• Title/Summary/Keyword: rate-limiting

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Theoretical Analysis on Bifurcation Behavior of Catalytic Surface Reaction on Nonadiabatic Stagnation Plane (비단열 정체면에서 촉매 표면반응의 천이 거동에 대한 이론적 해석)

  • Lee, Su- Ryong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.6
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    • pp.697-704
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    • 2004
  • Bifurcation behavior of ignition and extinction of catalytic reaction is theoretically investigated in a stagnation-point flow. Considering that reaction takes place only on the catalytic surface, where conductive heat losses are allowed to occur, activation energy asymptotics with a overall one-step Arrhenius-type catalytic reaction is employed. For the cases with and without the limiting reactant consumption, the analysis provides explicit expressions, which indicate the possibility of multiple steady-state solution branches. The difference between the solutions with and without reactant consumption is in the existence of an upper solution branch, and the neglect of reactant consumption is inappropriate for determining extinction conditions. For larger values of reactant consumption, the solution response is all monotone, suggesting that multiple solutions are not possible. It is shown that bifurcation Damkohler numbers increase (decrease) with increasing of conductive heat loss (gain) on the catalytic surface, which means that smaller (larger) values of the strain rate allow the surface reaction to tolerate larger heat losses (gains). Lewis number of the limiting reactant can also significantly affect bifurcation behavior in a similar way to the effect of heat loss.

A model for columnar-dendritic solidification of binary alloys accounting for dendrite tip undercooling (선단과냉을 고려한 이원합금의 주상 수지상응고 모델)

  • Yu, Ho-Seon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.5
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    • pp.698-707
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    • 1998
  • A simplified model for predicting microsegregation during columnar-dendritic solidification of binary alloys is developed, in which back diffusion, dendrite arm coarsening and dendrite tip undercooling are simultaneously incorporated. The inclusion of tip undercooling is accomplished by modifying the initial conditions of the existing solute diffusion model, in such forms that tip undercooling depresses the beginning of solidification below the liquidus temperature, and that the secondary arm spacing evolves in accordance with the minimum undercooling theory. Sample calculations for the well-known benchmark system show that the present predictions not only consist with the extablished limiting cases, but also agree favorably with the available experimental data within a reasonable tolerance. In particular, a typical decreasing trend in the eutectic fraction at high cooling rates is successfully resolved. Comparison of the individual and combined effects of characteristic parameters in reference with the limiting cases reveals the interactions among parameters. Every parameter plays the role of reducing the eutectic fraction, and the degree of influence depends primarily on the cooling rate. Coarsening enhances the effect of tip undercooling, while suppressing that of back diffusion. A vigorous back diffusion seems to restrain the apperance of the undercooling effect. Overall, each contribution of the three parameters to microsegregation is estimated to be of the same order, which suffices to justify the present study.

A Study on the Limiting Factors in Wastewater Treatment by Contact Oxidation Process (접촉담화공정에 의한 폐수처이에 있어서의 제한요권에 관한 연구)

  • 황상용;손종열;우완기
    • Journal of environmental and Sanitary engineering
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    • v.5 no.2
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    • pp.45-52
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    • 1990
  • This study is to discuss limiting factors influenced on the removal efficiency of organic materials investigated using the polypropyrene biofilter which appropriate to attach micro-organism in order to apply the contact oxidation proce,:5. The results obtained in the experiment were as follows : 1. In the range o: pH 4.0~ 12.0 was obtained the removal efficiency of COD higher than 85% It was proved that variation of pH(4.0 ~ 12.0) was nothing to do with the removal efficiency of substrate in continuous reactor. 2. Temperature to obtain removal efficiency of COD higher than 85% was $10^{\circ}$ ~$40^{\circ}$. Removal efficiency of COD was no less than those at high temperature if MLVSS concentration was maintained 8,000~ 15,000 m/1. 3. In the continuous reactor, the volumetric loading of COD for removal efficiency higher than 95% had to be 0.5~1.5 kg COD/.d below. And then the HRT was Bhrs. 4. In comparison with the conventional activate sludge process, the contact oxidation process was excellent in removal efficiency, sludge production rate and maintenance.

