• Proceedings of the KSME Conference
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• 2001.11b
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• pp.149-154
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• 2001

The emission characteristics, flame stability, the composition of the flame zone and temperature profile were studied experimentally. The compositions of oxydant were varied by substituting $N_2$ with $CO_2$ at the constant $O_2$ concentration. Results showed that flame became unstable due to the high heat capacity, low transport rate and strong radiation effect of $CO_2$ in comparison with those of $N_2$. The reaction zone was cooled, broadened, as the conversion ratio of $CO_2$ to $N_2$ was increased. Temperature has a large effect on the NOx emission. The concentration of NOx in flue gas decreased due to the decreased temperature of reaction zone. It was also shown that the reaction was delayed by the cooling effect. As the conversion ratio of $CO_2$ to $N_2$ was increased, the emission of CO and the higher temperature zone increased due to the decrease of reaction rate by the cooling effect.

• Applied Chemistry for Engineering
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• v.25 no.2
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• pp.198-203
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• 2014

In this study, steam reforming reaction and surface characteristics of Ni metal foam plate were investigated. Valence state of Ni could be changed by pretreatment, and metallic Ni species exposed on surface as a active site play important role in steam reforming reaction. Porous catalytic membrane also was prepared by mixing of Ni metal foam plate and Ni-YSZ catalyst to control the pore size and assign the catalytic function in Ni metal foam plate. In SEM analysis results, Pore size of Ni metal foam plate could be controlled and Ni-YSZ catalyst well dispersed on surface. Ni based porous catalytic membrane had a similar steam reforming activity regardless of space velocity.

• Textile Coloration and Finishing
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• v.24 no.1
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• pp.39-44
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• 2012

To improve flame retardation of poly(ethylene terephthalate) (PET) against burning, resorcinol bis(diphenyl phosphate) (RDP), phosphorous containing flame retardant, was incorporated into PET backbone by radical reaction pathway. Radical endcapping of PET with RDP was confirmed by spectroscopic and thermal analysis. From 400 MHz $^{31}P$ solid state FT-NMR spectrum of PET with RDP (PET-RDP), phosphorus spectra peak in RDP was found at ca. -10 ppm. Furthermore, P-C bond stretching vibration peaks were found ca. $530cm^{-1}$ in FT-IR spectrums of PET-RDP. These results indicated that RDP can be chemically bound at the ends of PET by radical addition method. Thermal characteristics of pure PET (pPET) and PET-RDP were measured and evaluated by TGA thermal analysis. There was not significant changes in thermal characteristics of PET-RDP compared to that of pPET.

• Journal of the Korean Ceramic Society
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• v.47 no.5
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• pp.394-400
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• 2010

This study examined the effects of particle size on characteristics of cement by controlling the particle size of commercial cement. Through a size adjustment, the cement has increasing more of particles that are less than $10{\mu}m$ in size so the initial reaction time has been shortened as a result of improvement in the early hydration reaction. Additionally, it showed a great characteristics of strength from the early age and the initial hydration heat has been increased as well. In the upper and middle parts cements, the initial hydration reaction rate contribution is high with the $10{\mu}m$ compared to original cement. So the initial hydration reaction rate is improved and as a result, it also showed relatively high hydration heat as well. Additionally, adiabatic temperature also showed an increase rate in the results.

• Journal of Powder Materials
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• v.15 no.2
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• pp.101-106
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• 2008

The objective of the present study is to investigate the increase in the functional characteristics of a substrate by the formation of a thin coating layer. Thin coating layers of $Ti_5Si_3$ have high potential because $Ti_5Si_3$ exhibits high hardness. Shock induced reaction synthesis is an attractive fabrication technique to synthesize uniform coating layer by controlling the shock wave. Ti and Si powders to form $Ti_5Si_3$ using shock induced reaction synthesis, were mixed using high-energy ball mill into small scale. The positive effect of this technique is highly functional coating layer on the substrate due to ultra fine substructure, which improves the bonding strength. These materials are in great demand as heat resisting, structural and corrosion resistant materials. Thin $Ti_5Si_3$ coating layer was successfully recovered and showed high Vickers' hardness (Hv=1183). Characterization studies on microstructure revealed a fairly uniform distribution of powders with good interfacial integrity between the powders and the substrate.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.93-96
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• 2015

Commercial coal gasifiers typically use entrained flow type reactors, but have unique features in terms of reactor shape, gasifying agent, coal feeding type, ash/slag discharge, and reaction stages. The MHI gasifier is characterized as air-blow dry-feed entrained reactor, which incorporates a short combustion stage at the bottom and a tall gasification stage above. This study investigates the flow and reaction characteristics inside a MHI gasifier by using computational fluid dynamics (CFD) in order to understand its design and operation features. For its pilot-scale system at 200 ton/day capacity, the distribution of coal and air supply between the two reaction stages was varied. It was found that the syngas composition and carbon conversion rate were not significantly influenced by the changes in the distribution of coal and air supply. However, the temperature, velocity and flow pattern changed sensitively to the changes in the distribution of coal and air supply. The results suggest that one key factor to determine the operational ranges of coal and air supply would be the temperature and flow pattern along the narrower wall between the two reaction stages.

