• Title/Summary/Keyword: reaction-diffusion modeling

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Mathematical Modeling for Leaching and dissolution of Solidified Radioactive Waste in a Geologic Reposiory (지하 처분장에서의 방사성폐기물 고화체의 용출 및 용해에 대한 수학적 모형 분석)

  • Kim, Chang-Lak;Park, Kwang-Sub;Cho, Chan-Hee;Kim, Jhinwung;Suh, In-Suk
    • Nuclear Engineering and Technology
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    • v.20 no.2
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    • pp.120-131
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    • 1988
  • A souce term model describes mathematically the source of radionuclides as they begin slow migration and decay in deep groundwater. Various source term models based on mass-transfer analysis and measurement-based source term models are reviewed. Ganerally, two processes are involved in leaching or dissolution: (1) chemical reactions and (2) mass transfer by diffusion. The chemical reaction controls the dissolution rates only during the early stage of exposure to groundwater. The exterior-field mass transfer may control the long term dissolution rates from the waste solid in a geologic repository. Mass-transfer analyses re3y on detailed and careful application of the governing equations that describe the mechanistic processes of transport of material between and within phases. If used correctly, source term models based on mass-transfer theory are valuable and necessary tools for developing reliable predictions.

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A Study on Analysis Technique for Chloride Penetration in Cracked Concrete under Combined Deterioration (복합열화에 노출된 균열부 콘크리트 내의 염화물 침투 해석 기법에 대한 연구)

  • Kwon, Seung-Jun;Song, Ha-Won;Byun, Keun-Joo
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.359-366
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    • 2007
  • Recently, analysis researches on durability are focused on chloride attack and carbonation due to increased social and engineering significance. Generally, chloride penetration and carbonation occur simultaneously except for in submerged condition and chloride behavior in carbonated concrete is evaluated to be different from that in normal concrete. Furthermore, if unavoidable crack occurs in concrete, it influences not only single attack but also coupled deterioration more severely. This is a study on analysis technique with system dynamics for chloride penetration in concrete structures exposed to coupled chloride attack and carbonation through chloride diffusion, permeation, and carbonation reaction. For the purpose, a modeling for chloride behavior considering diffusion and permeation is performed through previous models for early-aged concrete such as MCHHM (multi component hydration heat model) and MPSFM (micro pore structure formation). Then model for combined deterioration is developed considering changed characteristics such as pore distribution, saturation and dissociation of bound chloride content under carbonation. The developed model is verified through comparison with previous experimental data. Additionally, simulation for combined deterioration in cracked concrete is carried out through utilizing previously developed models for chloride penetration and carbonation in cracked concrete. From the simulated results, CCTZ (chloride-carbonation transition zone) for evaluating combined deterioration is proposed. It is numerically verified that concrete with slag has better resistance to combined deterioration than concrete with OPC in sound and cracked concrete.