• Journal of Food Hygiene and Safety
• /
• v.22 no.4
• /
• pp.243-247
• /
• 2007

A selective analytical method of headspace-GC/MS has been applied to determine levels of benzene in beverages. Food samples were 85 including 2 fruit juices, 6 fruit beverages, 11 carbonated beverages, 55 mixed beverages, and 4 beverage concentrations, and 7 extracted beverages. For phase equilibration of headspace, sample was stirred at $40^{\circ}C$ for 30 min. The oven temperature was $60^{\circ}C$ and elevated to $180^{\circ}C$ at $15^{\circ}C/min$. The internal standard was benzene-d6. The identification was done by the selected target ions such as m/z 51, 77, and 78 and the confirmation was done by the response ratio of m/z 77 to m/z 78 between sample and standard. The overall recoveries were ranged from 91% to 101% and the limit of quantification was $1{\mu}g/kg$. The average level of benzene were $5{\mu}g/kg$ for fruit beverages, $2{\mu}g/kg$ for carbonated beverages, $7{\mu}g/kg$ for mixed beverages and $7{\mu}g/kg$ for extracted beverages.

• Korean Journal of Food Science and Technology
• /
• v.39 no.1
• /
• pp.25-28
• /
• 2007

A survey of total aflatoxin levels was conducted on 565 food samples (cereals, nuts, etc) collected in commercial markets. The determination of aflatoxins ($B_{1}$, $B_{2}$, $G_{1}$ and $G_{2}$) was performed using HPLC with fluorescence detector. The Limit of Detections (LODs) of the B group and G group were 0.05 ng/g and 0.07 ng/g, respectively. In addition, recoveries of rice, peanut butter, and red pepper flour were satisfactory. Total aflatoxin was detected 27 samples(4.8%) out of 565 samples. Incidence ratios in cereals, nuts, processed products, and other foods were 0.2, 0.4, 3.0 and 1.2%, respectively, but aflatoxin was not detected in pulse and dried fruits. The daily intake of total aflatoxin using food intakes was 0.04 ng/kg bw/day.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.17 no.3
• /
• pp.215-226
• /
• 2015

In this study, with variables the cross section area ($97m^2$, $58m^2$, $38m^2$) and the wind velocity(0.5, 1.0, 1.5, 2.0, 2.5, 3.0, 3.5 m/s), the time of getting off train dependent on the way of itself and the width of the evacuation route was analyzed, and also fire and evacuation characteristics is reviewed by cross section area of each wind velocity. As the result, if cross section become smaller, the density of harmful gases in the tunnel increased more than the ratio of decreasing cross section area. In the case of small cross sectional area, the surrounding environment from initial fire is indicated to exceed the limit criteria suggested in performance based design. In the analysis of effective evacuation time for evacuation characteristics, the effective evacuation time was the shortest in the case of evaluating effective evacuation time by the visibility. Also, there was significant difference between the effective evacuation time on the basis of performance based evaluation and the effective evacuation time obtained by analyzing FED (Fractional effective dose), one of the analysis method obtaining the point that deaths occur, against harmful gases.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.12 no.1
• /
• pp.216-221
• /
• 2011

After the year of 2000, the Korean government has abolished the limit on foreign investments. Foreign investments in the domestic market have been thriving since. In domestic stock market, the proportion of market value held by foreign investors reaches over 40%. There are many followers in the markets, asking about what kinds of the firm that foreign investors prefer. Prior researches show that foreign investors in the American and European markets prefer stocks of the firm which are well known and are geographically closer. In this paper, we attempt to define the financial characteristics of the firms in which foreigners invest in the Korean market. The result shows that foreign investors in the domestic market tend to prefer firms with high market value of capital and dividend yield. It also shows that foreign investors in the Korean market choose firms with high book value to market value over others, while the firms with high debt ratio and the portion of the largest stock holders are shunned. This research suggests that foreign portfolio investments in the Korean market have contributed to liquidity of stock market and changed the governance structure of domestic firms in a positive way.

• Magazine of the Korean Society of Agricultural Engineers
• /
• v.17 no.3
• /
• pp.3795-3814
• /
• 1975

