구)

  • Han, Byung-Moon;Han, Hoo-Sek
    • Proceedings of the KIEE Conference
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    • 1999.11b
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    • pp.425-433
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    • 1999
  • This paper describes a simulation model and a scaled hardware model to analyze the dynamic performance of Unified Power Flow Controller, which can flexibly adjust the active and reactive power flow through the ac transmission line. The design of control system was developed using vector control method. The results of simulation and scaled hardware test show that the developed control system works accurately. And both models are very effective to analyze the dynamic performance of the Unified Power Flow Controller.

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RECENT DEVELOPMENT OF DC-TO-AC CONVERTERS FOR SMALL UPS SYSTEMS

  • Harada, Koosuke;Sakamoto, Hiroshi;Shoyama, Masahito
    • Proceedings of the KIEE Conference
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    • 1987.11a
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    • pp.21-24
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    • 1987
  • A novel type of the sinusoidal dc-to-ac converter is presented, where a pair of switches is placed in each side of the primary and the secondary of the isolation transformer. This converter is controlled by the phase difference between the two pairs of switches. As a result, the transformer is miniaturized by making the switching frequency high and the reactive energy can be easily recovered to the dc-source. This converter is especially suitable for small UPS systems.

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Microwave Wideband Constant Phase Shifter (마이크로파 광대역 정위상기)

  • Bae, Jung-Yi
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.23 no.2
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    • pp.182-188
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    • 1986
  • A method of wideband constant phase control is proposed. This can be applied to reflection type phase shifter with p-i-n diode. Using the proposed method, a microwave phase network which consists of a transmission line and reactive circuit element is suggested. By determining theproper values of design parameters, the desired wideband constant phase with different specification can easily be designed. Also, using the proposed method, the parameters variation, and 1.1 dB of insertion loss in the range of 12% bandwidth.

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Corrosion Inhibitors For Zinc in 2 M HCI Solution

  • A. S. Fouda;L. H. Madkour;A. A. El-Shafel;S. A. Abd ElMaksoud
    • Bulletin of the Korean Chemical Society
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    • v.16 no.5
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    • pp.454-458
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    • 1995
  • Inhibiting action of semicarbazide, thiosemicarbazide, sym. diphenylcarbazide towards corrosion of zinc in hydrochloric acid has been investigated. The rate of corrosion depends on the nature of the inhibitor and its concentration. The values of inhibition efficiency from, weight loss, thermometric measurements are in good agreement with those obtained from polarization studies. From the polarization studies, the inhibitors used act as mixed absorption type inhibitors, increased adsorption resulting from an increase in the electron density at the reactive C=S and C=O groups and N-atoms. The thermodynamic parameters of adsorption obtained using Bockris-Swinkels adsorption isotherm reveal a strong interaction of these carbazides on zinc surface.