• Bulletin of the Korean Chemical Society
• /
• v.31 no.7
• /
• pp.1956-1962
• /
• 2010

The formation of diverse spiral waves was studied in a polyacrylamide gel membrane with ruthenium(4-vinyl-4'-methyl-2,2'-bipyridine)bis(2,2'-bipyridine)bis(hexafluorophosphate) by a gas-free Belousov-Zhabotinisky (BZ) reaction system containing 1,4-cyclohexanedione (1,4-CHD). The gel membrane was found to be receptive for observing propagating waves since a clearer wave-train is obtained during a long reaction time without any disturbance from the immobilized metal catalyst which can be dissolved into the highly acidic solution of the BZ system. The distinctive waves in the system basically depend on both $BrO_3$ and 1,4-CHD in the initial phase, and are influenced by the intensity of illumination of visible light.

• Journal of Korean Society for Atmospheric Environment
• /
• v.17 no.1
• /
• pp.97-104
• /
• 2001

Decomposition of trichloroethlyene(TCE) in electron beam irradiation was examined on order to obtain information on the treatment of VOC in air. Air containing vaporized TCE has been studied in a flow reactor with different reaction environments, at various initial TCE concentration and in the presence and absence of water vapor. Maximum decomposition was observed in oxygen reaction environment and the degree of decomposition was about 99% at 20kGy for 2,000ppm initial TCE. The concentration of TCE exponentially decreased with dose in air and pure oxygen. The effect of water vapor on TCE decomposition efficiency was examined. The decomposition rate of TCE in the presence of water vapor (5,600 ppm) was approximately 10% higher than that in the absence of water vapor. Dichloroacetic acid, dichloroacethyl chloride and dichloroethyl ester acid were identified as primary products of this reaction adn were decomposed and oxidized to yield CO and $CO_2$. Perchloroethylene, hexachloroethane, chloroform and carbon tetrachloride were also observed as highly chlorinat-ed by products.

• Journal of the Korean Applied Science and Technology
• /
• v.17 no.2
• /
• pp.113-119
• /
• 2000

Alkylation of phenol with tert-butanol in the liquid phase on mordenite was studied. The influence of many reaction parameters such as calcination temperature, reaction temperature, t-butanol/phenol molar ratio on catalytic properties was discussed. The main products were 2,4-di-t-butylphenol, o-t-butylphenol, p-t-butylphenol, the last of these was wanted product. In order to enhance the selectivity of p-t-butylphenol, optimum conditions were recommended at $500^{\circ}C$ calcination temperature, $140^{\circ}C$ reaction temperature, 1.0 molar ratio of reactants over mordenite. P-t-butylphenol was formed with 90% isomer selectivity at optimum conditions after 4hr reaction. On the basis of the behavior obtained in the cases mentioned, optimum conditions and catalytic properties for t-butylation of phenol were provided.

• Resources Recycling
• /
• v.27 no.5
• /
• pp.3-8
• /
• 2018

Acid-base reaction together with oxidation-reduction reaction is an important reaction occurring in the aqueous phase. The definition by Lewis on the acid and base is more comprehensive than several definitions. HSAB theory has been introduced to consider the difference in the reactivity among the acids/bases. In this paper, several acid-base reactions were analyzed by applying the definition of acid and base. Moreover, the background of the introduction of HSAB and its application was explained.

• Proceedings of the Polymer Society of Korea Conference
• /
• 2006.10a
• /
• pp.375-375
• /
• 2006

The preparation methods are to be used as "melting method" and "absorption method", respectively. The reaction mixture in the reaction container was heating up the reaction mixture to $200^{\circ}C$ for 2 hour. The mixing time of lab scale preparation should be provided quit long, instead of the short working time in a compounder vessel. And The PP-PCM mixture in the reaction container was heating up the mixture around $60-80^{\circ}C$ for 2 hour. A melting method of frozen gel with 50/50 weight ratio of polypropylene-normal octadecane was prepared by adding PP chip and normal octadecane. An absorption method of frozen gel with 70/30 weight ratio of PP 4.8-normal n-octadecane was prepared by adding PP powder and normal octadecnae.

