• Title/Summary/Keyword: reaction factors

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Bisphenol-A Removal in Conventional Water Treatment Systems (정수처리공정에서 bisphenol-A의 제거에 관한 연구)

  • 김혜리;이윤진;박선구;남상호
    • Journal of Environmental Health Sciences
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    • v.30 no.1
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    • pp.59-64
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    • 2004
  • This study was carried out to investigate influencing factors of bisphenol A(BPA) removal characteristic in conventional water treatment systems to be connected with coagulation, sedimentation, filtration and disinfection. The result are summarized as follows; In BPA removal, optimal doses of PAC, alum, ferric chloride were 7.5 mg Al/L, 10.0 mg AI/L, 15.0 mg Fek. PAC was most effective coagulant to remove BPA. In coagulation process, BPA removal efficiency were increased about 2% by adjusting pH of raw water as 6. At temperature rise 1$0^{\circ}C$, BPA removal efficiency were increased 0.94%. but BPA removal efficiency in sand filtration process were under 1 %ie, so that BPA was almost not removed. At free chlorine dose 1, 2 mg/L, the reaction rate constant k in the BPA removal have been calculated to be 0.397, 0.953 min$^{-1}$ . At free chlorine dose 1, 2 mg/1-, degradation reaction of BPA was completed during 10 min and BFA removal efficiencies were 97.66, 99.99% at this time.

The Perception-Based Study of a Weak Syllable in English Words Containing Weak-Strong Pattern by Korean Learners (I) (약강구조를 포함하는 영어단어에 대한 영어학습자의 약음절 지각과 반응시간(I))

  • Shin Ji-Young;Kim Kee-Ho;Kim Hee-Sung
    • MALSORI
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    • no.57
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    • pp.31-42
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    • 2006
  • The purpose of this study is to observe how Korean learners perceive an English weak syllable in words containing WS syllable pattern. According to the automated discrimination task using E-Prime, the ratio of correct answer(%) and reaction time of the stimuli with same syllable patterns were respectively higher and faster than those with different syllable patterns. Specifically, in the stimuli with different syllable patterns, the frequency(familiarity) of stressed word succeeding weak syllable and whether the weak syllable had coda in it were two important factors in distinguishing between a word with and without weak syllable. Even though the high English proficiency Koreans had faster reaction time than the low English proficiency Koreans, all Korean learners had a difficulty in perceiving the weak syllable at the beginning of a word.

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Review of Reaction Drive Rotor System Sizing Methodology (반작용 구동로터 시스템의 사이징 방법론에 대한 고찰)

  • Ali, Freshipali Rasheeth;Jeon, Kwon-Su;Lee, Jae-Woo
    • 한국항공운항학회:학술대회논문집
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    • 2016.05a
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    • pp.9-13
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    • 2016
  • Reaction drive rotor system is capable of providing hover and low speed capabilities to different aircraft concepts such as stopped rotor wing, canard rotor wing, compound gyroplane etc. Existing sizing and analysis tools for shaft drive rotor system cannot be applied directly to this system. The available methodologies to size this system were reviewed. Power available calculation procedure and factors affects it were addressed prior to sizing process. Various design issues of this system due to interrelationship of internal gas flow dynamics and rotor external aerodynamics was discussed. Finally, a modification that is required in existing sizing methodologies was identified and combined approach in sizing process to consider the interrelationship among engine, rotor and blade duct was introduced.

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Modeling of a Pulverized Coal Combustion With Applying WSGGM (희체가스 가중합산모델을 적용한 미분탄 연소의 해석)

  • Yu, Myoung-Jong;Baek, Seung-Wook
    • 한국연소학회:학술대회논문집
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    • 1999.10a
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    • pp.155-163
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    • 1999
  • A numerical study for simulating a swirling pulverized coal combustion in axisymmetric geometry is done here by applying the weighted sum of gray gases model (WSGGM) approach with the discrete ordinate method (DOM) to model the radiative heat transfer equation. In the radiative transfer equation, the same polynomial equation and coefficients for weighting factors as those for gas are adopted for the coal/char particles as a function of partial pressure and particle temperature. The Eulerian balance equations for mass, momentum, energy, and species mass fractions are adopted with the standard ${\kappa}-{\varepsilon}$ turbulence model, whereas the Lagrangian approach is used for the particulate phase for soot. The eddydissipation model is employed for the reaction rate for gaseous mixture, and the single-step first-order reaction model for the devolatilization process for coal. By comparing the numerical results with experimental ones, the models used here are confirmed and found to be one of good alternatives for simulating the combustion as well as radiative characteristics.

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Analysis of Driving Performances on the Characteristics of Drivers (운전자의 특성에 따른 자동차 운전 수행도 분석)

  • 오영진
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.21 no.48
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    • pp.145-152
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    • 1998
  • Driving performance is characterized by many things such as driver's experience period, age, ability of information processing and reaction time of control devices and so forth. However, each factor of driving performance is needed to help and screen a poor driver for safe driving. In this paper, driving performance was estimated by reaction of manipulating brake, accelerator, steering wheel and speed. Subjects were grouped by experience of accident and age. Combinations of every group were analysed. For all the dependent variables, only steering wheel and speed were shown to have significant difference, which could be regarded as visual information of speed and direction were the important factors to drive safely. Especially for tile elderly, it is needed to enhance their ability of visual information processing that is to be decreased with aging. Therefore driving simulator to train and screen the poor driver should be studied.