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Analysis of Transient Characteristics of a SFCL Applied Into Third-winding Transformer in a Single Line-to-ground Fault (1선 지락 사고 시 3 권선 변압기에 적용된 초전도 한류기의 동작 특성 분석)

  • Choi, Hye-Won;Choi, Hyo-Sang;Jung, Byung-Ik
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.7
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    • pp.1033-1037
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    • 2013
  • Coercion transformer is commonly used in the electrical grid which in three phase of distribution system. The accident of the electrical grid is divided into a single, a double, a third line-to-ground faults and a double, a third line-to-line faults. A single line-to-ground fault accounts for nearly 75[%] among them. In this research, when a Superconducting Fault Current Limiters (SFCL) was applied to the three phase power system, operation in a single line-to-ground fault and limiting characteristics of fault current according to turns ratio of third winding were analyzed. When a single line-to-ground fault happened, secondary winding's circuit was open. Then third winding's circuit with a SFCL was closed. So fault current was limited by diverted circuit. At this time, we could find out that size of the limited fault current could be changed according to third winding rate. We confirmed that limiting operation of the fault current was carried out within one-period. These results will be utilized in adjusting the size of the SFCL.

Hypoxic repression of CYP7A1 through a HIF-1α- and SHP-independent mechanism

  • Moon, Yunwon;Park, Bongju;Park, Hyunsung
    • BMB Reports
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    • v.49 no.3
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    • pp.173-178
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    • 2016
  • Liver cells experience hypoxic stress when drug-metabolizing enzymes excessively consume O2 for hydroxylation. Hypoxic stress changes the transcription of several genes by activating a heterodimeric transcription factor called hypoxia-inducible factor-1α/β (HIF-1α/β). We found that hypoxic stress (0.1% O2) decreased the expression of cytochrome P450 7A1 (CYP7A1), a rate-limiting enzyme involved in bile acid biosynthesis. Chenodeoxycholic acid (CDCA), a major component of bile acids, represses CYP7A1 by activating a transcriptional repressor named small heterodimer partner (SHP). We observed that hypoxia decreased the levels of both CDCA and SHP, suggesting that hypoxia repressed CYP7A1 without inducing SHP. The finding that overexpression of HIF-1α increased the activity of the CYP7A1 promoter suggested that hypoxia decreased the expression of CYP7A1 in a HIF-1-independent manner. Thus, the results of this study suggested that hypoxia decreased the activity of CYP7A1 by limiting its substrate O2, and by decreasing the transcription of CYP7A1.

Experimental Study on Temporary Overvoltage Characteristics of MOV Based Surge Protective Devices (MOV 기반 서지보호기의 일시과전압 특성에 대한 실험적 연구)

  • Shim, Hae-Sup;Jeon, Tae-Hyun
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.1
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    • pp.71-77
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    • 2010
  • Protection against lightning surge is an essential part of almost any electrical and electronic equipment today. Metal Oxide Varistor(MOV) is the single most important component in the overwhelming majority of the Surge Protective Devices(SPD) designated to provide such protection. In this paperr various types of MOV based SPD are inspected and experiments are carried out on the side effects of the low Measured Limiting Voltage(MLV) characteristics. Experiment results show that a lower MLV could cause a higher Temporary Overvoltage(TOV)-induced SPD failure rate in the field, and SPD are more likely to be victims rather than protectors in a TOV scenario. This means that from a safety perspective, the SPD should be specified with higher TOV withstand capability(UT) and faster SPD disconnector.

Calcium-related genes associated with intracellular calcification of Emiliania huxleyi (Haptophyta) CCMP 371

  • Nam, Onyou;Shiraiwa, Yoshihiro;Jin, EonSeon
    • ALGAE
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    • v.33 no.2
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    • pp.181-189
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    • 2018
  • Emiliania huxleyi (a haptophyte) is the most abundant coccolithophore species that produces delicate calcite scales called coccoliths. In this study, we identified several candidate genes associated with coccolith production by comparing the transcriptomes of the calcifying (CCMP 371) and non-calcifying (CCMP 2090) strains of E. huxleyi. Among the candidates, genes highly expressed in CCMP 371 were identified. To confirm whether these genes are associated with calcification, we modulated coccolith production in CCMP 371 by culturing it at different calcium concentrations. At an ambient (10 mM) concentration of calcium in the growth medium, CCMP 371 sustained its calcifying ability. However, at a low (0.1 mM) concentration or absence of calcium, there was no calcite formation, demonstrating that calcium-limiting conditions negatively affect calcification. We also evaluated the expression patterns of the putative genes in cells grown at different calcium concentrations by quantitative reverse transcription polymerase chain reaction. In addition, we showed that the growth rate of cells cultured under calcium-limiting conditions does not differ from that under ambient conditions. Further studies are required to investigate the roles of the putative calcification-associated genes at the molecular level.