• Journal of Soil and Groundwater Environment
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• v.29 no.1
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• pp.63-71
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• 2024

Hydrothermal Reaction (HTR) was applied for the stabilization of contaminated soil with heavy metals, and then the test determined the optimal conditions for HTR. After HTR, the concentration of heavy metals in the contaminated soil increased. However, it was observed that the leachability potential significantly decreased as determined by TCLP and SPLP tests. This decrease was attributed to a decline in fractions 1-2 and an increase in fractions 3-4 as revealed by sequential extraction procedure. Due to the mineralogical characteristics of the dredged soil, distinct changes were not evident in the five-stage fraction. Therefore, it is deemed necessary to understand the chemical and mineralogical characteristics of the target soil for HTR application in order to selectively address contaminants. Comparison among operating conditions determined the optimal condition to be at 240℃ for one hour.

• International Journal of Precision Engineering and Manufacturing
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• v.3 no.2
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• pp.61-71
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• 2002

This paper presents the dynamic analysis of indeterminate rotor systems with angular contact ball bearings subject to axial and radial loads. The reaction forces against applied radial loads significantly influence the dynamic characteristics of angular contact ball bearings. However, the reaction forces are hard to determine in the case of indeterminate rotor-bearing systems. To this end, this paper proposes a finite element model for indeterminate rotor systems with angular contact ball bearings. An improved bearing model is adopted which is originated from the Harris's bearing dynamic model. The bearing model is also extended to include centrifugal forces due to the ball and inner ring. This paper utilizes a new iterative algorithm for general, indeterminate rotor systems with angular contact ball bearings. This examples are provided to illustrate the dynamic characteristics of rotor systems with angular contact ball bearings subject to axial and radial loads. The experimental and numerical results prove that the proposed method is useful for the dynamic analysis of indeterminate rotor systems with angular contact ball bearings.

• Journal of the Korean Society of Combustion
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• v.19 no.4
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• pp.28-34
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• 2014

Numerical study is conducted to grasp flame characteristics in $H_2/CO$ syngas counterflow diffusion flames diluted with He and Ar. An effective fuel Lewis number, applicable to premixed burning regime and even to moderately-stretched diffusion flames, is suggested through the comparison among fuel Lewis number, effective Lewis number, and effective fuel Lewis number. Flame characteristics with and without the suppression of the diffusivities of H, $H_2$, and He are compared in order to clarify the important role of preferential diffusion effects through them. It is found that the scarcity of H and He in reaction zone increases flame temperature whereas that of $H_2$ deteriorates flame temperature. Impact of preferential diffusion of H, $H_2$, and He in flame characteristics is also addressed to reaction pathways for the purpose of displaying chemical effects.

• Journal of Fashion Business
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• v.7 no.1
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• pp.27-37
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• 2003

This study is the first part of the research to reveal the effects of somatotype characteristics on body temperature control reaction as well as thermal sensation. Nine healthy female collegians (classified into 3 body types of thin, normal, and obese according to Rohrer index) living in Busan were chosen as the subjects. The following are the results: Significant differences of skin temperature appeared in the parts of epigastrium (thin/normal>obese), anterior forearm (normal>thin/obese), and anterior leg (obese > thin/normal) as well as mean skin temperature. Mean skin temperature temporarily dropped owing to the exercise but tended to recover as time went by. Skin temperature of normal/thin shows higher than obese type. The change of skin temperature was noticed in the order of forehead > epigastrium > anterior forearm > anterior leg > anterior thigh (obese type) ; epigastrium > forehead > anterior forearm > anterior thigh > anterior leg (normal type) ; epigastrium > forehead > anterior forearm > anterior thigh > anterior leg (thin type, before and after exercise); epigastrium > forehead > anterior forearm > anterior leg > anterior thigh (thin type, during exercise). Significant differences were shown in the temperature change inside clothes according to somatotypes. No significant differences were revealed in thermal sensation, moisture sensation, and comfortable sensation according to body types and time.