• 한국주조공학회지
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• 제27권6호
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• pp.250-254
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• 2007

3원계 Al-Nb-Zr의 용응 합금을 스프렛 ?봬?(splat-quenching) 방법을 이용하여 급속냉각응고 한 후, 응고된 시편을 698K에서 200시간까지 열처리하여 상전이를 연구하였다. 급속응고 및 열처리된 시편의 미세구조는 X-선 회절 및 투과전자 현미경으로 분석하였다. Al-1.95Nb-0.65Zr, Al-1.3Nb-1.3Zr, 및 Al-0.65Nb-1.95Zr (at%) 3원 합금계를 연구하였다. 각 합금의 조성은 Vegard's 법칙을 적용하여 Al(${\alpha}$)의 기지조직과 $L1_2-Al_3(Nb,Zr)$의 석출상들이 정합을 이루도록 선택되었다. 급속응고된 후 각 합금은 과고용된 Al(${\alpha}$)의 고용상을 형성하였다. Al-1.3Nb-1.3Zr, 및 Al-0.65Nb-1.95Zr의 급속응고된 상태의 시편을 698K에서 열처리하여 알루미늄 기지와 정합의 계면을 갖는 $L1_2-Al_3(Nb_{0.5}Zr_{0.5})$와 $L1_2-Al_3(Nb_{0.25}Zr_{0.75})$의 상을 각각 석출하였다. 반면 Al-1.95Nb-0.65Zr 합금은 평형상인 $D0_{22}-Al_3(Nb_{0.75}Zr_{0.25})$ 상을 석출하였다. 준안정상의 정합 $Al_3(Nb,Zr)$ 미세 분산상 석출은 입자의 조대화를 억제하고 재료의 고온 강도를 증가될 것으로 사료된다.

• Rapid Communication in Photoscience
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• 제4권1호
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• pp.22-24
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• 2015

A new trinuclear complex $[Ru(TPrPc)(CO)]_2[Ru(pytpy)_2](PF_6)_2$ (TPrPc = 2,7,12,17-tetra-n-propylporphycenato dianion and pytpy = 4'-(4-pyridyl)-2,2':6',2"-terpyridine) has been synthesized and characterized as the first example of a discrete molecular wire containing metalloporohycenes as a building block. The trinuclear complex shows multiple-step redox behavior in 0.1 M n-$Bu_4NPF_6$-dichloromethane. The mononuclear $[Ru(pytpy)_2]^{2+}$ precursor shows emission at 640 nm (deaerated acetone, 298 K) upon illumination at the metal-to-ligand charge transfer (MLCT) band at 495 nm, but the trinuclear molecular wire is found to be non-emissive upon photoexcitation at the central $[Ru(pytpy)_2]^{2+}$ entity, indicating an efficient quenching ability of the axially-linked, ruthenium(II)-porphycene chromophores in an intramolecular fashion.

• 한국재료학회지
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• 제30권9호
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• pp.474-479
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• 2020

The effect of precipitation and dissolution of Si on the thermal diffusivity in the Al-Si alloy system is reported in this study and solution heat treatment followed by aging treatment is carried out to determine the effects of heat treatment on the thermal characteristics. The solution treatment is performed at 535 ℃ for 4 and 10 h and then the specimens are cooled by rapid quenching. The samples are aged at 300 ℃ for 4 h to precipitate Si solute. The addition of 9 wt% silicon contents makes the thermal diffusivity decrease from 78 to 74 mm/s² in the cases of solid solution treated and quenched samples. After quenching and aging, the Si solute precipitates on the Al matrix and increases the thermal diffusivity compared with that after the quenched state. In particular, the increase of the thermal diffusivity is equal to 10 mm/s² without relation to the Si contents in the Al-Si alloy, which seems to corresponded to solute amount of Si 1 wt% in the Al matrix.

• Transactions on Electrical and Electronic Materials
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• 제1권3호
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• pp.6-9
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• 2000

Selectively excited photoluminescence(PL) spectroscopy has been carried out on the ~1540 nm $^{4}$I$_{13}$ 3/ to $^{4}$I/wub 15/2/ emissions of the multiple Er$^{3+}$ centers observed in Er-implante undoped and Mg-doped GAN at temperatures ranging from 6K to 295K. The temperature dependence of the Er$^{3+}$ PL spectra selectively excited by below -gap light demonstrates different quenching rates for the distinct Er$^{3+}$ centers, and indicates that the PL spectra with the most rapid thermal quenching rats do not contribute to the room temperature, above-p-pumped Er$^{3+}$ spectrum. In addition, selective PL spectroscopy has ben carried out on the Er$^{3+}$ emission in Er-implanted undoped and Mg-doped GaN at temperatures ranging 6K to 295K. The results indicate that the previously reported enhancement of the violet-pumped centers contribution to the low temperature above excited Er$^{3+}$ PL in Mg-doped GaN is also evident at room temperature.temperature.

