• Korean Chemical Engineering Research
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• 제54권3호
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• pp.299-304
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• 2016

Nitrate-citrate 혼합 전구체로부터 ZnO 입자 합성을 위한 자체진행 반응(Self-propagating reaction)의 특성을 고찰하였다. 질화물과 Citrate 그룹간의 자체진행 반응을 위해 탄소/질소 성분의 비는 0.7~0.8 수준으로 유지하였으며, 출발물질의 시료를 TGA방법에 의해 열분해하였다. 반응의 후반부인 반응 전환율이 0.5 이상에서 자체진행 반응의 특성을 나타내었으며 시료는 매우 짧은 시간에 많은 열을 방출하며 분해되었다. 반응의 전반부(X<0.5)가 전체반응의 율속단계로 나타났으며, 이 율속단계에서 반응의 특성을 Friedman, Ozawa-Flynn-Wall 그리고 Vyazovkin의 방법들을 사용하여 해석하였다. 율속단계에서 활성화 에너지는 46~130 (kJ/mol)의 범위로 반응 전환율이 증가함에 따라 증가하였으며, 반응차수는 2.9~0.9, 그리고 반응속도의 빈도인자(Frequency factor)는 85~278 ($min^{-1}$)의 범위에서 승온속도가 증가함에 따라 각각 전자는 감소하고 후자는 증가하였다.

• 대한가정학회지
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• 제27권4호
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• pp.11-20
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• 1989

Teen-agers are much concerned for their appearances. Their clothes reflect their living conditions and serve as a means to represents themselves as well. They also show great concern for the clothes of students of an age. So to guide their clothing behaviours in school plays a very important role in the living guidance of students. From this point, this study was aimed at examing closely the differences of recations as to the girl students' clothing behaviours between boy students and girl students of high school, and the correlation between environment condition and reaction upon the clothing behaviours of girl students. To check the physical environment condition of the family, the family circumstances test, made and standardized by Jung Won Sik, was used. To check the clothing behaviours of girl students, four items-modesty, fashion and esthetics were made and each item had five questions, wihich comprised fifteen questons all told. The subjects of this study included students in eight high schools located in Incheon, totaling 930 boys and girls. The results of this study were summarized as follows: 1. There are great differences in students' reaction upon girl students' clothing behaviours according to their physical circumstances level, sex, grade years and the degree of concern for other sex. (A) The correlation between students' physical circumstances level and their reaction upon the girl students' clothing behaviours is high in all the three items. The higher the students' circumstancses level is, the lower their reaction upon modesty is, and the higher their reaction upon fashion. In case of esthetics, only girl students show great concern for it. (B) As to the reaction upon the girls students' clothing behaviours by sex, girls show higher concern for modesty, fashion and esthetics than boys. (C) As to the reaction upon the girl students' clothing behaviours by the grade years, the first year students as a whole show higher concern for modesty than second grade year students. (D) As to the reaction upon the girl students' clothing behaviours by the degree of concern for other six, the more concern both the boy and the girl students have for other sex, the higher their reactions are upon fashion and esthetics, but the lower upon modesty. 2. From the point of reactions upon the girl students' clothing behaviours, (A) as to fashion, free variables can explain by 7.8 percent the degree of concern for other sex, physicial circumstances level, and sex in that order. (B) as to fashion, free variables can explain by 5.4 persent the concern for other sex, physicial circumstances level, and sex in that order. (C) as to esthetics, free variables can explain by 4.8 percent the concern for other sex, physicial circumstances level, and sex in that order. From the above analysis, the following are included: The concern for other sex has the greatest influence on the girl students clothing behaviours, the physicial circumstances level the nest, sex the third and the grade year the last.

• 환경위생공학
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• 제18권4호
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• pp.45-51
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• 2003

This study was conducted to remove the color in dyeing wastewater by ozone oxidation process, and the results were summarized as follows ; The 18.3％ of BOD and 56.3％ TOC were removed as decreasing with pH 1 in dyeing wastewater, containing the polyester reducing process. It showed that terephthalic acid was precipitated at low pH. The color of dyeing wastewater was removed by the first order reaction, and the reaction rate constants at pH 3, 7, 12 were investigated $0.234{\;}min^{-1},{\;}0.215{\;}min^{-1}{\;}and{\;}0.201{\;}min^{-1}$ respectively. It showed that color was more effectively removed with direct reaction of ozone than radical reaction(non-direct reaction). As increasing of the water temperature, the reaction rate constants were increased slightly. It indicated that activity of ozone was improved at high water temperature.

• Current Research on Agriculture and Life Sciences
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• 제25권
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• pp.25-31
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• 2007

The several enzymes reaction which involve the quality change of fresh vegetables, such as chlorophylase, polyphenol oxidase, lypoxygenase, C-S-lyase, myrosinase and enzymes related lignification were reviewed. Numerous enzyme reaction continuously proceeds to the deterioration of vegetables after harvest due to the respiration and biochemical metabolism reaction, especially in case of physical injuring. It is extremely important to inhibit and to control these enzyme reaction in order to maintain the organoleptic and nutritional quality of fresh vegetables.

