• Title/Summary/Keyword: rate of length change

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Determination of Reorganization Energy from the Temperature Dependence of Electron Transfer Rate Constant for Hydroquinone-tethered Self-assembled Monolayers (SAMs)

  • Park, Won-choul;Hong, Hun-Gi
    • Bulletin of the Korean Chemical Society
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    • v.27 no.3
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    • pp.381-385
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    • 2006
  • The temperature dependence on the electron transfer rate constant $(k_{app})$ for hydroquinone redox center in $H_2Q(CH_2)_n$SH-SAMs (n = 1, 4, 6, 8, 10, and 12) on gold electrode was investigated to obtain reorganization energy $(\lambda)$ using Laviron’s formalism and Arrhenius plot of ln $[k_{app}/T^{1/2}]$ vs. T^{-1} based on the Marcus densityof-states model. All the symmetry factors measured for the SAMs were relatively close to unity and rarely varied to temperature change as expected. The electron tunneling constant $(\beta)$ determined from the dependence of the $k_{app}$ on the distance between the redox center and the electrode surface gives almost the same $\beta$ values which are quite insensitive to temperature change. Good linear relationship of Arrhenius plot for all $H_2Q(CH_2)_n$SH-SAMs on gold electrode was obtained in the temperature range from 273 to 328 K. The slopes n Arrhenius plot deduced that $\lambda$ of hydroquinone moiety is ca. 1.3-1.4 eV irrespectively of alkyl chain length of the electroactive SAM.

Anticancer and Antioxidant Effects of Saturated Fatty Acid against Skin Cancer Cell Lines (포화지방산의 피부암 세포주에 대한 항암 및 항산화 효과)

  • Han, Du-Seok;Park, Yoon-Kyu;Kim, Hyun-Jin;Lee, Jae-Suk;Baek, Seung-Hwa
    • Journal of Society of Preventive Korean Medicine
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    • v.12 no.3
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    • pp.47-58
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    • 2008
  • The anticancer and antioxidant effect of different lengths of saturated fatty acids was tested on NIH3T3 fibroblasts and human skin melanoma cellsn in this study. The cell existence rate and antioxidizing capacity and optic reservation of cells were observed. This saturated fatty acid was concentration-dependent. IC50 Concentrations in NIH3T3 fibroblasts, human skin melanoma cells and DPPH radical scavenging activity of fatty acid was increasing the order of carbochain length ; caprylic acid < lauric acid < palmitic acid < stearic acid. The reduction in cell number and morphological change in human skin melanoma cells was increasing the order of carbochain length ; caprylic acid < lauric acid < palmitic acid < stearic acid. These results suggest that carbochain length of fatty acid can be used as structure-activity relationships for anticancer and antioxidant.

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Stress-Strain-Strain Rate of Overconsolidated Clay Dependent on Stress and Time History (응력이력과 시간이력에 따른 과압밀점토의 응력-변형-변형률 속도)

  • 한상재;김수삼;김병일
    • Journal of the Korean Geotechnical Society
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    • v.19 no.1
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    • pp.143-150
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    • 2003
  • This study deals with the stress-strain-strain rate behaviour of overconsolidated clay. Consolidated-drained stress path tests were performed on the stress-time dependent condition. Stress history consists of rotation angle of stress path, overconsolidation ratio, and magnitude of length of recent stress path. Time history includes loading rate of recent and current stress path. Test results show that all influence factors have an increasing strain rate with time, and the strain rate varies with the change of the rotation angle of stress path. With the increase of overconsolidation ratio and loading rate of current stress path, the strain rate also increases. For the stress history, correlation between stress-strain and strain rate is indicated but the time history is not.

Modeling of Capillary Filling Length in Silwet L-77 Added Poly(Dimethylsiloxane) (PDMS) Microchannels (Silwet L-77 이 포함된 Polydimethylsiloxane(PDMS) 마이크로 채널의 유동 길이 모델링)

  • Lee, Bom-Yee;Lee, Bong-Kee
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.8
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    • pp.823-829
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    • 2014
  • In the present study, simple models were proposed to predict the capillary-driven flow length in a surfactant-added poly(dimethylsiloxane) (PDMS) rectangular microchannel. Owing to the hydrophobic nature of PDMS, it is difficult to transport water in a conventional PDMS microchannel by means of the capillary force alone. To overcome this problem, microchannels with a hydrophilic surface were fabricated using surfactant-added PDMS. By measuring the contact angle change on the surfactant-added PDMS surface, the behavior was investigated to establish a simple model. In order to predict the filling length induced by the capillary force, the Washburn equation was modified in the present study. From the investigation, it was found that the initial rate-of-change of the contact angle affected the filling length. Simple models were developed for three representative cases, and these can be useful tools in designing microfluidic manufacturing techniques including MIcroMolding In Capillaries (MIMIC).