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Chromate Refractory by Combustion Process (연소합성에 의한 크로메이트 내화물 제조)

  • 김형순;한정환
    • Journal of the Korean Ceramic Society
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    • v.31 no.12
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    • pp.1437-1442
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    • 1994
  • Self propagating synthesis and thermal explosion of combustion reactions were applied to Al/K2Cr2O7/Al2O3 system as the first stage for a production of magnesia-chromium refractory. Several factors related to products made by two combustion reactions were considered and properties of products were characterised. Two processes were required to preheat upto at least 80$0^{\circ}C$ for the thermal explosion and the self propagating synthesis. These processes were so violent and explosive that alumina as diluent was added to the system in order to absorb the reaction heat and reduce the reaction rate. The products consisted of crystal phases of KAl5O8, Cr2O3, Al2O3, K2CrO4, and K2Al2O4.3H2O. The amount of KAl5O8 and K2Al2O4.3H2O crystal phases of products were decreased with further addition of alumina.

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Solvent Effect on Restriction Endonuclease : Alteration of Specificity of Restriction Endonuclease PvuII in Hydrophobic Solution (제한효소에 대한 용매의 영향 :소수성 용매에 의한 PvuII 특이성 변화)

  • 김희정;이강민
    • KSBB Journal
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    • v.9 no.1
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    • pp.63-71
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    • 1994
  • During the last decade enzyme reaction in organic solvent has been studied to show that specificity in buffer is different from that in organic solvent. The specificity of restriction enzyme was effected by various factors such as ionic strength, salt organic solvent and temperature. In this study, restriction enzyme PvuII which is used most frequently in genetic engineering and the substrate was vector pGEM3 whose sequence was already known were used. As a result the recognition sequence site was changed in the presence of organic solvents whose Log P are -1.5∼0. Their specificities were contrast with activities were contrasted. Specificities were not changed in organic solvent easily in inactivating enzyme. We think that the enzyme recognition site was not changed randomly but by preferential order. A recombinant vector which does not contain typical cleavage site CAG↓CTG was cleaved in 20% ethanol solution. This result might show that restriction enzyme could be used to cleave at unusual sites by changing the reaction conditions.

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Kinetics and Mechanism of the Pyridinolysis of Diisopropyl Thiophosphinic Chloride in Acetonitrile

  • Hoque, Md. Ehtesham Ul;Lee, Hai-Whang
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4387-4391
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    • 2011
  • The kinetic studies on the pyridinolysis of diisopropyl thiophosphinic chloride have been carried out in acetonitrile at $55.0^{\circ}C$. The free energy correlations for substituent X variations in the X-pyridines are biphasic concave upwards with a break point at X = 3-Ph. A concerted SN2 mechanism is proposed with a change of the attacking direction of the X-pyridine from a frontside attack for the strongly basic pyridines to a backside attack for the weakly basic pyridines. The factors to determine the rates and thio effects on the rates for the pyridinolyses of thiophophinic chloride, chlorothiophosphate, phosphinic chloride, phosphonochloridothioate, and chlorophosphate systems are briefly reviewed on the basis of the magnitude of the positive charge of the reaction center P atom and steric effects of the two ligands.

Synthesis of barium hexaaluminate by sol - gel method (졸 - 겔법에 의한 바륨헥사알루미네이트 합성)

  • 백영순;김형진
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.2
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    • pp.142-151
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    • 1995
  • Complex alkoxides were synthesized using metal alkoxide method and were then hydrolyzed to prepare the precursors using sol - gel method. Then, the precursors were calcined in order to make barium hexaaluminate. Factors affecting the material properties of the barium hexaaluminate precursors were studied and they are the kinds and amount of alcohols, and reaction time. In addition, in the course of hydrolysis, the effects of the amount of water, reaction temperature and aging time were also studied in terms of the specific surface area and average particle size of the barium hexaaluminates.

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The Effects of Sputtering conditions in Pre Sputtering on the Formation Behavior of Nitride Layer in the Ion Nitriding of Stainless Steel (초기 스퍼터링조건이 스테인리스강의 이온질화시 지로하층 형성거동에 미치는 영향)

  • 최상진
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1999.10a
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    • pp.197-203
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    • 1999
  • Stainless steels in general has passive film having strong corrosion resistance on surface. Therefore it must be necessarily removed by etching in mixing solution of sulfuric and chloric acid before Nitriding treatment. But in the ion nitriding, nitride layer was easily formed because passive film was removed without difficult by sputtering effect. The removal extent of these passive films was greatly effected by gas mixing ratios and pressure and holding times of pre sputtering factors in pre sputtering stage. As a results of experiment it has been known that pre sputtering pressure and holding time was not nearly effective on the formation behavior of nitride layer. But when A/H2 gas mixing ratios was 1/2 (vol%) was the most effective of the all pre sputtering conditions. It was resulted from the combination of mechanical reaction byArgon bombardment and chemical reaction by reduction of hydrogen on the passive film.

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