• 제목/요약/키워드: reactive type

검색결과 807건 처리시간 0.03초

Sintering of Alloyed $Ni_3Al$ Starting from Mechano-composites Powders

  • Lucaci, Mariana;Orban, Radu L.;Lungu, Magdalena;Enescu, Elena;Gavriliu, Stefania
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1234-1235
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    • 2006
  • Considering the idea that some properties, especially the mechanical properties of $Ni_3Al$ at ambient temperature can be improved by adding of some substitutional/interstitial elements, our goal was to obtain these materials starting from mechano-composites powders. In this aim, using mechanical alloying techniques three type of mechano-composite powders starting from elemental powders were obtained. Then, by reactive sintering in argon atmosphere at temperature over $900^{\circ}C$, alloyed $Ni_3Al$ materials were realized. This paper presents our research results regarding the microstructural aspects and phase formation in obtained materials.

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6가 크롬의 환원과 발암 (Reduction of Chromium (Ⅵ) and Carcinogenesis)

  • 박형숙
    • Environmental Analysis Health and Toxicology
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    • 제18권3호
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    • pp.165-174
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    • 2003
  • Cr (Ⅵ) - containing compounds are well-established carcinogens, although the mechanism for chromium - induced carcinogenesis is still not well understood. The reduction of Cr (Ⅵ) to its lower oxidation states, par ticularly Cr (V) and Cr (IV), is an important step for the production of chromium-mediated reactive oxygen species (ROS). The persistent oxidative stress during the reduction process may play a key role in the mechanism of Cr (Ⅵ) -induced carcinogenesis. This paper summarizes recent studies on (1) the reduction of Cr (Ⅵ) to Cr (III) occur by a multiplicity of mechanisms depending on the nature of reducing agents including ascorbate, diol-and thiol-containing molecules, certain flavoenzymes, cell organelles, intact cells, and whole animals; (2) free-radical production with emphasis on hydroxy radical generation via Fenton or Haber-Weiss type reactions; and (3) free radical - induced cellular damage, such at DNA strand breaks, hydroxylation of 2'-deoxyguanosine, and activation of nuclear transcription factor kB.

염화물을 함유한 제설제가 콘크리트의 열 특성과 미끄럼저항성에 미치는 영향에 관한 연구 (Effect of Chloride-containing Deicer on the Thermal Charateristics and Skid Resistance of Concrete)

  • 이병덕;윤병성
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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    • pp.509-512
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    • 2004
  • This research is targeting that estimate the effect on cement concrete pavement with type of chloride deicers. In order to this study objective, when chloride deicers were spread on road surface, thermal characteristics test was conducted. Also, skid resistance test according to types and concentration of chloride deicier, road surface conditions were investigated. As a test results, thermal characteristics with kind of chloride deicier could know that sodium chloride(NaCl) is exothermic reactive material, calcium chloride$(CaCl_2)$ is endothermic reactive material. And, in case of mixed salt of the calcium and sodium chloride, it could know that can change to the exothermic or endothermic reaction according to dosage ratios. Skid value by British Pendulum Tester(BPT) has shown that it is seldom difference between the types($CaCl_2$, NaCl, mixed salt) and solution concentrations(0.5, 0.8, 1.0, 4.0, $10\%$) of chloride deicier comparing with tap water except mixed salt($10\%$ solution concentration).

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무효전력 제어에 의한 PCC전압 보상을 갖는 삼상 병렬형 능동전력필터 (A Three-Phase Parallel Active Power Filter Operating with PCC Voltage Compensation by Controlling Reactive Power)

  • 이우철;현동석;이택기
    • 대한전기학회논문지:전기기기및에너지변환시스템부문B
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    • 제49권3호
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    • pp.211-218
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    • 2000
  • The performance and dynamic characteristics of three-phase active power filter with PCC voltage compensation is presented and analyzed in this paper. The characteristics of parallel active filter are discussed when they are applied to nonlinear loads with current source and voltage source type, the characteristics of voltage compensator and comparison of two functions are discussed. The proposed scheme in this paper employs a PWM voltage-source inverter and has two operation modes. First, it operates as a conventional active filter with reactive power compensation while PCC voltage is in a certain range. Second, is operates as a voltage compensator while PCC voltage is out of range. Finally, the validity of this scheme is investigated through analysis of simulation and experimental results for a prototype active power filter system rated at 10KVA.

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이동로봇의 자율주행을 위한 행동기반의 퍼지 제어 (Behavior-Based Fuzzy Control of Mobile Robots for Autonomous Navigation)

  • 최현철;홍석교
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 하계학술대회 논문집 D
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    • pp.2464-2466
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    • 2001
  • In this paper, a behavior-based fuzzy control of mobile robots for autonomous navigation is presented. Behaviors of mobile robots are divided into two categories: reactive behavior and purposeful behavior, which are incompatible with each other. The former is reaction performed in terms of the sensory data and the latter is action for achieving the goal. The presented method generates appropriate control inputs to the robot to trade-off between the reactive and purposeful behaviors using fuzzy inferences. The method is applied to an synchro-drive type mobile robot and shown to be useful for autonomous robot navigation by providing simulation results.