• 한국식품영양과학회지
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• 제26권4호
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• pp.743-750
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• 1997

세포막에서의 지방산 이동은 매우 빠르게 일어나므로 방사성 원소를 사용해서는 여러가지 단점이 있고, 정확한 이동속도 측정에도 어려움이 많았다 최근에 개발된 FRET assay는 형광성 물질과 형광성 물질을 상쇄시키는 quencher를 사용한 실험방법 이다. 이는 공명 에너지 이동의 원리를 이용한 것으로 형광광도계, stopped-flow장치를 사용하여 소수성 물질 이동을 직접 컴퓨터 모니터로 측정하는 방법으로 기존방법의 단점을 보완하였다. Donor막에는 형광성 표지를 붙인 지방산이 들어 있고 acceptor막에는 형광을 흡수하는 물질이 들어 있어서 형광성 지방산이 donor에서 acceptor로 이동하면 형광도가 감소하며, 시간에 따른 형광도 감소를 측정하여 지방산 이동속도를 측정하는 방법이다. 형광성 표지를 이용하여 소수성 물질 이동에 사용되는 또 다른 방법은 self-Quenching assay이다. 형광 물질의 농도가 높아지면 서로 형광을 흡수하는 성질을 이용한 방법으로 주로 micelle에서의 물질 이동에 많이 쓰인다. Donor micelle에는 높은 농도의 형광성 지방산이 들어 있고 acceptor micelle에는 형광성 지방산이 들어 있지 않을 때 형광성 지방산이 donor에서 acceptor로 이동하면 형광도가 증가하게 되고 시간에 따른 형광도 증가를 측정하는 방법이다.

• Bulletin of the Korean Chemical Society
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• 제33권5호
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• pp.1608-1612
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• 2012

Singlet oxygen ($^1O_2$) is an important species for oxidation in biological processes. $^1O_2$ is implicated in the genotoxic effect, and plays an important role in the cell-signaling cascade and in the induction of gene expression. However, the rapid detection of $^1O_2$ in biological environments with sufficient specificity and sensitivity is hampered by its extremely low emission probability. Here, a layer-by-layer (LbL) film of CdTe quantum dots (QDs), polymers, and ascorbate have been designed as a rapid, highly selective, and sensitive fluorescence probe for $^1O_2$ detection. Upon reaction with $^1O_2$, the probe exhibits a strong photoluminescence (PL) response even at trace levels. This remarkable PL change should enable the probe to be used for $^1O_2$ detection in many chemical and biological systems and as an environmental sensor.

• 열처리공학회지
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• 제6권4호
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• pp.194-203
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• 1993

Rapid solidified splats Al-(1, 3, 5Cr) Alloys were produced by atomization-splat quenching method. Effects of mechanical alloying on the structure and mechanical properties of rapidly solidified Al-(1, 3, 5)Cr alloys were studied. Degree of mechanical alloying of Al-(1, 3, 5)Cr alloys can be determined by observing the microstructural refinement, microhardness and microstructure of Al-(l, 3, 5)Cr splats during processing. In the initial stage of mechanical alloying of the Al-(1, 3, 5)Cr splats fracturing of the grain boundaries occured first, followed after fracturing of zone A regions. Saturation hardness of Al-(1, 3, 5)Cr alloys increased proportionally with increasing concentration of the solute (Cr). Age hardening was not observed in these alloys. Decomposition temperature of Al-1Cr splats after mechanical alloying was higher than that of Al-5Cr splats. The density of $Al_7$ Cr precipitates increased proportionally with increasing chromium content, as a result, there was a transition to finely and spherically dispersed phase after mechanical alloying.

• 한국해양공학회지
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• 제6권2호
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• pp.113-124
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• 1992

The offshore industry created a need for quality wet weld repairs. Wet welding is a fast method of repair providing sound, structural quality welds. It requires less support equipment than a similar underwater dry weld repair or the alternative mechanical connections. Compared to welds made in air, underwater wet welds are plagued by increased hardness due to rapid quenching by the surrounding water. In this paper is described the experimntal study of improving the cooling rates of wet welds of TMCP steel plate by shielding around weld arc surroundings. The principal results of this experimental investigation can be summarized as follows : By shielding around weld arc surrounding, the cooling rates resulting from wet welds on TMCP steel plate could be lower than that of nonshielded wet welds and the fesibility on high quality of mecanical properties of wet weld on TMCP steel plate was carried out with shielded weld arc surrounding.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회A
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• pp.160-165
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• 2007

It is well recently recognized that quench is one of the serious problems for the integrity of superconducting magnets, which is mainly attribute to the rapid temperature rising in the magnet due to some extrinsic factors such as conductor motion, crack initiation etc. In order to apply acoustic emission(AE) technique effectively to monitor and diagnose superconducting magnets, it is essential to identify the sources of acoustic emission. In this paper, an acoustic emission technique has been used to monitor and diagnose quenching phenomenon in racetrack shaped superconducting magnets at cryogenic environment of 4.2K. For these purposes special attention was paid to detect AE signals associated with the quench of superconducting magnets. The characteristics of AE parameters have been analyzed by correlating with quench number, winding tension of superconducting coil and charge rate by transport current.

• 대한조선학회논문집
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• 제41권6호
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• pp.65-74
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• 2004

The inherent strain method is known to be very efficient in predicting the deformation of steel plate by line heating. However, in the actual line heating process in shipyard, the rapid quenching changes the phase of steel. In this study, In order to consider additional effects under phase transformation, inherent strain regions were assumed to expand. Also, when calculating inherent strain, material properties of steel in heating and cooling are applied differently considering phase transformation. In this process, a new method which can reflect thermal volume expansion of martensite is suggested.8y the suggested method, it was possible to predict the plate deformations by line heating more precisely.