• The Journal of Internal Korean Medicine
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• v.31 no.4
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• pp.846-856
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• 2010

Objective : Allergic disease, a very common chronic illness that affects all ages of patients, has been well characterized as an IgE-dependent immunologic response. Recently, interest has grown about the late inflammatory reaction as well as the early one characterized by IgE and mast cells in allergic disease. The purpose of this study was to find the anti-inflammatory effect of Taeeumjowui-tang (Taiyintiaowei-tang) in allergic reaction. Methods : The experiment was performed using Raw 264.7 cells pretreated with Taeeumjowui-tang contents extracts. The results were measured for different concentrations of Taeeumjowui-tang extracts (100, 200, $300{\mu}g$/ml): the toxicity and proliferation of cells by MTT analysis, LPS-induced NO production using Griess reagent and IL-6/ TNF-${\alpha}$ production, which is a significant criteria for diagnosing allergic reaction. Results : No toxicity of Taeeumjowui-tang (100, 200, $300{\mu}g$/ml) on Raw 264.7 cells was found after 24 hours incubation. LPS-induced NO production was reduced after treatment with Taeeumjowui-tang (100, 200, $300{\mu}g$/ml)(P<0.001). IL-6 decreased only at $100{\mu}g$/ml(P<0.05). TNF-${\alpha}$ production decreased only at $300{\mu}g$/ml, but still statistically insignificant. There was no relationship between any components of Taeeumjowui-tang alone and inhibition of NO production. Conclusions : These data suggest that Taeeumjowui-tang has anti-inflammatory effects in allergic reaction.

• Journal of agricultural medicine and community health
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• v.5 no.1
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• pp.40-45
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• 1980

Paragonomiasis is a common trematodiasis of medical importance and one of public health. problems in many araes af southern part of Korea. Authars carried out the survey for human paragonimiasis in Ung Chi Myun, Bo Sung Gun during 1968 to 1979 by the use of intradermal screening test with veronal buffered saline antigens. In 1968 and 1978, inhabitants of all age groups in Ung Chi Myun were examined. In 1979, 1, 119 consisting of primary school children and middle school students in Ung Chi Myun and 521 high school students in Beol Gyo Eup were examined. The following results were obtained in this survey. 1) In 1968, 136 inhabitants were showed 61.0% positive reaction (66.3% in male, 53.6% in female). The positive rates were similar in each age groups. 2) In 1978, 207 Inhabitants were showed 32.9% positive reaction (36.3% in male, 29.4% in female). The positive rate was shown as high as 30% in the age groups of over 10 years old. 3) In 1979, primary school children and middle school students in Ung Chi Myun were showed 15.8% positive reaction and high school students in Beol Gyo Eup were showed 6.9% positive reaction.

• Analytical Science and Technology
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• v.17 no.3
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• pp.225-229
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• 2004

The effect of the silicon acrylate as a reactive additive on the UV-curing photopolymerization reaction was studied by micro raman technique. For the study, acrylate systems and Darocur 1173 were used as oligomer and monomers, and a photo initiator, respectively. The content of silicon acrylate was within the range of 0-3 wt%. The extent of photo-polymerization reaction as a function of depth from the air interface was obtained from the conversion ratio of acrylate double bond calculated from the intensities of measured bands at $1410cm^{-1}$ and at $1635cm^{-1}$. Micro raman spectroscopic technique can be an useful tool for the investigation of the factors, which can affect the reaction progress, such as oxygen inhibition, composition of the formulations, depth, etc.

• Journal of the Korean Chemical Society
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• v.32 no.4
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• pp.291-296
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• 1988

Rates of the reaction for p-nitrobenzyl chloride, benzyl chloride and p-methylbenzyl chloride with pyridine in DMF solvent have been measured by an electric conductivity method at $40^{\circ}\;and\;50^{\circ}C$ under various pressures. From those rate constants, the activation parameters ${\Delta}V^{\neq},\;{\Delta}{\beta}^{\neq},\;{\Delta}H^{\neq},\;{\Delta}S^{\neq},\;{\Delta}G^{\neq}$) were evaluated. ${\Delta}V^{\neq}\;and\;{\Delta}{\beta}^{\neq}$ are both negative valued, but ${\Delta}H^{\neq}$ is positive and ${\Delta}S^{\neq}$ is large negative value. From the evaluation of the initial state and transition state which was resulted from substituents and pressure, it was found that this reaction proceeds through bimolecular reaction.

• Archives of Pharmacal Research
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• v.29 no.9
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• pp.721-727
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• 2006

To continue exploration of structure activity relationship of novel 1-(indoline-5-sulfonyl)-4-phenylimidazolidinones (1) reported as anticancer agent with broad spectrum, three 1-(arylsulfonyl)-4-vinylimidazolidinones (2) were synthesized from methyl serinate (3) in 8 steps. Reaction of intermediate 2-phenoxycarbonylaminobut-3-enyl p-toluenesulfonate (10) with arylsulfonamide in the presence of potassium carbonate produced corresponding 2 and N-(4-vinyloxazolidin-2-yl)arylsulfonamide 11 in approximately equal ratio. This reaction is believed to undergo through urea intermediate 16 as shown in scheme 3. 1-Arylsufonyl-4-vinylimidazolidinones 2 show much reduced activity against human colon carcinoma (Colo205), human chronic myelogenous leukemia (K562), and human ovarian adenocarcinoma (SK-OV-3) and compatible activity against human lung carcinoma (A549) compared to 1. Therefore phenyl at 4-position should be the optimum planar motif for the activity of 1.

