• Bulletin of the Korean Chemical Society
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• 제7권2호
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• pp.137-142
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• 1986

The luminescence spectra of $Ru(bpy)_3^{2+}$ in poly(methacrylic acid) (PMA) solutions varied sensitively with pH. At pH < 5.5, the emission intensity increased with pH up to 4 times, while it decreased with pH beyond the pH. The enhanced emission intensity was accompanied by blue-shift of the emission maxima as much as 15 nm. The enhancement of emission intensity was attributed to the restricted rotational mobility of ligand of the cation bound to densely coiled PMA molecules at pH < 5.5. The sharp decrease in emission intensity with increasing pH near pH 5.6 was accounted for conformational transition of the polymer to more extended structure, which was also revealed in viscosity measurement. The enhancement of emission intensity became higher as NaCl concentration of the solution increased. The binding constant of $Ru(bpy)_3^{2+}$ with two carboxylate groups of PMA was calculated as $2{\times}10^5\;M^{-1}$ in 0.1 M NaCl at pH 5.2. The pH dependence of luminescence quenching rate of $Ru(bpy)_3^{2+}$ by $Cu^{++}$ also showed maximum near pH 5, and the rate was more than $10^3$ times higher than that in water, whereas the maximum enhancement of quenching rate (about 20 times) in poly(acrylic acid) (PAA) solution occurred at pH 4.5. On the other hand, the pH dependence for neutral water soluble nitrobenzene (NB) exhibited opposite trend to that of $Cu^{++}$. The quenching constant vs pH curve for $MV^{++}$ was composite of those for $Cu^{++}$ and NB. The anomalous high quenching rate for $Cu^{++}$ in PMA solution at pH < 5.5 was attributed to the binding of $Ru(bpy)_3^{2+}$ and $Cu^{++}$ to the same region of PMA, when it conforms densely coiled structure in the pH range. The observation of mininium quenching rate for NB near pH 5.5 indicated that the $Ru(bpy)_3^{2+}$ bound to the densely coiled PMA is not accessible by NB, which is in bulk water phase. The composite nature of the pH dependence of quenching rate for $MV^{++}$ in PMA solution was attributed to the smaller binding affinity of the cation to PMA, compared to that of $Cu^{++}$. The sharp, cooperative conformational transition with pH observed in PMA was not revealed in PAA. But, the pH dependence of quenching rates in this polymer reflected increased charge density and, thus, binding of cations to the polymer, and expansion of the polymer chain with pH.

• 응용통계연구
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• 제24권5호
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• pp.809-820
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• 2011

VaR는 투자목적이나 위험관리수단으로 시장위험을 측정하는 방법으로 현실생활에서는 다변량 분포에 대하여 추정을 필요로 한다. 본 연구는 다변량 확률변수들의 분포를 생성하기 위하여 Copula 함수를 사용한다. 확률변수들의 종속구조를 exchangeable Copula, fully nested Copula, partially nested Copula로 구별하여 토론한다. 국내의 네 종류의 산업체의 수익률 자료를 실증예제로 하여 Clayton, Gumbel, Frank Copula 함수가 포함된 Archimedean Copula 함수의 모수들을 세 종류의 종속구조를 이용하여 구하고, 이 자료에 적합한 Copula 함수와 각 함수에 대응하는 VaR를 추정하고 비교탐색한다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.425-428
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• 1996

Treeing deterioration which is one of the main cause of breakdown in insulating materials is affected by temperature, applied voltage and frequency. In this study, GN was introduced to improve impact strength of DGEBA/MDA system and the temperature dependence of AC treeing deterioration in this system was investigated. Dielectric breakdown strength decreased with the increment of temperature. As temperature increased, the growth rate of tree Increased.

• 한국정보통신학회:학술대회논문집
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• 한국해양정보통신학회 2002년도 추계종합학술대회
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• pp.796-799
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• 2002

BSCCO thin films are fabricated via a co-deposition process at an ultra-low growth rate using ion beam sputtering. The sticking coefficient of Bi element exhibits a characteristic temperature dependence. This temperature dependence of the sticking coefficient was explained consistently on the basis of the evaporation and sublimation processes of Bi$_2$O$_3$.

• 한국산학기술학회논문지
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• 제15권12호
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• pp.7248-7258
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• 2014

본 연구는 전화상담과 문자메시지 제공 금연프로그램이 중재 횟수를 달리한 실험군1, 실험군2와 대조군의 금연 자기효능감, 니코틴의존도, 호기일산화탄소 농도, 금연성공률에 미치는 효과를 알아보기 위한 유사실험연구로 허혈성 심질환자 60명을 대상으로 하였다. 프로그램효과를 측정한 결과, 실험군은 대조군에 비해 금연 자기효능감, 금연성공률은 유의하게 증가하였고, 니코틴의존도, 호기 일산화탄소 농도는 유의하게 감소하였다. 또한 실험군1은 실험군2에 비해 금연 자기효능감, 금연성공률은 유의하게 증가하였고, 호기 일산화탄소는 유의하게 감소하였으나, 니코틴의존도에는 유의한 차이가 없었다. 따라서 허혈성 심질환자에게 제공한 전화상담과 문자메시지 중재 금연프로그램은 금연성공률의 향상에 효과가 있으며 중재 횟수에 따라 더욱 효과가 있는 것으로 나타났다.