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Kinetics and Mechanism for the Reaction of 4-Nitrophenyl 2-Furoate with Secondary Alicyclic Amines

  • 이종팔;윤지회;엄익환
    • Bulletin of the Korean Chemical Society
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    • 제20권7호
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    • pp.805-808
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    • 1999
  • Second-order-rate constants (kN) have been measured spectrophotometrically for the reactions of 4-nitrophenyl 2-furoate (1) with a series of secondary alicyclic amines in H2O containing 20 mole % DMSO at 25.0℃. 1 is about 5-8 times more reactive than 4-nitrophenyl benzoate (2), although 1 is expected to be less reactive than 2 based on MO calculations and 13 C NMR study. The Brфnsted-type plots for the aminolysis reactions of 1 and 2 are linear with βnuc values of 0.78 and 0.85, respectively. The replacement of the CH=CH group by an O atom in the acyl moiety (2->1) does not cause any mechanism change. The reaction of piperidine with a series of substituted phenyl 2-furoates gives a linear Hammett plot with a large ρ- value (ρ- = 2.88) when σ- constants are used. The linear Brфnsted and Hammett plots with a large ρ- value suggest that the aminolysis reaction of 1 proceeds via rate-determining break-down of the addition intermediate to the porducts.

Analytical Approach for Optimal Allocation of Distributed Generators to Minimize Losses

  • Kaur, Navdeep;Jain, Sanjay Kumar
    • Journal of Electrical Engineering and Technology
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    • 제11권6호
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    • pp.1582-1589
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    • 2016
  • In this paper the integration of Distributed Generation (DG) in radial distribution system is investigated by computing the optimal site and size of DG to be placed. An analytical expression based on equivalent current injection has been derived by utilizing topological structure of radial distribution system to find optimal size of DG to minimize losses. In the presented formulation, the optimal DG placement is obtained without repeatedly computing the load flow. The proposed formulation can be used to find the optimal size of all types of DGs namely Type-I, Type-II, Type-III and Type-IV DGs. The investigations are carried out on IEEE 33-bus and 69-bus radial distribution systems. The optimal DG placement results into reduction in active and reactive power losses and improvement in voltage profile of the buses.

Atomization Characteristics of a Double Impinging F-0-0-F Type Injector with Four Streams for Liquid Rockets

  • Kang, Shin-Jae;Rho, Byung-Joon;Oh, Je-Ha;Kwon, Ki-Chul
    • Journal of Mechanical Science and Technology
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    • 제14권4호
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    • pp.466-476
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    • 2000
  • This paper presents atomization characteristics of a double impinging F -0-0- F type injector with four streams. A phase Doppler particle analyzer was employed to measure the droplet-size and water was used as the inert simulant liquid instead of reactive propellant liquids. The droplet mean diameter (SMD) and size distribution were measured to investigate the effects of the momentum ratio and pressure drop variations. This experimental results can be used during the preliminary design stage of a impinging stream type injector for liquid rockets.

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입력전류의 검출이 없는 승압형 정류기의 고역률제어 (High-powerfactor Control of Boost-type Rectifier without input Current Sensing)

  • 배창한;이교범;송중호;이광운
    • 대한전기학회논문지:전기기기및에너지변환시스템부문B
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    • 제48권9호
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    • pp.510-516
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    • 1999
  • In this paper, a new high-powerfactor control method for boost-type rectifier is proposed, which removes the necessity of input current sensing. This method generates a sinewave duty template only from the line voltage waveform and rectifier output, and reduces reactive power remarkably utilizing three compensation coefficients which are determined through experiments. These compensations make the input current to be in phase with the input voltage all over the load range. A prototype boost-type rectifier is designed and experimental results are presented.

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Rear Surface Passivation of Silicon Solar Cell with AlON Layer by Reactive Magnetron Sputtering

  • Moon, Sun-Woo;Kim, Eun-Kyeom;Park, Won-Woong;Kim, Kyung-Hoon;Kim, Sung-Min;Kim, Dong-Hwan;Han, Seung-Hee
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.430-430
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    • 2012
  • The surface recombination velocity of the silicon solar cell could be reduced by passivation with insulating layers such as $SiO_2$, SiNx, $Al_2O_3$, a-Si. Especially, the aluminium oxide has advantages over other materials at rear surface, because negative fixed charge via Al vacancy has an additional back surface field effect (BSF). It can increase the lifetime of the hole carrier in p-type silicon. The aluminium oxide thin film layer is usually deposited by atomic layer deposition (ALD) technique, which is expensive and has low deposition rate. In this study, ICP-assisted reactive magnetron sputtering technique was adopted to overcome drawbacks of ALD technique. In addition, it has been known that by annealing aluminium oxide layer in nitrogen atmosphere, the negative fixed charge effect could be further improved. By using ICP-assisted reactive magnetron sputtering technique, oxygen to nitrogen ratio could be precisely controlled. Fabricated aluminium oxy-nitride (AlON) layer on silicon wafers were analyzed by x-ray photoelectron spectroscopy (XPS) to investigate the atomic concentration ratio and chemical states. The electrical properties of Al/($Al_2O_3$ or $SiO_2/Al_2O_3$)/Si (MIS) devices were characterized by the C-V measurement technique using HP 4284A. The detailed characteristics of the AlON passivation layer will be shown and discussed.

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