• 제목/요약/키워드: reactive influence

검색결과 315건 처리시간 0.022초

초소수성 표면 개질에 미치는 마이크로 나노 복합구조의 영향 (The Effect of Micro Nano Multi-Scale Structures on the Surface Wettability)

  • 이상민;정임덕;고종수
    • 대한기계학회논문집A
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    • 제32권5호
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    • pp.424-429
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    • 2008
  • Surface wettability in terms of the size of the micro nano structures has been examined. To evaluate the influence of the nano structures on the contact angles, we fabricated two different kinds of structures: squarepillar-type microstructure with nano-protrusions and without nano-protrusions. Microstructure and nanostructure arrays were fabricated by deep reactive ion etching (DRIE) and reactive ion etching (RIE) processes, respectively. And plasma polymerized fluorocarbon (PPFC) was finally deposited onto the fabricated structures. Average value of the measured contact angles from microstructures with nanoprotrusions was $6.37^{\circ}$ higher than that from microstructures without nano-protrusions. This result indicates that the nano-protrusions give a crucial effect to increase the contact angle.

기판바이어스 인가에 따른 반응성 마그네트론 스퍼터링에 의한 TiN 코팅 (TiN Coatings by Reactive Magnetron Sputtering Under Various Substrate Bias Voltages)

  • 서평섭;전성용
    • 한국표면공학회지
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    • 제41권6호
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    • pp.287-291
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    • 2008
  • Reactively magnetron sputtered TiN films were deposited on Si wafers under varying bias voltage and characterized by X-ray diffraction, field-emission scanning electron microscopy and Nanoindentation. The films deposited under an Ar + $N_2$ atmosphere exhibited a mixed (200)-(111) orientation with a strong (200) texture, which subsequently changed to a strong (111) texture with increasing bias voltage. The changes in texture and grain size of the TiN thin films are due to one or a combination of factors such as strain energy, surface free energy, surface diffusivity and adatom mobility. The influence of each factor depends on the processing conditions. The average deposition rate and grain size were calculated from FE-SEM images of the films indicating that the deposition rate was lower at the films deposited under bias voltage.

산화물 및 비산화물 Microfiller의 첨가가 저시멘트 알루미나 캐스타블의 특성에 미치는 영향 (Influence of Various Oxide and Nonoxide Microfillers on the Thermomechanical Properties of Alumina Based Low-Cement-Castables)

  • 이승재;이상원
    • 한국세라믹학회지
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    • 제32권9호
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    • pp.977-988
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    • 1995
  • Several oxide (ZrO2, Al2TiO5, reactive Al2O3) and nonoxide (SiC, Si3N4, "ALON" (5AlN.9Al2O3)) additives were used as a microfiller for alumina based LCC (Low-Cement-Castable). High temperature prooperties (HMOR, softening under load) and the phase changes of developed LCC on various sintering temperatures were examined. In addition, thermal shock test and corrosion test were accomplished. Based on these data the effects of each microfiller on the properties of LCC were established comparing to those of the commercial LCC with amorphous silica as a microfiller. The castables, containing reactive alumina, ZrO2 and "ALON" (5AlN.9Al2O3) as a first portion, exhibited considerably higher HMOR-values over 100$0^{\circ}C$, better creep behavior, and thermal shock resistance than those of castables with amorphous silica. The LCC with 5% Al2TiO5 showed no corrosion against molten aluminum.nst molten aluminum.

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비대칭 펄스 DC 반응성 마그네트론 스퍼터링으로 증착된 나노결정질 TiN 박막의 성장거동 (Growing Behavior of Nanocrystalline TiN Films by Asymmetric Pulsed DC Reactive Magnetron Sputtering)

  • 한만근;전성용
    • 한국세라믹학회지
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    • 제48권5호
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    • pp.342-347
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    • 2011
  • Nanocrystalline TiN films were deposited on Si(100) substrate using asymmetric pulsed DC reactive magnetron sputtering. We investigated the growing behavior and the structural properties of TiN films with change of duty cycle and pulsed frequency. Grain size of TiN films were decreased from 87.2 nm to 9.8 nm with decrease of duty cycle. The $2{\theta}$ values for (111) and (200) crystallographic planes of the TiN films were also decreased with decrease of duty cycle. This shift in $2{\theta}$ could be attributed to compressive stress in the TiN coatings. Thus, the change of plasma parameter has a strong influence not only on the microstructure but also on the residual stresses of TiN films.

모터부하 특성에 따른 국내 전력계통의 전압 지연 회복 현상 분석 (An Analysis of Delayed Voltage Recovery Phenomenon according to the Characteristics of Motor Load in Korean Power System)

  • 이윤환
    • 전기학회논문지P
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    • 제65권3호
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    • pp.178-182
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    • 2016
  • FIDVR(Fault Induced Delayed Voltage Recovery) is a phenomenon that recovery of the system voltage level delays after the fault. Cause of FIDVR phenomenon is motor load characteristic about voltage and reactive power. In low voltage condition, the motor go to stall state that consume large amount of reactive power. As a result, the voltage recovery problem is that of repeated occurrences of sustained low voltage following faults on the system. In this paper, analysis the characteristics of the motor load. And using the korean power system actual data, perform a case studies to voltage delay recovery phenomenon alleviation method. Change of each parameters by analyzing the effect on system and selecting an influence parameter. In addition, dynamic characteristic analysis of the resulting difference in the proportion by the motor load in power systems, considering the effect on the voltage stability.