• Bulletin of the Korean Chemical Society
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• 제33권11호
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• pp.3539-3543
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• 2012

Butacaine sulfate is an ester of p-aminobenzoic acid which has been widely used as a local anaesthetic and it is a long standing agent particularly for spinal anaesthesia. For this reason, a kinetic study of oxidation of butacaine sulfate by sodium N-chlorobenzenesulfonamide (chloramine-B or CAB) has been carried out in $HClO_4$ medium at 303 K in order to explore this redox system mechanistic chemistry. The rate shows a first-order dependence on both $[CAB]_o$, and $[substrate]_o$, and a fractional-order dependence on acid concentration. Decrease of dielectric constant of the medium, by adding methanol, increases the rate of the reaction. Variation of ionic strength and addition of benzenesulfonamide or NaCl have no significant effect on the rate. The reaction was studied at different temperatures and the activation parameters have been evaluated. The stoichiometry of the reaction has been found to be 1:2 and the oxidation products have been identified by spectral analysis. The observed results have been explained by plausible mechanism and the related rate law has been deduced.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 추계학술대회 논문집
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• pp.208-208
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• 2009

We used Brewster's Law to examine the mechanism of liquid crystal (LC) alignment on an organic insulation layer when subjected to ion-beam irradiation. Brewster's Law implies that the maximum rate polarized ray on a slanted insulation layers on the substrate and it illustrates the dependence of polarization and themechanical structure on the ion beam irradiation process. The pretilt angle of nematic LCs on the organic insulation surface was about $1.13^{\circ}$ for an ion beam exposure of $45^{\circ}$ for 1 minute at 1800eV. This shows the dependence of LC alignment on the polarization ratio in a slanted organic insulation layer.

• Bulletin of the Korean Chemical Society
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• 제8권6호
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• pp.449-453
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• 1987

The temperature dependence of the vibrational relaxation of NO(= 2) by NO(v = 0) has been investigated over the temperature range 100-3000 K. We have assumed that the deexcitation of NO(2) by NO(0) undergoes vibration-to-vibration (VV) energy exchange with the transfer of the energy mismatch ${\Delta}$E through rotation (R) and translation(T). The relaxation rate constants are calculated by solving the time-dependent Schrodinger equation. The sum of V-V, T, and V-V, R contributions shows very weak temperature dependence and is in reasonable agreement with observed data over the temperature range 300-3000 K.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1995년도 춘계학술대회 논문집
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• pp.167-171
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• 1995

The orientation dependence of sputtering rate in the sendust polysrystalline targets was studied, It was fount from the present work that the erosion process is not uniform from one grain to another even within a target because of its polysrystalline nature showing many different orientation of grains. The grains oriented to promote efficient erosion were characterized by the close-packed planes which have large interplanar spacing and strong binding energy, The characteristic line patterns appeared on as-sputter target surface are discussed in terms of symmetry of crystllographic planes.

• 천문학회보
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• 제45권1호
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• pp.52.4-53
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• 2020

It is less well known that the properties, especially the mass accretion rate, of accretion flow are affected by the angular momentum of accreting gas. Park (2009) found that the mass accretion rate \dot{m}, mass accretion rate in units of Bondi accretion rate, is inversely proportional to the angular momentum of gas λ, at the Bondi radius where gas sound speed is equal to the free-fall velocity and proportional to the viscosity parameter α, and also Narayan & Fabian (2011) found a similar relation, but the dependence of the mass accretion rate of the gas angular momentum is much weaker. In this work, we investigate the global solutions for the rotating Bondi flow, i.e., polytropic flow accreting via viscosity, for various accretion parameters and the dependence of the mass accretion rate on the physical characteristics of gas. We set the outer boundary at various radius r_{out}=10^3~10^5 r_{Sch}, where r_{Sch} is the Schwarzschild radius of the black hole. For a small Bondi radius, the mass accretion rate changes steeply, as the angular momentum changes, and for a large Bondi radius, the mass accretion rate changes gradually. When the accreting gas has a near or super Keplerian rotation, we confirm that the relation between the mass accretion rate and angular momentum is roughly independent of Bondi radius as shown in Park (2009). We find that \dot{m} is determined by the gas angular momentum at the Bondi radius in units of r_{Sch}c. We also investigate the solution for the rotating Bondi flow with the outflow. The outflow affects the determination of the mass accretion rate at the outer boundary. We find that the relation between the mass accretion and the gas angular momentum becomes shallower as the outflow strengthens.