• Korean Journal of Materials Research
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• v.9 no.5
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• pp.467-472
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• 1999

The isothermal cure behavior of diglycidyl ether of bisphenol A(DGEBA) 4,4'-methylene dianiline(MDA) system with various contents of neopentyl glycol(NPG) has been analyzed by differential scanning calorimetry(DSC). TO increase the cure rate of DGEBA/MDA system, NPG was introduced as an accelerator. Regardless of the NPG content, the shape of the conversion curves showed sigmoid indication that DGEBA/MDA/NPG system followed autocatalytic cure reaction. The cure reaction of DGEBA/MDA system increased with the increment of NPG content and it was due to the catalytic role of hydroxyl groups of NPG.

• Korean Journal of Applied Biomechanics
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• v.20 no.2
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• pp.205-212
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• 2010

The purpose of this study was to compare the efficiency of visual perception and impulse according to the three types of Taekwondo players to be able to supply an efficient training method, for this a total of 12 representative Taekwondo players of the Korean National team, 4 poomsae players, 4 kyokpa players and 4 kyorugi players weighting between 68 to 74 kg, and the results from the motion analysis system, eye tracker and Electronic hogu are as follows. For the visual perceptual function, the total body reaction time was slowest for the kyokpa group, and for the visible reaction and vision fixation time was longest of the poomsae group, while the performance movement was fastest for the kyorugi group. As for description of the two kicking motions dollyo chagi and dolgae chagi the longer visual fixation helps the accuracy of the kick. In conclusion, as there was a difference between the groups, this information could help to train the visual perception of players according to what event they are participating in.

• Journal of the Korean Chemical Society
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• v.40 no.5
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• pp.327-332
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• 1996

The rates of solvolylsis of methyl chloroformate, phenyl chloroformate and 1-adamantyl derivatives in binary solvent mixtures have been measured by conductometric method at various temperatures and pressures. The activation parameters were estimated from the rate constants. The activation volume (${\Delta}V_o^{\neq}$) and the activation entropy (${\Delta}S^{\neq}$) are both negative, but the activation enthalpy (${\Delta}H^{\neq}$) is positive. This behavior is discussed in terms of electrostriction of solvation. The reactivities of these reactions were also estimated from the correlation of the activation volumes with the activation entropies. From these results, it could be estimated that the solvolyses of 1-adamantyl fluoroformate (in aqueous TFE) and 1-adamantyl tosylate have pathway involving unimolecular reaction, while the reaction of methyl chloroformate, phenyl chloroformate and 1-adamantyl fluoroformate (in aqueous alcohol) proceed through a bimolecular reaction.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.1
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• pp.41-52
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• 2021

NiO and Co3O4-doped porous La(CoNi)O3 perovskite oxides were prepared from excess Ni addition by a hydrothermal method using porous silica template, and characterized as bifunctional catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) for Zn-air rechargeable batteries in alkaline solution. Excess Ni induced to form NiO and Co3O4 in La(CoNi)O3 particles. The NiO and Co3O4-doped porous La(CoNi)O3 showed high specific surface area, up to nine times of conventionally synthesized perovskite oxide, and abundant pore volume with similar structure. Extra added Ni was partially substituted for Co as B site of ABO3 perovskite structure and formed to NiO and Co3O4 which was highly dispersed in particles. Excess Ni in La(CoNi)O3 catalysts increased OER performance (259 mA/㎠ at 2.4 V) in alkaline solution, although the activities (211 mA/㎠ at 0.5 V) for ORR were not changed with the content of excess Ni. La(CoNi)O3 with excess Ni showed very stable cyclability and low capacity fading rate (0.38 & 0.07 ㎶/hour for ORR & OER) until 300 hours (~70 cycles) but more excess content of Ni in La(CoNi)O3 gave negative effect to cyclability.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.8
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• pp.1089-1096
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• 2003

An experiment was performed to investigate lift-off, blow-off and combustion characteristics of a lifted coaxial diffusion flame according to fuel jet and air velocity. A jet diffusion flame which is attached on the nozzle rim begins to be lifted with increase of air velocity, and finally becomes blow-off at higher air velocity. In experiment, blow-off limit increased with increase of fuel jet velocity, however lift-off occurred at lower air velocity. Flame structure and combustion characteristics were examined by schlieren photos, temperature distributions and emission concentration distributions. Flame temperature became higher at midstream and its RMS became larger at up and downstream with increase of air velocity. Local NO concentration decreased but $CO_2$concentration increased with increase of air velocity, which shows combustion reaction becomes close to be stoichiometric at higher air velocity in spite of lift-off.