An investigation of the behavior in the corner crack propagation of Al-Alloy by the plane bending fatigue (평면 굽힘 피로하중에 의한 알루미늄 합금재의 모서리 균열 전파거동에 관한 연구)

  • 김영식;김영종
    • Journal of Advanced Marine Engineering and Technology
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    • v.8 no.1
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    • pp.49-63
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    • 1984
  • The 5086-H116 Al-Alloy plate specimens having an edge through-thickness notch were investigated to find out the characteristics of the corner crack propagation by the plane bending fatigue. The experiments were also carried out in order to clarify the change of the corner crack propagation behaviour due to the various materials and their thicknesses. In addition, the retardation effect of overload on the corner crack propagation was quantatively studied. Main results obtained are as follows; 1. In the case of estimating the crack propagation rate of the corner crack, it is more reasonable to consider the growth rate of fracture surface area than that of crack length. 2. The shape of the corner crack growing in the plane plate under the bending fatigue can be estimated. 3. The crack propagation rate increases with the increasing of the thickness and the decreasing of the Young's modulus of materials. 4. Regardless of a thickness and kind of materials of specimen, the characteristics of the corner crack propagation can be concluded. 5. The retardation effect of overload is distinct in the corner crack propagation.

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An Experimental Study on Tip Velocity and Downstream Recirculation Zone of Single Groyne Conditions (단일 횡수제 조건에 따른 선단부 유속과 재순환 영역에 대한 실험 연구)

  • Kang, Joon-Gu;Yeo, Hong-Koo;Kim, Sung-Jung
    • Journal of Korea Water Resources Association
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    • v.38 no.2
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    • pp.143-153
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    • 2005
  • Recently, the concern of groynes that provide us with various ecological environment and improvement of scenary near river as well as hydraulic improvement has greatly increased for naturalized river and ecological river restoration. However there is no adequate design guidelines in Korea. Furthermore there is lack of research for installation of groynes in Korea. Thus, in this study, we have conducted hydraulic modeling test for kinds of groyne and changes of permeability and made a study of the analysis for installation factor of groyne. Experimental conditions were the fixed bed model for flow pattern of groyne tip and separation length about changes of groyne length and permeability. The Experiments were conducted to measure velocity and drift angle at groyne tip. The main study kas measured the groyne tip velocity for a factor of scour and drift angle for velocity increase at center of channel. We have suggested the equation about groyne tip velocity rate(tip velocity/ approach velocity) and area rate(groyne area/ flow area). And In recirculation zone of groyne downstream, To study the basic data of groyne about installation interval has analyzed the change of separation length and incidence angle. We have suggested the equation about separation length rate(separation length/ groyne length), changes of permeability and installation angle.

A Patient's Satisfaction with Denture in the Old People (노인들의 의치 장착 후의 만족도에 관한 연구)

  • Lee, In-Kyu;Song, Yun-Hee
    • Journal of Technologic Dentistry
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    • v.23 no.2
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    • pp.61-74
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    • 2002
  • This experiment was to find out the complacency of wearing dentures and the linkage to the quality of life style of oldsters 60 years old and over. 122 numbers of oldsters who came to aid to the health center were put to survey. This was taken place within the areas of Deajun, Koonsan, Mooju and Jinahn, thus procured the following result. 1. The length of edentulous period of 1-6years of oldsters aged around 60s showed 26.0%. The oldsters with edentulous period of over 7years aged in the 70s showed 26.1 % and 56.0% on oldsters aged in the 80s. This shows that as the age increases the edentulous period lengthens. (P<0.05) The length of time of using the denture shows. llyears or over on women 41.9%, less than 6years on men 71.4% as the highest rate. 11 years or over on towns/subcounty show 57.5%, small and medium cities more than 1 year 63.6%, less than six years also 63.6% and Kwangyuk city 47.6%. 2. The complacency on medical treatment of dentures was highest in Kwangyuk city of 61.3%, compared to towns/subcounty of 50.8% and small and medium cities of 33.3%. (P<0.05) 3. The complacency on mastication and pronunciation appears, 2.74% in Kwangyuk city, 3.10% in towns/ subcounty which is higher than the small and medium cities showing 1.09% on average. Satisfaction rate tends to be higher as the length of time of using the denture is longer. 4. Inconvenience on eating habits caused by dentures were felt by women. Wanting to get a new denture was 25.6% by women showing much higher rate than that of men which is 2.8% by men. (P<0.05) 5. The complacency of change in their life style after wearing the dentures were higher in Kwangyuk city of 64.5% whereas it showed 27.0% in towns! subcounty and 16.7%in small and medium cities. (P<0.05)

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A Study on Measuring Vehicle Length Using Laser Rangefinder (레이저 거리계를 이용한 차량 전장 측정 방법에 관한 연구)

