• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.08a
• /
• pp.394-394
• /
• 2012

We fabricated organic-inorganic superlattice films using molecular layer deposition (MLD) and atomic layer deposition (ALD). The MLD is a gas phase process in the vacuum like to atomic layer deposition (ALD) and also relies on a self-terminating surface reaction of organic precursor which results in the formation of a monolayer in each sequence. In the MLD process, 'Alucone' is very famous organic thin film fabricated using MLD. Alucone layers were grown by repeated sequential surface reactions of trimethylaluminum and ethylene glycol at substrate temperature of $80^{\circ}C$. In addition, we developed UV-assisted $Al_2O_3$ with gas diffusion barrier property better than typical $Al_2O_3$. The UV light was very effective to obtain defect-free, high quality $Al_2O_3$ thin film which is determined by water vapor transmission rate (WVTR). Ellipsometry analysis showed a self-limiting surface reaction process and linear growth of each organic, inorganic film. Composition of the organic films was confirmed by infrared (IR) spectroscopy. Ultra-violet (UV) spectroscopy was employed to measure transparency of the organic-inorganic superlattice films. WVTR is calculated by Ca test. Organic-inorganic superlattice films using UV-assisted $Al_2O_3$ and alucone have possible use in gas diffusion barrier for OLED.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.21 no.11
• /
• pp.1527-1537
• /
• 1997

Extinction characteristics and acoustic response of hydrogen-air diffusion flames at various pressures are numerically studied by employing counterflow diffusion flame as a model flamelet in turbulent flames in combustion chambers. The numerical results show that extinction strain rate increases linearly with pressure and then decreases, and increases again at high pressures. Thus, flames are classified into three pressure regimes. Such nonmonotonic behavior is caused by the change in chemical kinetic behavior as pressure rises. The investigation of acoustic-pressure response in each regime, for better understanding of combustion instability, shows different characteristics depending on pressure. At low pressures, pressure-rise causes the increase in flame temperature and chain branching/recombination reaction rates, resulting in increased heat release. Therefore, amplification in pressure oscillation is predicted. Similar phenomena are predicted at high pressures. At moderate pressures, weak amplification is predicted since flame temperature and chain branching reaction rate decreases as pressure rises. This acoustic response can be predicted properly only with detailed chemistry or proper reduced chemistry.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.22 no.2
• /
• pp.193-204
• /
• 1998

Numerical analysis was performed with multicomponent transport properties and detailed reaction mechanisms for axisymmetric 2-D CH$_{4}$ jet diffusion flame. Calculations were carried out twice with the $C_{2}$-Thermal Mechanism including $C_{2}$ and thermal NO reactions and the $C_{2}$-Full Mechanism including prompt NO reactions in addition to the above $C_{2}$-Thermal NO mechanism. The results show that the flame structures such as flame temperature, major and minor species concentration are indifferent to respective mechanisms. The production path of Thermal NO is dominant comparing with that of Prompt NO in total NO production of pure CH$_{4}$ jet diffusion flame. This is because thermal NO mechanism mainly contributes to positive formation of NO in the whole flame region, but Prompt NO mechanism contributes to negative formation in the fuel rich region. In addition, 0$_{2}$ penetration near the nozzle outlet affects the flame structures, especially N0$_{2}$ formation characteristics.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.31 no.12
• /
• pp.1009-1016
• /
• 2007

Numerical study on preferential diffusion effects in flame structure in $CH_4-H_2$ diffusion flames is conducted with detailed chemistry. Comparison of flame structures with mixture-averaged species diffusion and suppression of the diffusivities of $H_2$ and H was made. Discernible differences in flame structures are displayed with three species diffusion models. The behaviors of maximum flame temperatures with those species diffusion models are not explained by scalar dissipation rate but by the nature of chemical kinetics. It is seen that the modifcation of flame structure is mainly due to the preferential diffusion of H2 and thereby the nature of chemical kinetics. It is also found that the behaviors of major species with the three species diffusion models are addressed to the nature of chemical kinetics, and this is evident by examining importantly contributing reaction steps to the production and destruction of those chemical species.

