• 제목/요약/키워드: ratio of deterioration

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계면활성제가 라텍스 블렌딩 폴리스티렌/단일벽 탄소나노튜브 나노복합재료의 유변학적, 전기적 물성에 미치는 영향 (Effect of Surfactant on Rheological and Electrical Properties of Latex-Blended Polystyrene/Single-Walled Carbon Nanotube Nanocomposites)

  • 강명환;노원진;우동균;이성재
    • 폴리머
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    • 제36권3호
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    • pp.364-371
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    • 2012
  • 폴리스티렌(PS)/단일벽 탄소나노튜브(SWCNT) 나노복합재료를 라텍스 기술로 제조하여 계면활성제(SDS) 첨가에 따른 SWCNT의 분산 정도와 나노복합재료의 유변학적, 전기적 물성을 고찰하였다. 나노복합재료는 단분산 PS 입자에 SDS를 첨가한 SWCNT 분산액을 혼합한 후 동결건조하여 제조하였다. SDS 함량이 증가함에 따라 나노튜브의 분산성이 향상되어 나노복합재료의 저장 탄성률과 복소 점도는 증가하지만, 지나치게 증가시킨 경우에는 저분자량의 SDS로 인해 감소하는 결과를 보여주었다. 전기 전도도는 SDS를 첨가함에 따라 급격히 향상된 후 큰 변화를 보이지 않았다. 이는 나노튜브의 분산성 향상에 의한 전기 전도도 증가와 SDS 도포에 의한 SWCNT의 전기 전도도 저하의 경쟁에 의한 것으로 추론된다. SDS를 SWCNT 함량의 2배로 첨가한 경우가 나노복합재료의 전기 전도도 및 사용 물성 향상에 최적 조건이었다. 이 경우 전도성을 부여하는 SWCNT의 임계 함량은 1 wt% 이하에서 나타났다.

2상 스테인레스 주강의 공냉 열처리 적용 가능성 (Applicability of Air Cooling Heat-treatment for a Duplex Stainless Steel Casting)

  • 김봉환;양식;신제식;이상목;문병문
    • 한국주조공학회지
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    • 제26권1호
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    • pp.17-26
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    • 2006
  • The substitution of cooling method from water quenching to air cooling after solution heat treatment was aimed for the development of a convenient and economical heat treatment process of duplex stainless steels without deterioration of mechanical and corrosion resistant properties for the industry. In order to achieve this goal, the mechanical properties and corrosion properties of a ASTM A890-4A duplex stainless steel were systematically investigated as functions of casting condition and cooling method after solution heat treatment. A 3-stepped sand mold and a permanent Y-block mold were used to check the effects of solidification structure and cooling rate after solution heat treatment. The microstructural characteristics such as the ferrite/austenite phase ratio and the precipitation behavior of ${\sigma}$ phase and carbides were investigated by combined analysis of OM and SEM-EDX with an aid of TTT diagram. Hardness and tension test were performed to evaluate the mechanical properties. Impact property at $-40^{\circ}C$ and corrosion resistance were also examined to check the possibility of the industrial application of this basic study. Throughout this investigation, air-cooling method was proved to effectively substitute for water-quenching process after the solution heat treatment, when the duplex stainless steel was sand mold cast with a thickness below 15 mm or permanent mold cast with a thickness below 20 mm.

오스테나이트계 Fe-18Cr-10Mn-2Ni 합금의 연성-취성 천이 거동에 미치는 침입형 원소의 영향 (Effect of Interstitial Elements on Ductile-Brittle Transition Behavior of Austenitic Fe-18Cr-10Mn-2Ni Alloys)

  • 황병철
    • 한국재료학회지
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    • 제23권11호
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    • pp.649-654
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    • 2013
  • The effect of interstitial elements on the ductile-brittle transition behavior of austenitic Fe-18Cr-10Mn-2Ni alloys with different nitrogen and carbon contents was investigated in this study. All the alloys exhibited ductile-brittle transition behavior because of unusual low-temperature brittle fracture, even though they have a faced-centered cubic structure. With the same interstitial content, the combined addition of nitrogen and carbon, compared to the sole addition of nitrogen, improved the low-temperature toughness and thus decreased the ductile-brittle transition temperature (DBTT) because this combined addition effectively enhances the metallic component of the interatomic bonds and is accompanied by good plasticity and toughness due to the increased free electron concentration. The increase in carbon content or of the carbon-to-nitrogen ratio, however, could increase the DBTT since either of these causes the occurrence of intergranular fracture that lead to the deterioration of the toughness at low temperatures. The secondary ion mass spectroscopy analysis results for the observation of carbon and nitrogen distributions confirms that the carbon and nitrogen atoms were significantly segregated to the austenite grain boundaries and then caused grain boundary embrittlement. In order to successfully develop austenitic Fe-Cr-Mn alloys for low-temperature application, therefore, more systematic study is required to determine the optimum content and ratio of carbon and nitrogen in terms of free electron concentration and grain boundary embrittlement.