• Korean Chemical Engineering Research
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• 제56권3호
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• pp.416-420
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• 2018

A comprehensive kinetic study has been conducted on dimethyl carbonate synthesis by transesterification reaction of ethylene carbonate with methanol. An alkali base metal (KOH) was used as catalyst in the synthesis of DMC, and its catalytic ability was investigated in terms of kinetics. The experiment was performed in a batch reactor at atmospheric pressure. The reaction orders, the activation energy and the rate constants were determined for both forward and backward reactions. The reaction order for forward and backward reactions was 0.87 and 2.15, and the activation energy was 12.73 and 29.28 kJ/mol, respectively. Using the general factor analysis in the design of experiments, we analyzed the main effects and interactions according to the MeOH/EC, reaction temperature and KOH concentration. DMC yield with various reaction conditions was presented for all ranges using surface and contour plot. Furthermore, the optimal conditions for DMC yield were determined using response surface method.

• 한국세라믹학회지
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• 제33권12호
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• pp.1331-1338
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• 1996

In order to investigate the reaction in the system of fly ash-sulfuric acid-calcium hydroxide the hydrates were produced by the addition of Ca(OH)2 to fly ash activated with sulfuric acid at various temperatures. And then they were characterized by XRD. SEM and TG-DTA. It was found that in the reaction of fly ash with sulfuric acid fly ash was not decomposed but Al2O3 and SiO2 component in it were activated. The addition of calcium hydroxide into this system resulted in the formation of ettringite and calcium silicate hydrate (C-S-H) As the concentration of sulfuric acid and reaction temperature increased the amount of calcium hydroxide decreased fast. At this time gypsum produced by the reaction calcium hydroxide with sulfuric acid was consumed to form ettringite. Accordingly the formation of ettringite increased with calcium hydroxide and reaction time. And it showed faster than the formation of C-S-H.

• Journal of the Korean Wood Science and Technology
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• 제18권4호
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• pp.79-85
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• 1990

Many kinds of acetosolv lignin including ricestraw and spruce lignin were pyrolyzed. and liquefied in the autoclave reactor using 50% tetralin and m-cresol solution respectively as soluble solvent and Co-Mo as catalyst. In order to promote deoxyhydrogenolysis reaction $H_2$ gas was supplied into the reactor. The ratio between lignin and the soluble solvent are lg and 10cc. The reaction conditions are $200^{\circ}-700^{\circ}C$ of reaction temperature, 10-50 atms of reaction pressure and 100-500rpm of the reactor stirrer. By the deoxyhydrogenolysis liquefaction reaction, the main chemical structures of lignin which are aryl-alkyl-${\beta}$-0-4 ether, phenylcoumaran and biphenyl etc. are easily destroyed into liqufied aromatic compounds and aliphatic compunds linked with aromatic compounds. The percent yield of monomeric phenols on the weight bvase of lignin reacted reached to 12-14% by the chemical analytic GC-MS etc.

• 대한인간공학회지
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• 제17권2호
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• pp.65-82
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• 1998

To investigate the difference of sweating reaction by the somato types, we measured total sweat rate, local sweat rate, skin temperature, physiological reaction and psychological reaction at $25{\pm}1^{\circ}C$ and $29{\pm}1^{\circ}C$ under laboratory conditons. Nine healthy adult females were divided into three somato types : slender (3), normal (3) and obese (3). The results were as follows ; Total sweat rate was highest in the obese type, followed by the normal and slender types in order. Local sweat rate was highest in the infrascapular area, and then came breast, the back of the hand, upper ann, anterior leg, and anterior thigh in all somato types. Mean skin temperature was highest in the slender type, and followed the normal and obese types. Rectal temperature, blood pressure and pulse rate were highest in the obese type. Psychological reaction appeared 'hot', 'humid', 'sweaty' as ambient temperature went up. Somato types made little difference in psychological reaction.

• Archives of Metallurgy and Materials
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• 제64권3호
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• pp.931-934
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• 2019

Al-CuO is a thermite material exhibiting the exothermic reaction only when aluminum melts. For wide spread of its application, the reaction temperature needs to be reduced in addition to the enhancement of total reaction energy. In the present study, a thermite nanocomposite with a large contact area between Al and CuO was fabricated in order to lower the exothermic reaction temperature and to improve the reactivity. A cryomilling process was performed to achieve the nanostructure, and the effect of composition on the microstructure and its reactivity was studied in detail. The microstructure was characterized using SEM and XRD, and the thermal property was analyzed using DSC. The results show that as the molar ratio between Al and CuO varies, the fraction of uniform nanocomposite structure was changed affecting the exothermic reaction characteristics.

• 한국추진공학회지
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• 제20권1호
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• pp.50-57
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• 2016

본 논문은 DNAM(Dinitroammeline)합성공정 개발을 위한 Lab scale 합성 과정을 소개하고 분석결과를 기록한 것으로 주요 내용은 다음과 같다 Melamine을 출발물질로 하여 니트로화와 산화 반응을 통해 DNAM을 합성하였다. 수율과 순도의 최적 조건을 찾기 위해 투입순서, 반응시간, 반응물 당량 등을 변경하여 실험을 수행하였다. DNAM 합성의 최적화된 조건은 3시간에서 3시간 30분 정도 반응시간이고, 니트로화 혼합물의 무게비는 1:1.4(아세트산 무수물:농질산)이며, 최종 수율은 60% 이상이다.