• 제목/요약/키워드: rapid solidification

검색결과 178건 처리시간 0.034초

주강품 압탕 설계에 체적 수축을 고려한 응고해석의 적용 (Application of Solidification Analysis considering Volumetric Contraction to Riser Design of Steel Castings)

  • 김지준;김기영;최정길;홍준표
    • 한국주조공학회지
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    • 제15권5호
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    • pp.494-506
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    • 1995
  • Test castings in plate, disc, and cubic shaped castings for 0.2wt.% carbon and stainless steel have been poured to examine the effects of the riser dimensions including riser neck on the casting soundness. Three empirical methods were chosen in risering of steel castings. A computer program of solidification analysis considering liquid and solidification contraction was developed to apply for riserdesign calculated by using their methods in plate, disc, and cubic shaped castings, and to calculate the position and dimension of shrinkage cavity in complex shaped casting. The potential of present method has been successfully demonstrated by comparing predicted cavity shapes with those obtained in a series of experimental castings. Three empirical methods can be used in a practical way to make a rapid estimation of tie minimum riser diameter, but they can not provide a criterion of casting soundness with shape and material on all occasions. The shape and position of shrinkage cavity can be successfully predicted both using the present method and using risering calculated by their methods regardless of the shape and cast material.

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액체급랭응고법으로 제조된 리튬 이차전지 음극활물질용 Si50Al30Fe20 비정질 합금의 결정화 거동 및 전기화학적 특성 (Crystallization Behavior and Electrochemical Properties of Si50Al30Fe20 Amorphous Alloys as Anode for Lithium Secondary Batteries Prepared by Rapidly Solidification Process)

  • 서덕호;김향연;김성수
    • 한국전기전자재료학회논문지
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    • 제32권4호
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    • pp.341-348
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    • 2019
  • This paper reports the microstructure and electrochemical properties of Si-Al-Fe ternary amorphous alloys prepared by rapid solidification as an anode for lithium secondary batteries. The microstructure was analyzed using XRD and HR-TEM with EDS mapping. In accordance with DSC analysis, annealing was performed to crystallize the active nano-Si in the amorphous alloy. Thus, nano-Si forms (~80 nm) embedded in the matrix alloy, such as $Fe_2Al_3Si_3$, $FeSi_2$, and $Fe_{0.42}Si_{2.67}$, were successfully synthesized. The electrode based on the Si-Al-Fe ternary alloy delivered an initial discharge capacity of approximately $700mAh^{g-1}$, and exhibited a high Coulombic efficiency of 99.0~99.6% from the $2^{nd}$ to $70^{th}$ cycles.

$CO_2$ 레이저빔을 이용한 예민화된 Alloy 600의 급속응고 미세구조 연구 (Study on microstructure of sensitized Alloy 600 rapidly solidified by a $CO_2$ laser beam)

  • 임연수;서정훈;국일현;김정수
    • 한국레이저가공학회지
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    • 제1권1호
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    • pp.18-23
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    • 1998
  • A Study on microstructural changes of sensitized Alloy 600 which was rapidly solidified by a $CO_2$ laser beam was conducted using microscopic equipments such as SEM and TEM. Dissolution of Cr-rich carbides and resultant Cr recovery on the grain boundaries occurred in the heat affected zone (HZA). The microstructure of the laser melted zone (LMZ) having epitaxially solidified from the HAZ was mainly celluar-dendritic with the 〈100〉 crystallographic direction of growth. The Cr concentration was observed to increase along the cell bondaries, and tiny particles were distributed along the cell walls with tangled dislocations around them. Cr-rich carbides had been completely melted by the high density of a laser beam, and were not re-precipitated during the matrix solidification due to a fast cooling rate in the LMZ.

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Corrosion Behavior of Rapidly Solidified Mg-Zn-Y Alloys in NaCl Solution

  • Izumi, Shogo;Yamasaki, Michiaki;Sekigawa, Takahiro;Kawamura, Yoshihito
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1043-1044
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    • 2006
  • Compositional dependence of corrosion behavior of rapidly solidified Mg-rich Mg-Zn-Y alloys in NaCl aqueous solution has been investigated. Mg-Zn-Y ternary alloys containing small amounts of Zn exhibited low corrosion rate, although the $Mg_{98}Y_2$ (at. %) binary alloy showed severe corrosion with violet evolution of hydrogen. The alloy with highest corrosion-resistance was $Mg_{97.25}Zn_{0.75_Y_2$, its corrosion rate was about 1 mm year-1 in 0.17 M (1.0 wt. %) NaCl solution. $Mg_{97.25}Zn_{0.75}Y_2$ alloy exhibited passive region in anodic polarization curves when immersed in NaCl solution. Rapidly solidification and small amount of Zn addition may bring about an increase in electrochemical homogeneity of Mg-Zn-Y alloys, resulting in enhancement of corrosion resistance.