The purpoes of this thesis is to study the effect of the variation of the beginning date of the suspension of irrigation and the length of intermittent suspension period of irrigation in the paddy field on the growth and yield of rice, so as the provide a critical limit of saving irrigation water and an irrigation method to prevent drough damage in rice cultivation. In this experiment, the rice variety adopted was NONGRIM No.29. There were seven main test plot, each test plot having a different beginning date of the suspension of irrigation. A main test plot was susdivided into five small test plots, each having a different length of the suspension period of irrigation. The results obtained in this experiment are summarized as follows: 1. The number of tillers is controlled by the treatment of the suspension of irrigation, its beginning date being early of late. The reductive effects of beginning dates of suspension upon the number of tillers. investigated on July 30, are about 84% for the treatment suspended on July 8, 87% on July 12, and 92% on July 19, respectively, in comparison with the standard plot. However. the suspenion treatments after the foregoing dates does not affect the control of their numbers. On the other hand, the lengths of intermittent suspension periods influence highly on the number of tillers to be restrained considerably, the decrease ratio ranging from 91% to 80% Both treatments on dates and periods are so intermingled that the restraining effects of suspension periods become greater as the dates of its beginning are earlier. 2. The elongation of plant hieghts also restrained considerably by the longer periods and earlier dates of suspension treatments of irrigation. Especially, the effects of the lengths of suspension periods become more serious. 3. Heading dates are delayed by two to five days through the suspension treatments of irrigation. However, the heading stage ends almost on the same day without relation to the differences between the irrigation suspension treatments. In the test plot where the suspension date of irrigation comes after the young panicle forming stage, the heading stage ends one or two days later than in the standard test plot. 4. Both culm lengths and panicle lengths show significant differences in their values, i.e., their lengths are shorter, as the begining dates of irrigation suspension are earlier and the suspension periods are longer. 5. The earlier the beginning date and the longer the period of irrigation suspension, the less is the number of panicles per hill in comparison with the standard plot. 6. The earlier the beginning date and the longer the period of irrigation suspension, the higher is the significant difference in the number of kernels per panicle in comparison with that in the standard test plot, i.e., the less is the number of kernels per panicle. 7. The earlier the beginning date and the longer the period of irrigation suspension, the lighter are the weights of rough rice and straws per hill in comparison with those in the standard plot.

• Journal of Nutrition and Health
• /
• v.40 no.1
• /
• pp.78-88
• /
• 2007

The purpose of this study was to investigate dietary fat and individual fatty acids intake pattern of 174 college women living in Seoul and Gyong-gi province through internet nutritional assessment system. Each of the subjects was required to input their own food intake for three days, which included two days during the week and one day of the weekend, on the web program directly and all of the data collected were used for statistical analysis. The mean daily caloric intake of the subjects was 1,500.9 kcal which was at 71.5% of Estimated Energy Requirement (EER). Dietary fat contributed 27.6% of the total caloric intake which was slightly higher than the recommended limit of 25%. Daily cholesterol intake was 310.0 mg, which was also high to some degree. Mean daily N6 and N3 fatty acid intake was 6.1 g and 0.9 g, respectively, and calory % calculated from each were 3.63% and 0.53%. This result showed the intake of N3 fatty acid fell in Acceptable Macronutrient Distribution Ranges (AMR) $0.5\sim1.0%$ but that of N6 fatty acid was somewhat lower than the AMDR $4\sim8%$. N6/N3 ratio 8.5/l, however, was within the desirable range $4\sim10/1$. Considering overall dietary fatty acids intake, oleic acid was the most abundant, followed by linoleic and palmitic acid. And among polyunsaturated fatty acids intake, linoleic acid was exclusively high, accounting for 97.4% of total N6 fatty acid intake. On the contrary, three fatty acids, linolenic (67.3%), DHA (21.1%) and EPA (10.0%), together supplied 98.4% of total N3 fatty acid intake. Mean P/M/S was 0.9/l.1/1.0. The subjects' intake of fat, many fatty acids and cholesterol came from diverse food groups including meats, fats and oils, milk and milk products, eggs, fish, and soybean products. Nevertheless, the subjects tended to show unfavorable fat and fatty acids intake pattern in terms of quantity and quality. Based on these results, it is important to monitor dietary fat intake pattern of the general population continuously and an internet program such as the one used for this study would be valuable, especially for assessing dietary patterns in the younger generation.

• The Korean Journal of Pesticide Science
• /
• v.15 no.2
• /
• pp.149-159
• /
• 2011

Bentazone is benzothiadiazole group herbicide, and used to foliage treatment. This herbicide have already been widely used for cereals and vegetables planting in worldwide. This experiment was conducted to establish a determination method for bentazone residue in crops using HPLC-UVD/MS. Bentazone residue was extracted with acetone (adjusted pH 1 with phosphoric acid) from representative samples of five raw products which comprised hulled rice, soybean, apple, green pepper, and Chinese cabbage. The extract was diluted with saline water, and dichloromethane partition was followed to recover bentazone from the aqueous phase. Florisil column chromatography was additionally employed for final clean up of the extract. The bentazone was quantitated by HPLC with UVD, using a YMC ODS AM 303 ($4.6{\times}250$ mm) column. The crops were fortified with bentazone at 3 levels per crop. Mean recovery ratio were ranged from 82.0% for a 0.2 mg/kg in apple to 97.9% for a 0.02 mg/kg in Chinese cabbage. The coefficients of variation were ranged from 0.5% for a 0.02 mg/kg in soybean to 9.7% for a 0.02 mg/kg in Chinese cabbage. Quantitative limit of bentazone was 0.02 mg/kg in representative five crop samples. A LC/MS with selected-ion monitoring was also provided to confirm the suspected residue. Therefore, this analytical method was reproducible and sensitive enough to determine the residue of bentazone in agricultural commodities.

