• Title/Summary/Keyword: rate dependent

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Oxidative Degradation Kinetics of Tocopherols during Heating

  • Chung, Hae-Young
    • Preventive Nutrition and Food Science
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    • v.12 no.2
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    • pp.115-118
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    • 2007
  • Tocopherols are important lipid-phase antioxidants that are subject to heat degradation. Therefore, kinetic analyses for oxidative degradation of tocopherols as a function of temperatures and times were performed. Alpha-, gamma- and delta-tocopherols dissolved in glycerol were heated at 100${\sim}$250$^{\circ}C$ for 5~60 min. Oxidized tocopherols were analyzed by HPLC using a reversed phase ${\mu}$-Bondapak C$_{18}$-column with two kinds of elution solvent systems in a gradient mode. The degradation kinetics for tocopherols followed a first-order kinetic model. The rate of tocopherol degradation was dependent on heating temperatures. The degradation rate constants for ${\gamma}$- and ${\delta}$-tocopherols were higher than those for ${\alpha}$-tocopherol. The experimental activation energies of ${\alpha}$-, ${\gamma}$- and ${\delta}$- tocopherols were 2.51, 6.05 and 5.34 kcal/mole, respectively. The experimental activation energies for the oxidative degradation of ${\gamma}$- and ${\delta}$-tocopherols were higher than that of ${\alpha}$-tocopherol.

Characteristics of Rotating Stall in a Centrifugal Compressor with Vaned Diffuser (원심압축기 베인 디퓨저에서의 선회실속 특성)

  • Lee, Du-Yeol;Kang, Chang-Sik;Shin, You-Hwan;Kim, Kwang-Ho
    • 유체기계공업학회:학술대회논문집
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    • 2001.11a
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    • pp.99-105
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    • 2001
  • In this study, the instability of a centrifugal compressor with vaned diffuser was investigated. During unstable operation of the test compressor, pressure fluctuations at different diffuser radius ratios were measured by using high frequency pressure transducers. Two different types of stall, mild and deep stall, were observed alternately and irregularly at some flow rate where the compressor performance was steeply deteriorated. In this transient zone, the size of rotating stall cell was estimated through the Wavelet transform analysis. It was about 45 percents of rotor circumferential space at 3000 rpm and not dependent on flow rate.

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Comparison with Biodegradation of Anionic Surfactants (계면활성제의 생분해 비교)

  • 최대웅;이광현;김인효
    • Journal of Environmental Health Sciences
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    • v.21 no.4
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    • pp.37-43
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    • 1995
  • The course of biodegradation of anionic surfactants, Linear Alkylbenzene Sulfonates(LAS), Sodium Lauryl Ethoxylate Sulfonate(SLES), and Sodium Lauryl Sulfonates(SLS), which are mainly used to make detergents and shampoo, was investigated. The degree of biodegradation was studied as a function of concentration, volumetric flow rate, and temperature in Naktong River. MethyleneBlue Active Substances(MBAS), Total Dissolved Organic Carbon(TOC), and Chemical Oxygen Demand(COD) were measured to evaluate the degree of biodegradation. The degree of biodegradation of LAS was highly dependent upon the concentration and was increased as the concentration was decreased and that of SLES and SLS was almost constant at the concentration of less than 200 ppm, but was much increased as the volumetric flow rate was increased or the temperature was increased.

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An Analytical Study on the Turbocharger Engine Matching of the Marine Four-Stroke Diesel Engine (선박용 4행정 디젤기관의 배기 과급기 엔진 매칭에 관한 해석적 연구)

  • Choi, Ik-Soo;Kim, Hyun-Kyu;Yoo, Bong-Whan
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.11a
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    • pp.86-87
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    • 2005
  • The combustion characteristics of the D.I. diesel engine are largely dependent on the air-fuel ratio and the gas exchange process. The main factors are the shape of combustion chamber, fuel injection system, air flow inside the cylinder, intake air mass flow rate and so forth. Because these factors affect the combustion in a mutual and combined manner, it is very important to clearly understand the correlation of these factors in order to provide the combustion improvement plans. In this paper, we studied the performance and the gas exchange process of marine four-stroke engine using the engine cycle simulation. Also, we predicted briefly turbocharger engine matching.

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A Study on the Micro Machining in Polyurethane by Excimer Laser (엣시머 레이져를 이용한 폴리우레탄의 미세 가공에 관한 연구)

  • 김재구;이성국;윤경구
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.04a
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    • pp.366-370
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    • 1997
  • This paper descibes a micro groove machining process on the polyurethane biopolymer by KrF excimer laser. To investigate the etch charcteristics of polyurethane biopolymer quantitatively,laser system for ablation was installed with high precison moter and then polymer ablation experiment, in which paramteters were fluence,pulse repetition rate,numbers of pulses and assist gas, was carred out. In this experiment, we found out that the value of critical energy density for ablation is 30mJ/cmsup2/ and the etching rate is more dependent on the pulse number and fluence than any other pamameter. Finally, we machined micro grooves for fiexibility as width 300.mu.m depth 100.mu.m and port for micro-devices mounting as length 100.mu.m width 300.mu.m depth .mu.m on the outer wallof polyurethane biopolymer tube which is used as medical device.