  • Ryu, In-Hwan;Kwon, Jang-Woo;Lee, Sang-Min
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.15 no.1
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    • pp.66-76
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    • 2016
  • Determination of type of a vehicle is being used in various areas such as collecting tolls, collecting statistical traffic data and traffic prognosis. Because most of the vehicle type classification systems depend on vehicle length indirectly or directly, highly reliable automatic vehicle length measurement system is crucial for them. This study makes use of a pencil beam laser rangemeter and devises a mechanical device which rotates the laser rangemeter. The implemented system measures the range between a point and the laser rangemeter then indicates it as a spherical coordinate. We obtain several silhouettes of cross section of the vehicle, the rate of change of the silhouettes, signs of the rates then squares the rates to apply cell averaging constant false alarm rate (CA-CFAR) technique to find out where the border is between the vehicle and the background. Using the border and trigonometry, we calculated the length of the vehicle and confirmed that the calculated vehicle length is about 94% of actual length.

Effects of continuous involved weight bearing training on symmetrical weight supporting rate improvement and gait characteristics of patients with Hemiplegia (전자체중계를 이용한 환측 체중부하훈련이 편마비 환자의 제중지지율과 보행에 미치는 효과)

  • Lee, Suk-Min;Shim, Tae-Ho
    • Journal of Korean Physical Therapy Science
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    • v.10 no.1
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    • pp.7-17
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    • 2003
  • The purpose of this study was to investigate the effect of the involved lower limb weight bearing training on symmetrical weight supporting rate improvement and gait characteristics of patients with hemiplegia including their gait velocity, cadence, stride length, step length of the non affected side, step length of the affected side, foot angle of the non affected side, foot angle of the affected side, base of support, and so on. The subject of the study was 28 men and women patients with hemiplegia from 22 to 77 age, among patients who doctor diagnosed as hemiplegia due to stroke or traumatic brain injury, were possible to do independent gait more than 45m without others assistance, the flexion contracture of hip pint was less than $15^{\circ}$, did not have contracture for knee pint and one more than $5^{\circ}$ for ankle joint, did not have contraindication for exercise or gait did not show visual defect due to brain injury. The patients, the subject of the study, were classified into 14 patients of treatment. group applying continuous involved weight bearing with general therapeutic exercise and 14 patients of control group applying general therapeutic exercise, and then analyzed their gait before and after exercise. Temporal distance gait analysis(Boening, 1977) was used to analyze their gait, and ink foot-print was applied as one of measurement methods. However, it was statistically signifiant in the change rate(%) of gait characteristics, and treatment group's patients with hemiplegia had been highly changed in gait characteristics in comparison with control group. From the above-mentioned results, could find that continuous involved weight bearing training for patients with hemiplegia was effective to improve their gait ability and it could increase the ability in comparison with general exercise.

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Community Structure and Productivity of Phytobenthos in Juckdo (Eastern Coast of Korea) II. Seasonal Changes of Algal Vegetation in Relation to Annual Growth of Large Brown Algae (저서식물의 군집구조와 생산성(동해안, 죽도) II. 해조류 식생의 계절변화와 대형갈조류 성장상태의 관계)

  • 고철환
    • Journal of Plant Biology
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    • v.26 no.4
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    • pp.181-190
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    • 1983
  • Seasonal occurrence of benthic algae and changes of subtidal vegetation were studied for their species composition, diversity and biomass during 1982 and 1983 at several selected sites at Juckdo Island (38$^{\circ}$12'N, 128$^{\circ}$32'E), eastern coast of Korea. Three large brown algae which played a role in change of algal vegetation through their great biomass were investigated with regard to their seasonal growth. Large brown algae such as Undaria pinnatifida, Costaria costata, Laminaria japonica, Agarum cribrosum, Sargassum confusum and S. hornerii constitute the major portion of vegetation in this area throughout the year. Algal vegetation in spring time is characterized by dominance of species U. pinnatifida and C. costata, whereas the summer vegetation by S. confusum and S. hornerii. In autumn large brown algae are shedded and only small algae, such as Chondrus ocellatus and Grateloupia filicina, remain. The vegetation in winter is dominated by the growth of U. pinnatifida and C. costata. Monthly changes in mean length and weight of randomly collected U. pinnatifida, C. costata and S. confusum are as follows; U. pinnatifida occurs from December to June and shows their maximum growth during March (120 cm in length, 201 g/individual in wet weight), its maximum growth rate is 1.4 cm/day, 3.3 g/day in this month. The growth season of C. costata is very similar to U.pinnatifida, but their average maximum length(110 cm) and weight (106 g/ind.) are lower than U. pinnatifida. The greatest growth rate is during March (1.8 cm/day, 2.0g/day). S. confusum is present throughout the year and reaches the maximum growth (102 cm, 63g/ind.) in July. Maximum growth rate (1.5 cm/day, 1.2 g/day) occurs also during this month. U. pinnatifida and C. costata show different months of maximum growth evidently during the two year. This seems to be caused by a considerable damage to the local vegetation followed by heavy storm in February 1983.

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