• The Korean Journal of Pesticide Science
• /
• v.15 no.2
• /
• pp.125-133
• /
• 2011

Ametryn is used in USA, China, and Japan, but not introduced in Korea yet. So, MRL (Maximum Residue Level), and analytical method of ametryn were not establishment in Korea. Therefore, this experiment was conducted to establish a determination method for ametryn residue in crops using HPLC-UVD/MS. Ametryn residue was extracted with acetone from representative samples of five raw products which comprised hulled rice, soybean, apple, green pepper, and Chinese cabbage. The extract was diluted with saline water, and dichloromethane partition was followed to recover ametryn from the aqueous phase. Florisil column chromatography was additionally employed for final clean up of the extract. The ametryn was quantitated by HPLC with UVD, using a Tosoh ODS 120T ($4.6{\times}250$ mm) column. The crops were fortified with ametryn at 2 levels per crop. Mean recovery ratio were ranged from 83.7% for a 0.2 mg/kg in soybean to 91.1% for a 1.0 mg/kg in hulled rice. The coefficients of variation were ranged from 1.2% for a 1.0 mg/kg in hulled rice to 3.6% for a 1.0 mg/kg in soybean. Quantitative limit of amatryn was 0.02 mg/kg in representative 5 crop samples. A LC/MS with selected-ion monitoring was also provided to confirm the suspected residue. Therefore, this analytical method was reproducible and sensitive enough to determine the residue of ametryne in agricultural commodities.

• Journal of Veterinary Clinics
• /
• v.28 no.1
• /
• pp.7-12
• /
• 2011

This study was performed to evaluate the size and asymmetry of the lateral ventricles in CT images of three different small breed dogs. CT examinations were performed on thirty Yorkshire terriers, malteses, and shihtzu dogs, respectively. The size and asymmetry of their lateral ventricles were evaluated at three different levels of brain, and dogs were categorized on the basis of the percentage of their ventricular height (Vh) to brain height (Bh). Degree of asymmetry was also categorized based on the rVh (ratio of right and left ventricular heights) as normal (rVh < 1.5), mild (1.5 < rVh < 2.0), or severe (2.0 < rVh). Clinically insignificant ventricular dilation was common in these breed dogs. However, severe asymmetry was not presented in clinically normal dogs. We suggested 11 mm as an upper limit of ventricular size in normal small breed dogs.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.12
• /
• pp.3795-3799
• /
• 2013

The second-order rate constants ($k_N$) have been measured spectrophotometrically for nucleophilic substitution reactions of Y-substituted-phenyl 2-methylbenzoates (6a-e) with a series of cyclic secondary amines in MeCN at $25.0{\pm}0.1^{\circ}C$. Comparison of the $k_N$ values for the reactions of 4-nitrophenyl 2-methylbenzoate (6d) with those reported previously for the corresponding reactions of 4-nitrophenyl 2-methoxybenzoate (5) reveals that 6d is significantly less reactive than 5, indicating that modification of 2-MeO in the benzoyl moiety of 5 by 2-Me (i.e., $5{\rightarrow}6d$) causes a significant decrease in reactivity. This supports our previous report that aminolysis of 5 proceeds through a six-membered cyclic intermediate, which is highly stabilized through intramolecular H-bonding interactions. The Br${\o}$nsted-type plot for the reactions of 6d with a series of cyclic secondary amines is linear with ${\beta}_{nuc}=0.71$, which appears to be a lower limit of ${\beta}_{nuc}$ for a stepwise mechanism with breakdown of an intermediate ($T^{\pm}$) being rate-determining step (RDS). The Br${\o}$nsted-type plot for the reactions of 6a-e with piperidine is curved, i.e., the slope of Br${\o}$nsted-type plot (${\beta}_{lg}$) decreases from -1.05 to -0.41 as the leaving-group basicity decreases. The nonlinear Br${\o}$nsted-type plot has been taken as evidence for a stepwise mechanism with a change in RDS (e.g., from the $k_2$ step to the $k_1$ process as the leaving-group basicity decreases). Dissection of $k_N$ into the microscopic rate constants associated with the reactions of 6a-e with piperidine (e.g., $k_1$ and $k_2/k_{-1}$ ratio) also supports the proposed mechanism.