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Characteristics of Shear-Thinning Fluid Viscosity under Traversal Vibration (진동장에서의 전단박화 유체 점도의 특성 연구)

  • Ku Yun-Hee;Lee Ji-Hyung;Shin Sehyun
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.317-320
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    • 2002
  • The effect of vibration on the viscosity of a shear-thinning fluid was investigated with a newly designed pressure-scanning capillary viscometer. The viscometer was designed to measure non-Newtonian viscosity continuously over a range of shear rates at a time. Low frequency vibration was applied perpendicularly to the direction of the flow. The effect of the transversal vibration was investigated for both Newtonian fluids and non-Newtonian fluids. The experimental results showed that the vibration had no effect on the viscosity of the Newtonian fluids. However, the vibration caused a significant reduction of the shear-thinning fluid viscosity. The viscosity reduction was strongly dependent on both vibration frequency and shear rate. In addition, the viscosity reduction was affected by the amplitude of vibration, and, the bigger amplitude applied, the more viscosity reduction occurred.

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Influence of Side Leakage Loss on the Performance of a Micro Positive Displacement Hydraulic Turbine (마이크로 용적형 수차의 측면누설손실이 성능에 미치는 영향)

  • Choi, Young-Do
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.2
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    • pp.291-295
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    • 2006
  • Recently, greenhouse effect by $CO_2$ gas emitted by use of fossil fuel causes earth environmental problem. As a countermeasure of the global warming. micro hydropower under 100kW becomes the focus of attention for its clean and renewable energy sources. Newly developed micro positive displacement hydraulic turbine shows high efficiency and good applicability for the micro hydropoewer. The purpose of this study is to clarify the influence of leakage loss and effective head on the performance of the positive displacement hydraulic turbine for the further improvement of the turbine performance. The results show that the turbine. with a smaller side clearance. has much higher efficiency than that with bigger side clearance and it can sustain the high efficiency under the wider range of operation conditions. The turbine torque is proportional to the effective head and independent of the flow rate. The leakage is also dependent on the effective head but nearly independent of the flow rate.

Start-up dynamics in a CMSMPR crystallizer (CMSMPR 결정화기의 시동 특성 연구)

  • 신영준;이철수
    • 제어로봇시스템학회:학술대회논문집
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    • 1986.10a
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    • pp.200-204
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    • 1986
  • Particle size distribution in a Continuous Mixed Suspension Mixed Crystal Removal (CMSMPR) crystallizer has been analyzed using the Population Balance (PB) model. This method presents difficulties when the growth rate of crystal depends on the crystal size. Recent studies indicate that in many cases the growth rate is dependent on size when the crystal sizes are small. In this study, a Residence Time Distribution(RTD) model was proposed to take the size dependence into account together with an appropriate numerical scheme. When compared with the approximate results based on PB model, RTD model results showed improvements also a nucleation effect which is normally unimportant for steady state analysis. Start-up data for NaCl-Water-Ethanol system was compared with computed values.

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A Study on MLP Neural Network Architecture and Feature Extraction for Korean Syllable Recognition (한국어 음절 인식을 위한 MLP 신경망 구조 및 특징 추출에 관한 연구)

  • 금지수;이현수
    • Proceedings of the IEEK Conference
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    • 1999.11a
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    • pp.672-675
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    • 1999
  • In this paper, we propose a MLP neural network architecture and feature extraction for Korean syllable recognition. In the proposed syllable recognition system, firstly onset is classified by onset classification neural network. And the results information of onset classification neural network are used for feature selection of imput patterns vector. The feature extraction of Korean syllables is based on sonority. Using the threshold rate separate the syllable. The results of separation are used for feature of onset. nucleus and coda. ETRI's SAMDORI has been used by speech DB. The recognition rate is 96% in the speaker dependent and 93.3% in the speaker independent.

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The Effects of Various Dehiscence Materials, Growth Regulators and Fungicides on the of Ginseng Seed ( Panax ginseng C A. Meyer ) (개갑처리재료, 생장조절제 및 살충제가 고려인삼종자의 개갑에 미치는 영향)

  • 양덕조;천성기
    • Journal of Ginseng Research
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    • v.6 no.1
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    • pp.56-66
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    • 1982
  • The effects of various dehiscent application such as dehiscent materials (big chaffs, vermiculite etc.), growth regulators and agricultural chemicals (plant protector.) on stimulation of dehiscence and shortening of dehiscent period were investigated Results obtained were as follows : 1. The moisture content of endosperm and seed coat at 10 day after dehiscent application amounts between 40% and 50%. 2. Endosperm diameter was increased with time of stratification, and the embryo growth showed in linear function, 3. Non-dehiscent seed showed also normally development of embryo, and the property of dehiscence dependent from physico-chemical nature of ginseng seed coat. 4. The best dehiscent materials were big chaffs and followed vermiculite, sand and sand with big chaffs. 5. The effect of dehiscence of ginseng seed showed higher activity in fungi than in bacteria in general. 6. Agricultural chemicals ( plant Protector) reduced the dehiscent rate of ginseng seed 7. The best timing of dehiscent treatment was between August 1 and August 10 but the smaller amount of dehiscent rate after August 10 dehiscent appllication indicated that big chaffs and growth regulator treatment may be controlled shortening of dehiscent period of ginseng seed.

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