• Journal of the Korean Ceramic Society
• /
• v.32 no.1
• /
• pp.37-44
• /
• 1995

TiO2 fine powders were synthesized using oxygenolysis and hydrolysis reaction of TiCl4 vapor in gas phase. The TiO2 powder synthesized showed morphological differences depending on reaction system as follows: TiCl4-O2 reaction system produced the monosized particles having polyhedral shape with well-defined crystal planes and the particles did not agglomerate into secondary particles. TiCl4-H2O reaction system, whereas, produced the spherical secondary particles which consisted of fine primary particles. Other powder characteristics such as particle size, impurity content and rutile content are also reported in this study.

• Journal of Aerospace System Engineering
• /
• v.10 no.1
• /
• pp.74-81
• /
• 2016

Space propulsion system produces required thrust for satellites and space launch vehicles by using chemical reactions of a liquid fuel and a liquid oxidizer typically. Among several liquid propellants, the monomethylhydrazine-dinitrogen tetroxide is expecially preferred for a GEO satellite propellants due to their better storability in liquid phase during a long mission life under a freezing space environment. Recently, a development of the monomethylhydrazine-dinitrogen tetroxide bipropellant system becomes important as the national space program requires the heavier and the more efficient space system. Thus, the objective of the present study is to review a foreign research trend of a chemical reaction between the monomethyhydrazine fuel and the dinitrogen tetroxide oxidizer to understand a fundamental basis of their characteristics to prepare for domestic development in future.

• Journal of Power System Engineering
• /
• v.5 no.4
• /
• pp.74-81
• /
• 2001

The infiltration behavior of molten Al-alloy, microstructures, hardness, and the interfacial reactions of $SiC_p/Al$ composites fabricated by the pressureless infiltration technique were investigated. It was made clear that both the weight fraction of SiC reinforcement and additive Mg content considerably influenced on the infiltration behavior of the molten Al-alloy matrix. Complete infiltration of molten Al-alloy achieved under the conditions that weight fraction of SiC content is more than 30wt%, and additive Mg content is more than 9wt%. Interfacial region of Al-alloy matrix and SiC reinforcement phase, $Mg_2Si$ was formed by the reaction between Mg and SiC. Another reaction product AlN was also formed by the reaction between Al-alloy matrix and gas atmosphere nitrogen.

• Journal of Powder Materials
• /
• v.6 no.2
• /
• pp.139-144
• /
• 1999

The pure Ti, Ni and carbon powders were reaction milled to synthesize the TiC-Ni based cermet powders with ultrafine microstructures. After milling, the ultrafine TiC or amorphous Ti-Ni phase was obtained, respectively, according to the milling condition. The effects of milling variables on the synthesizing behavior of the powders were investigated in detail. The sintered TiC-Ni based cermet of the reaction milled powders consisted of very fine TiC of 0.2~1.5$\mu$m, as compared with that of a commercial cermet of 3~5$\mu$m. This demonstrates the potenial of reaction milling as an effective processing route for the preparation of cermet materials.

• Korean Journal of Metals and Materials
• /
• v.46 no.4
• /
• pp.227-232
• /
• 2008

Solvent extraction reaction of cobalt by Alamine336 from strong hydrochloric acid solution was identified by analyzing the solvent extraction data reported in the literature. Analysis of the data by graphical method revealed that Alamine336 took part in the solvent extraction reaction as a monomer in the concentration ranges, [Co(II)] : 0.0169 - 0.102 M, [Alamine336] ; 0.02- 1.75 M, and [HCl ] : 5 - 10 M. The following solvent extraction reaction and equilibrium constant was obtained from the experimental data by considering the activity coefficients of chemical species present in the aqueous phase. $Co^{2+}+2Cl^{-}+R_3NHCl_{org}=CoCl_3\;R_3NH_{org}$, $K_{ex}=2.21$ The distribution coefficients of cobalt predicted in this study agreed well with those reported in the literature.