• 한국연소학회:학술대회논문집
• /
• 2003.05a
• /
• pp.129-136
• /
• 2003

Numerical study with momentum-balanced boundary conditions has been conducted to grasp chemical effects of added $CO_{2}$ and $H_{2}O$ to fuel- and oxidizer-sides on flame structure and NO emission behavior in $CH_{4}$/Air counterflow diffusion flames. The dilution with $H_{2}O$ results in significantly higher flame temperatures and NO emission, but dilution with $CO_{2}$ has much more chemical effects than that with $H_{2}O$. Maximum reaction rate of principal chain branching reaction due to chemical effects decreases with added $CO_{2}$. but increases with added $H_{2}O$. The NO emission behavior is closely related to the production rate of OH, CH and N. The OH radical production rate increases with added $H_{2}O$ but those of CH, N decrease. On the other hand the production rates of OR CH and N decrease with added $CO_{2}$. It is found that NO emission behavior is considerably affected by chemical effects of added $CO_{2}$ and $H_{2}O$.

• Journal of the Korean Chemical Society
• /
• v.41 no.8
• /
• pp.385-391
• /
• 1997

Diffusion Coefficient$(D_0)$ and electrode reaction rate Constant$(K_0)$ of Co$(dimethyl bipyridine)_3(ClO_4)_2$ were determined by cyclic voltammetry and chronoamperometry. It was also investigated that the effects of solvent, concentration, and scan rate, etc. on the diffusion coefficient and the temperature effect on the rate constant. The peak currents and diffusion coefficients were dcreased as increasing the viscosity of solvent. Diffusion coefficient was $5.54{\times}10^{-6 }cm^2/sec$ and the reaction rate constant was $2.39{\times}10^{-3 }/s$ at 25$^{\circ}C$. The thermodynamic parameters such as ${\Delta}G^{\neq},\;{\Delta}H^{\neq},\;and\;{\Delta}S$ were calculated from plotting the reaction rate constants versus the solution temperatures. This compound was shown the catalytic effect on the oxygen reduction that the reduction peak current of oxygen was greatly enhanced and the peak potential was shifted to +0.2 volt.

• Journal of Advanced Navigation Technology
• /
• v.22 no.6
• /
• pp.648-653
• /
• 2018

Analysis of a specific wavelength band of a video signal is an old research field. However, studies on the analysis of signals having the characteristics of a specific wavelength band or the generation of samples have been conducted actively in recent years. In this paper, we analyze the signal of digital halftoned image. The interpretation of halftoning in terms of signals was first made by Ulichney. We have come to the view that the signal characteristics between pixels used for half toning are good for blue noise. Lau has developed a halftoning method that uses green-noise characteristics by using output-dependent feedback as an error diffusion method. Jho has developed a method for producing halftoned images using a reaction diffusion model. In this paper, we analyze reaction diffusion halftoning in terms of signal to show green noise and compare it with existing green noise half tone.

• East Asian mathematical journal
• /
• v.32 no.3
• /
• pp.387-397
• /
• 2016

This paper is concerned with the optimal control problem for some reaction diusion model. That is, we show the existence of the global weak solution for the Field-Noyes model. We also show the existence of the optimal control.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2002.05a
• /
• pp.207-212
• /
• 2002

Reportedly, the use of mineral admixtures make concrete more durable and tighten against water. But, it is needed to study more about the relationship between the admixtures and the chloride ion diffusion. When concrete is mixed with fly-ash, pozzolanic reaction occur to time. So we should consider the factors that can evaluate inner structure of concrete in order to evaluate the chloride diffusion of the concrete more accurately. Therefore, in this study, we analyzed the correlation between chloride ion diffusion and physical properties such as compressive strength, void ratio, air permeability of the concrete, and tried to use them as fundamental data for analyzing chloride ion diffusion mechanism of the concrete mixed with fly-ash.

• Journal of Mechanical Science and Technology
• /
• v.16 no.9
• /
• pp.1156-1165
• /
• 2002

The characteristics of combustion and radiation heat transfer of an oxygen-enhanced diffusion flame was experimentally analyzed. An infrared radiation heat flux gauge was used to measure the thermal radiation of various types of flames with fuel, air and pure oxygen. And the Laser Induced Incandescence (LII) technique was applied to characterize the soot concentrations which mainly contribute to the continuum radiation from flame. The results show that an oxygen-enhanced inverse diffusion flame is very effective in increasing the thermal radiation compared to normal oxygen diffusion flame. This seems to be caused by overlapped heat release rate of double flame sheets formed in inverse flame and generation of higher intermediate soot in fuel rich zone of oxygen-fuel interface, which is desirable to increase continuum radiation. And the oxygen/methane reaction at slight fuel rich condition (ø=2) in oxygen-enhanced inverse flame was found to be more effective to generate the soot with moderate oxygen availability.