플럭스 염화물 조성이 Zn-Mg-Al 3원계 합금도금층의 미세조직 및 도금성에 미치는 영향 (Effect of Flux Chloride Composition on Microstructure and Coating Properties of Zn-Mg-Al Ternary Alloy Coated Steel Product)

  • 김기연;소성민;오민석
    • 한국재료학회지
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    • 제31권12호
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    • pp.704-709
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    • 2021
  • In the flux used in the batch galvanizing process, the effect of the component ratio of NH4Cl to ZnCl2 on the microstructure, coating adhesion, and corrosion resistance of Zn-Mg-Al ternary alloy-coated steel is evaluated. Many defects such as cracks and bare spots are formed inside the Zn-Mg-Al coating layer during treatment with the flux composition generally used for Zn coating. Deterioration of the coating property is due to the formation of AlClx mixture generated by the reaction of Al element and chloride in the flux. The coatability of the Zn-Mg-Al alloy coating is improved by increasing the content of ZnCl2 in the flux to reduce the amount of chlorine reacting with Al while maintaining the flux effect and the coating adhesion is improved as the component ratio of NH4Cl to ZnCl2 decreases. Zn-Mg-Al alloy-coated steel products treated with the optimized flux composition of NH4Cl·3ZnCl2 show superior corrosion resistance compared to Zn-coated steel products, even with a coating weight of 60 %.

표면피복재 종류에 따른 철근콘크리트의 철근 부식특성에 관한 실험적 연구 (An Experimental Study on the Corrosion Characteristics of Reinforcement Concrete According to Types of Surface Covering Material)

  • 김갑수;장종호;김재환;김용로;오시덕;김무한
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2003년도 학술.기술논문발표회
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    • pp.39-43
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    • 2003
  • Chloride ions are considered to be the major cause of steel corrosion in concrete structures exposed to seashore environments and also permeation of chloride is controlled by chloride diffusion. Therefore, the study on chloride diffusion of concrete have been done so far by many researchers. It is reported that coating material as surface covering material is effect about deterioration of salt damage and carbonation, therefore these materials are important in durability of concrete structure. In this study, corrosion characteristics of reinforcement concrete according to types of surface covering material were evaluated by water-cement ratio, chloride penetration by age on the corrosion area rate and mass decrement of reinforcement. And it is considered that the result of this study on application of the corrosion characteristics of reinforcements under salt damage environmental will be suggested as fundamental data of control performance of salt damage. It is performed that comparison and examination of control performance of salt damage by the corrosion characteristics under salt damage environmental.

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노인요양시설 요양층의 기능별 면적구성과 상관요인에 관한 연구 (A Study on the Functional Area Composition and Correlation Factors of Elderly Care Floor in Nursing Home)

  • 윤소희;김석태
    • 한국실내디자인학회논문집
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    • 제24권3호
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    • pp.156-164
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    • 2015
  • Nursing Homes do not have a defined standard in the space area nor does it have a detailed standard facility requirement by law. This can possibly lead to the deterioration of the facility and the system. This directly affects the medical treatment space area within the nursing home. The medical treatment area provides medical treatment to seniors and this is where the seniors get most of their daily services. Therefore, this is research is about the study of the space area of the medical center and the ratio trend of the space area for the medical treatment facility located in senior nursing homes. Ten facilities have been selected in this study to analyze the correlation factors between space area and its trends. The analysis performed includes the conditions relating to the area and what affects the center. We have followed up with a proposal for improvement of the facility and area configuration for the medical treatment facility. Based on the analysis, the following conclusion can be made: First, the senior welfare centers are mostly used as a residence purpose followed a temporary stay of residence facility for the seniors. Second, research indicates that the bigger the facility, nursing and public functions took a larger portion of the space area compared to other services within the senior welfare centers. Third, the study shows the management space area took up about 1%~6% of the entire medical center within the nursing home which is a narrow space area because of the integrated management. Fourth, analysis based on the trend in the time-series indicate after the adoption of the system, there is a continued decline in the space area of nursing, management and public areas. Lastly, since before and after 2008, the space area composition of the nursing facility shows a continuous decline in our study. We can safely conclude that the revised senior welfare act's construction plan has an effect in the facility and is effectively working to meet its requirement. Therefore, the revision of the law is required to reflect the social needs of the residents.

골관절염 환자의 활동제한이 건강관련 삶의 질과 우울증에 미치는 영향 (Effects of Activity Limitations on the Health-Related Quality of Life and Depression in Osteoarthritis Patients)

  • 이도연;남승민
    • 대한물리의학회지
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    • 제15권3호
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    • pp.109-116
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    • 2020
  • PURPOSE: The objective of this study was to provide a basis for the need to apply psychological factors-based rehabilitation programs to osteoarthritis patients by understanding how the limitations on the activities of osteoarthritis patients relate to the health-related quality of life and depression. METHODS: This study assessed 1,994 osteoarthritis patients from the 7th Korea National Health and Nutrition Examination Survey (KNHANES, 2016-2018). The subjects were divided into two categories: with activity limitation and without activity limitation. A Chi-square test and logistic regression analysis were conducted. RESULTS: The EQ-5D index of subjects with activity limitation was .84 ± .16, it was .94 ± .12 in those with no activity limitation (p < .05). The diagnosis of depression was 16.8% and; 8.3% in those with and without activity limitation, respectively (p < .05). There was a significant difference in the odds ratio for each item in the EQ-5D. Moreover, the odds ratio for depression with an activity limitation was 2.171 (1.512 - 3.118) compared with no activity limitation. CONCLUSION: The activity limitation of osteoarthritis patients reduces the health-related quality of life significantly and increases the probability of depression. Therefore, the treatment of osteoarthritis patients should be approached considering the psychological conditions. Moreover, early diagnosis of depressive symptoms is needed to prevent symptom deterioration and increase the compliance with rehabilitation therapy.