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용사법에 의한 용사층의 형성과 기계적 성질에 관한 연구 (A study on the formation and mechanical properties of the spray deposits by thermal spray)

  • 최기영;박동환;김명호
    • Journal of Welding and Joining
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    • 제7권3호
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    • pp.55-62
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    • 1989
  • Variation of the spray droplet velocity with spraying distance and the microstructural characteristics of spray deposits fromed by oxy-fuel thermal spraying with Ni-base alloy powder contained chrome boride for hard facing were examined. Measurements of spray droplet velocity as a function of distance from the nozzle tip were inexcellent agreement with computer simulated predictions. Optimum condition for thermal spray deposits in this experiment was found to be under #10kg/cm^2$ of acceleration gas pressure with 15cm of spraying distance. Fine microstructure and higher microhardness of the initial part of the deposits due to rapid solidification were found to be able to maintained in a thickness up to 0.4mm, and this initial microstructure and properties could be maintained throughout the thickness of a thick spray deposits by performing the multipass spraying with 0.4mm thickness of each pass.

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Rapid Manufacturing of Microscale Thin-walled Structures using a Phase Change Work-holding Method

  • Shin Bo-Sung;Yang Dong-Yol
    • International Journal of Precision Engineering and Manufacturing
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    • 제7권3호
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    • pp.47-50
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    • 2006
  • High-speed machining is a very useful tool and one of the most effective rapid manufacturing processes. This study sought to produce various high-speed machining materials with excellent quality and dimensional accuracy. However, high-speed machining is not suitable for microscale thin-walled structures because the structure stiffness lacks the ability to resist the cutting force. This paper proposes a new method that is able to rapidly produce very thin-walled structures. This method consists of high-speed machining followed by filling. A strong work-holding force results from the solidification of the filling materials. Low-melting point metal alloys are used to minimize the thermal effects during phase changes and to hold the arbitrarily shaped thin-walled structures quickly during the high-speed machining. We demonstrate some applications, such as thin-walled cylinders and hemispherical shells, to verify the usefulness of this method and compare the analyzed dimensional accuracy of typical parts of the structures.

Consolidation 방법에 의해 제작된 유리섬유강화 복합재료의 결정성과 기계적성질에 관한 연구 (Crystallinity and Mechanical Properties of Glass Fiber Reinforced Thermoplastic Composites by Rapid Press Consolidation Technique)

  • 신익재;김동영;이동주
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2000년도 춘계학술대회논문집A
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    • pp.91-96
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    • 2000
  • Glass fiber reinforced thermoplastic composites were manufactured by Rapid Press Consolidation Technique(RPCT) as functions of temperature, pressure and time in pre-heating, consolidation and solidification sections during the manufacturing processing. It was found that the material property is greatly affected by pre-heating temperature under vacuum, mold temperature and molding pressure. Among them, the temperature In the mold was the most critical factor in determining the mechanical properties and the molded conditions of specimen. The crystallinity of PET matrix was also investigated by differential scanning calorimetry(DSC) measurements for various processing conditions. The level of crystallinity($X_c$) depended strongly on the mold temperature, cooling rate and the type of composite. The difference in $X_c$ is believed to be one of important factors in characterizing the mechanical properties.

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Crystallization Mechanisms of Joule-Heating-Induced Crystallization

  • Park, Doo-Jung;Ro, Jae-Sang
    • Journal of Information Display
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    • 제10권2호
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    • pp.76-79
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    • 2009
  • In Joule-heating-induced crystallization, solid-to-solid or liquid-to-solid phase transformation could occur. It was found that novel physical phenomena that randomly nucleated liquid seeds, followed by rapid solidification in an amorphous matrix, during the Joule-heating-up period play an important role especially in liquid-to-solid transformation. Under some processing conditions, super-grains sized 6-8 ${\um}m$ were produced by the lateral growth from the initial seeds, without any artificially control.

고강도 알루미늄합금 용접부의 고온균열 Mechanism (Mechanism of Hot Cracking in High Strength Al Welds)

  • 이창희;조성석
    • Journal of Welding and Joining
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    • 제14권3호
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    • pp.93-104
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    • 1996
  • This study evaluated relative hot cracking susceptibility of commercial aluminum alloy welds, and then suggested possible mechanisms operated in the weld fusion zone and in the heat affected zone based on the observed cracking morphologies, fractography and microstructural features. The fusion zone solidification cracking was found to be mainly due to a microsegregation of Cu, Si, and Mg in grain boundaries, while liquation cracking in the HAZ was by the incipient melting of the segregated grain boundaries and the consitutional liquation of large aging precipitates and intermetallic compounds in the partially melted zone adjacent to the fusion line which experienced a rapid thermal excursion during welding.

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Magnetic properties of large-scaled MnBi bulk magnets

  • Kim, Sumin;Moon, Hongjae;Jung, Hwaebong;Kim, Su-Min;Lee, Hyun-Sook;Choi-Yim, Haein;Lee, Wooyoung
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2017년도 임시총회 및 하계학술연구발표회
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    • pp.122-122
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    • 2017
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