A Study on the Rectifying Inspection Plan & Life Test Sampling Plan Considering Cost (소비자 보호를 위한 선별형 샘플링 검사와 신뢰성 샘플링 검사의 최적설계에 관한 연구)

  • 강보철;조재립
    • Journal of Korean Society for Quality Management
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    • v.30 no.1
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    • pp.74-96
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    • 2002
  • The objectives of this study is to suggest the rectifying sampling inspection plan considering quality cost. Limiting quality level(LQL) plans(also called LTPD plans) and outgoing quality(OQ) plans are considered. The Hald's linear cost model is discussed with and without a beta prior for the distribution of the fraction of nonconforming items in a lot. It is assumed that the sampling inspection is error free. We consider the design of reliability acceptance sampling plan (RASP) for failure rate level qualification at selected confidence level. The lifetime distribution of products is assumed to be exponential. MIL-STD-690C and K C 6032 standards provide this procedures. But these procedures have some questions to apply in the field. The cost of test and confidence level(1-$\beta$ risk) are the problem between supplier and user. So, we suggest that the optimal life test sampling inspection plans using simple linear cost model considering product cost, capability of environment chamber, environmental test cost, and etc. Especially, we consider a reliability of lots that contain some nonconforming items. In this case we assumed that a nonconforming item fail after environmental life test. Finally, we develope the algorithm of the optimal sampling inspection plan based on minimum costs for rectifying inspection and RASP. And computer application programs are developed So, it is shown how the desired sampling plan can be easily found.

Effects of Upstream Wake Frequency on the Unsteady Boundary Layer Characteristics On a Downstream Blade (상류 후류의 발달 주파수가 하류 익형의 비정상 경계층 거동에 미치는 영향)

  • Bae Sang Su;Kang Dong Jin
    • 한국전산유체공학회:학술대회논문집
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    • 1999.11a
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    • pp.181-186
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    • 1999
  • The effects of the frequency of upstream gust on the unsteady boundary characteristics on a downstream blade was simulated by using a Navier-Stokes code. The Navier-Stokes code is based on an unstructured finite volume method and uses a low Reynolds k-e turbulence model to close the momentum equations. The MIT flapping foil experiment set-up is used to simulate the interaction between the upstream wake and a blade. The frequency of the upstream wake is simulated by varying rate of pitching motion of the flapping airfoils. Three reduced frequencies. 3.62. 7.24. and 10.86. are simulated. As the frequency increases, the unsteady fluctuation on the surfaces of the downstream hydrofoil is shown to decrease while the upstream flapper wake has larger first harmonics of y-velocity component. The unsteady vortices are shown to interact with each other and. as a result. the upstream wake becomes undiscernible inside the inner layer. The turbulence kinetic energy shows a similar behavior. Limiting streamlines around the trailing edge of the flapper are shown to conform with the unsteady Kutta condition for a round trailing edge. while limiting streamlines around the trailing edge of the hydrofoil conforms with the unsteady Kutta condition for a sharp edge.

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A study on understanding of differentiation (미분의 이해에 대한 연구)

  • Oh, Hye-Young
    • Communications of Mathematical Education
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    • v.32 no.2
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    • pp.131-146
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    • 2018
  • Differentiation with integration is an important subject which is widely applied in mathematics, natural science, and engineering. Derivative is an important concept of differentiation. But students don't understand its concept well and concentrate on acquiring only the skill to solve the standardized calculus problem. So they are poor at understanding of the concept of differentiation. In this study, after making a survey of differentiation on college students, we try to analyze errors which appeared in solving differentiation problem and investigate mathematics process of limiting process inherent in the derivative and historical development about derivative. Thus, we try to analyze the understanding of differentiation and present the results about this.