Using Quality of Life Scales with Nutritional Relevance after Gastrectomy: a Challenge for Providing Personalized Treatment

  • Lee, Seung Soo;Yu, Wansik;Chung, Ho Young;Kwon, Oh Kyoung;Lee, Won Kee
    • Journal of Gastric Cancer
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    • 제17권4호
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    • pp.342-353
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    • 2017
  • Purpose: This study evaluated the changes in nutritional status based on quality of life (QoL) item-level analysis to determine whether individual QoL responses might facilitate personal clinical impact. Materials and Methods: This study retrospectively evaluated QoL data obtained by the European Organisation for Research and Treatment of Cancer (EORTC) Quality of Life Questionnaire-Core 30 (QLQ-C30) and Quality of Life Questionnaire-Stomach (QLQ-STO22) as well as metabolic-nutritional data obtained by bioelectrical impedance analysis and blood tests. Patients were assessed preoperatively and at the 5-year follow-up. QoL was analyzed at the level of the constituent items. The patients were categorized into vulnerable and non-vulnerable QoL groups for each scale based on their responses to the QoL items and changes in the metabolic-nutritional indices were compared. Results: Multiple shortcomings in the metabolic-nutritional indices were observed in the vulnerable groups for nausea/vomiting (waist-hip ratio, degree of obesity), dyspnea (hemoglobin, iron), constipation (body fat mass, percent body fat), dysphagia (body fat mass, percent body fat), reflux (body weight, hemoglobin), dry mouth (percent body fat, waist-hip ratio), and taste (body weight, total body water, soft lean mass, body fat mass). The shortcomings in a single index were observed in the vulnerable groups for emotional functioning and pain (EORTC QLQ-C30) and for eating restrictions (EORTC QLQ-STO22). Conclusions: Long-term postoperative QoL deterioration in emotional functioning, nausea/vomiting, pain, dyspnea, constipation, dysphagia, reflux, eating restrictions, dry mouth, and taste were associated with nutritional shortcomings. QoL item-level analysis, instead of scale-level analysis, may help to facilitate personalized treatment for individual QoL respondents.

Numerical modeling of concrete cover cracking due to steel reinforcing bars corrosion

  • Mirzaee, Mohammad Javad;Alaee, Farshid Jandaghi;Hajsadeghi, Mohammad;Zirakian, Tadeh
    • Structural Engineering and Mechanics
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    • 제61권6호
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    • pp.693-700
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    • 2017
  • Concrete cover cracking due to the corrosion of steel reinforcing bars is one of the main causes of deterioration in Reinforced Concrete (RC) structures. The oxidation level of the bars causes varying levels of expansion. The rebar expansions could lead to through-thickness cracking of the concrete cover, where depending on the cracking characteristics, the service life of the structures would be affected. In this paper, the effect of geometrical and material parameters, i.e., concrete cover thickness, reinforcing bar diameter, and concrete tensile strength, on the required pressure for concrete cover cracking due to corrosion has been investigated through detailed numerical simulations. ABAQUS finite element software is employed as a modeling platform where the concrete cracking is simulated by means of eXtended Finite Element Method (XFEM). The accuracy of the numerical simulations is verified by comparing the numerical results with experimental data obtained from the literature. Using a previously proposed empirical equation and the numerical model, the time from corrosion initiation to the cover cracking is predicted and then compared to the respective experimental data. Finally, a parametric study is undertaken to determine the optimum ratio of the rebar diameter to the reinforcing bars spacing in order to avoid concrete cover delamination.

Experimental investigation on multi-parameter classification predicting degradation model for rock failure using Bayesian method

  • Wang, Chunlai;Li, Changfeng;Chen, Zeng;Liao, Zefeng;Zhao, Guangming;Shi, Feng;Yu, Weijian
    • Geomechanics and Engineering
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    • 제20권2호
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    • pp.113-120
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    • 2020
  • Rock damage is the main cause of accidents in underground engineering. It is difficult to predict rock damage accurately by using only one parameter. In this study, a rock failure prediction model was established by using stress, energy, and damage. The prediction level was divided into three levels according to the ratio of the damage threshold stress to the peak stress. A classification predicting model was established, including the stress, energy, damage and AE impact rate using Bayesian method. Results show that the model is good practicability and effectiveness in predicting the degree of rock failure. On the basis of this, a multi-parameter classification predicting deterioration model of rock failure was established. The results provide a new idea for classifying and predicting rockburst.