Penicillium janthinellum 균체를 이용한 생물흡착에 의한 염료의 제거 (Removal of Dyes by the Biosorption Using Biomass of Penicillium janthinellum)

  • 이제혁;전억한
    • KSBB Journal
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    • 제14권1호
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    • pp.31-35
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    • 1999
  • Penicillium janthinellum의 생균체와 변형 균체를 사용한 azo와 reactive계 염료의 생흡착에 대한 연구가 수행되었다. 반응액의 pH가 초기 흡착율과 탈색에 영향을 주어, 최적 pH는 3.0이었으며, 최적 온도는 $40^{\circ}C$이었다. Reactive계 염료인 Apollocion Red 7EB와 Apollfix Red SF-3B와 Apollocion Red HE-3B는 각각 초기 흡착율이 0.06, 0.086, 0.07mg/g.mm이었다. Azo와 reactive 계 염료들을 함유한 혼합염료도Pen janthinellum 균체에 흡착되어 0.084mg/g.min의 초기 흡착율을 보였다. Detergent 첨가시 탈색 백분율과 초기 흡착율은 대조군의 경우보다 낮았다. 또한 이온의 첨가는 염료의 흡착율에 영향을 미치지 않았다 Pen janthinellum의 변형 균체도 염료의 흡착율을 보였고, Apollocion Red 7EB의 흡착에 있어 이온교환수지보다 월등한 흡착능을 보였다.

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DC Reactive Magnetron Sputtering법에 의한 Ti-Al-V-N 박막의 성장거동 (Growth behavior of Ti-Al-V-N Films Prepared by Dc Reactive Magnetron Sputtering)

  • 손용운;정인화;이영기
    • 한국재료학회지
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    • 제9권7호
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    • pp.688-694
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    • 1999
  • Ti-6Al-4V 합금을 타겟트로 사용하여 유리 기판위에 dc reactive magnetron sputtering법으로 $N_2$/(Ar+N_2)$ 비, 기전력 및 시간등의 여러 가지 증착 조건에서 Ti-6Al-4V-N 필름을 증착하였고, 각각의 증착 조건에 따른 결정구조 및 우선방위 거동은 X-선 회절장치를 사용하여 조사하였다. Ti-6Al-4V-N 필름은 본질적으로 fcc 결정구조의 $\delta$-TiN에 Al과 V이 결함으로서 고용된 변형된 형태의 $\delta$-TiN구조이고, TiN의 격자상수(4.240 )보다 작은 값을 나타내었는데, 이는 Ti(1.47 )에 비하여 상대적으로 원자반경이 작은 Al(1.43 )과 V (1.32 )이 Ti의 격자위치에 치환된 결과이다. 그리고 Ti-6Al-4V-N 필름은 $_N2$가스 분압이 감소됨에 따라 (111) 우선방위 성장거동을 하였을 뿐만아니라 증착시간의 증가에 따라 뚜렷한 (111) 우선방위 성장거동을 나타내었다. 그리고 증착속도 및 결정입도의 거동 또한 여러 가지 증착 조건에 크게 의존한다

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신경세포가 별아교세포의 아교섬유성 산단백질 표현에 미치는 영향 (Effect of Glial-neuronal Cell Co-culture on GFAP Expression of Astrocytes)

  • 배형미;박정선;연동수
    • The Korean Journal of Physiology and Pharmacology
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    • 제1권3호
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    • pp.285-296
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    • 1997
  • Injury to brain transforms resting astrocytes to their reactive form, the hallmark of which is an increase in glial fibrillary acidic protein (GFAP), the major intermediate filament protein of their cell type. The overall glial response after brain injury is referred to as reactive gliosis. Glial-neuronal interaction is important for neuronal migration, neurite outgrowth and axonal guidance during ontogenic development. Although much attention has been given to glial regulation of neuronal development and regeneration, evidences also suggest a neuronal influence on glial cell differentiation, maturation and function. The aim of the present study was to analyze the effects of glial-hippocampal neuronal co-culture on GFAP expression in the co-cultured astrocytes. The following antibodies were used for double immunostaining chemistry; mouse monoclonal antibodies for confirm neuronal cells, rabbit anti GFAP antibodies for confirm astrocytes. Primary cultured astrocytes showed the typical flat polygonal morphology in culture and expressed strong GFAP and vimentin. Co-cultured hippocampal neurons on astrocytes had phase bright cell body and well branched neurites. About half of co-cultured astrocytes expressed negative or weak GFAP and vimentin. After 2 hour glutamate (0.5 mM) exposure of glial-neuronal co-culture, neuronal cells lost their neurites and most of astrocytes expressed strong CFAE and vimentin. In Western blot analysis, total GFAP and vimentin contents in co-cultured astrocytes were lower than those of primary cultured astrocytes. After glutamate exposure of glial-neuronal co-culture, GFAP and vimentin contents in astrocytes were increased to the level of primary cultured astrocytes. These results suggest that neuronal cell decrease GFAP expression in co-cultured astrocytes and hippocampal neuronal-glial co-culture can be used as a reactive gliosis model in vitro for studying GFAP expression of astrocytes.

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고호모시스테인혈증 임신 흰쥐에서 엽산보충이 혈장 호모시스테인, Thiobarbituric Acid Reactive Substances (TBARS) 수준과 간의 SAM/SAH에 미치는 영향 (Effects of Folio Acid Supplementation on Plasma Homocysteine and Thiobarbituric Acid Reactive Substances (TBARS) Levels and Liver SAM/SAH Ratio in Hyperhomocysteinaemia-induced Pregnant Rats)

  • 홍경주;현태선;장남수
    • Journal of Nutrition and Health
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    • 제38권7호
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    • pp.495-502
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    • 2005
  • This study was performed to investigate effects of dietary folic acid supplementation on plasma homocysteine levels, thiobarbituric acid reactive substance s (TBARS) level s and liver SAM/SAH ratio in hyperhomocysteinaemia-induced pregnant rats. Forty-two female Sprague-Dawley rats were divided three groups (C: control diet, HFD: $0.3\%$ homocystine and 0 mg folic acid diet, HFS: $0.3\%$ homocystine and 8 mg/kg folic acid diet) according to homocystine and folic acid levels in the diet. They were fed experimental diets for 5 weeks prior to the mating and also during the entire period of pregnancy till gestational day 20. Dietary folic acid supplementation caused a significant decrease in plasma homocysteine levels which had been increased by a homocystine-diet, with a concomitant increase in plasma and liver folate levels. Liver TBARS levels in homocysteine-folic acid-deficient group (HFD) were higher than those in control group. Dietary folic acid supplementation increased hepatic SAM/SAM ratio in homocysteine-folic acid- sopplemetantion group (HFS) when compared to the HFD (p < 0.05). These data suggest that folate depletion and elevated plasma homocysteine may promote oxidative stress in rat livers and influence the remethylation cycle of the homocysteine metabolism detrimentally. In conclusion, dietary folic acid supplementation was found to be effective for lowering plasma homocysteine levels, relieving oxidative stress, and improving the methylation status in the body.

염소계 유기화합물로 오염된 지하수의 반응성 투과 벽체 처리 효율에 대한 온도의 영향 (Influence of Temperature on the Treatment Efficiency of Chlorinated Organic Substances in Groundwater by Permeable Reactive Barrier)

  • 김선혜;김은지;김동수
    • 한국물환경학회지
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    • 제30권2호
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    • pp.175-183
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    • 2014
  • The influence of temperature on the treatment efficiency of chlorinated organic substances contained in groundwater by permeable reactive barrier which is composed of $Fe^{\circ}$ has been investigated by constructing the Pourbaix diagrams for Fe-$H_2O$ system at different temperatures based on thermodynamic estimation. In aerobic condition, the equilibrium potentials for $Fe^{\circ}/Fe^{2+}$ and $Fe^{2+}/Fe^{3+}$ were observed to increase, therefore, the dechlorination reaction for organic pollutants by $Fe^{\circ}$ was considered to decline with temperature due to the diminished oxidation of reactive barrier. The result for the variations of the ionization fraction of $Fe^{2+}$ and $Fe^{3+}$ ion in the pH range of 0 ~ 2.5 obtained by employing Visual MINTEQ program showed that the ionization fraction of $Fe^{2+}$ increased with pH, however, that of $Fe^{3+}$ decreased symmetrically and the extent of the variation of ionization fraction for both ions was raised as temperature rises. The equilibrium pH for $Fe^{3+}/Fe(OH)_3$ was examined to decrease with temperature so that the treatment efficiency of chlorinated organic substance was expected to decrease with temperature due to the enhanced formation of passivating film in aerobic condition. The change of the reactivity of a specific chemical species with temperature was defined quantitatively based on the area of its stable region in Pourbaix diagram and depending on this the reactivity of $Fe^{3+}$ was shown to decrease with temperature, however, that of $Fe(OH)_3$ was decreased monotonously as temperature is raised for $Fe^{3+}/Fe(OH)_3$ equilibrium system. In anaerobic condition, the equilibrium potential for $Fe^{\circ}/Fe^{2+}$ was observed to rise and the equilibrium pH for $Fe^{2+}/Fe(OH)_2$ were examined to decrease as temperature increases, therefore, similar to that for aerobic condition the efficiency of the dechlorination reaction for organic substances was considered to be diminished when temperature rises because of the reduced oxidation of $Fe^{\circ}$ and increased formation of $Fe(OH)_2$ passivating film.