• Title/Summary/Keyword: rapid solidification

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Solidification Characteristics of Al-Cu Polycrystalline Ribbons in Planar Flow Casting (PFC법에 있어서의 Al-Cu 다결정리본의 응고특성)

  • Lee, Kyung-Ku;Lee, Sang-Mok;Hong, Chun-Ryo
    • Journal of Korea Foundry Society
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    • v.15 no.4
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    • pp.408-415
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    • 1995
  • Polycrystalline Al-Cu ribbons were produced by planar flow casting(PFC). Solidification behavior and microstructual changes of the ribbons have been investigated as a function of ribbon thickness and processing parameters. The solidification front velocity, V varies within the ribbon, decreasing with increasing the distance, S from the wheel-contact surface, as $V=17.6S^{-1}$. In Al-4.5wt%Cu alloy, rapid decrease in solidification velocity toward the free surface causes a change in solidification morphology from planar to cellular, and finally, to dendritic. The length and inclination of columnar grains solidified with planar front were related to the wheel velocity. The transition from particulate degenerate eutectic structure to regular lamellar eutectic structure was observed to be caused by a difference of the relative growth velocites of ${\alpha}-Al$ and ${\theta}$ during solidification in the Al-Cu eutectic alloy.

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Solidification Behaviors of the Rapidly Solidified Metallic Powders and Development of the Powder Making Process.;Part I : Development of the Powder Making Process (급속응고된 금속분말의 응고거동 및 제조법에 관한 연구;Part I : 급속응고 제조법)

  • Kim, Jong-Yoon;Yoon, Woo-Young
    • Journal of Korea Foundry Society
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    • v.15 no.2
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    • pp.164-174
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    • 1995
  • New metallic powder making processes, named "Centrifugal Emulsification Process(CEP)" and "Mixer and Settler(MS)" have been developed to synthesize rapid solidified metallic powders. Through CEP and MS processings, the high temperature metals as well as the low temperature alloys are manufactured. Also, the effects of rapid solidification on the undercooling, solidification rate and crystallization behaviors can be evaluated effectively through the processes. The standard deviations of the synthesized typical Pb-Sn eutectic powders are 1.63 and 1.51 for CEP and MS respectively, and the average size of the MS powders was $18{\mu}m$. The possibility of the customized not only size and shape control but microstructure control was also shown. Both of the new methods can be applied to continuous powder making processes.

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Solidification/stabilization of Hazardous Wastes Using Cementitious Materials(III) (특수시멘트 고형화재를 이용한 지정폐기물의 고형화/안정화(III))

  • Lim, Chae-Yong;Ku, Ki-Dae;Um, Tae-Sun;Lee, Jong-Ryul;Choi, Long;Oh, Byoung-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.289-294
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    • 2001
  • This study concerns the cement-solidification/stabilization of the waste with high concentration heavy metals. Compressive strength and leaching test of heavy metals were evaluated for ing types of cements and the effect of the additives of Hauyne clinker and slag were also cussed. Using ordinary portland cement, rapid hardening portland cement and the cement with additives solidification materials, it shows that the strength and stability of concrete is satisfactory and superiority is in the order of rapid hardening portland cement > the cement with additives > nary portland cements.

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Structure and Properties of Rapidly-Solidified Al-Pb Monotectic Alloys.;I. Characteristics of Rapidly-Solidified Microstructure (급속 응고한 Al-Pb 편정 합금의 조직과 성질;I. 급속 응고 조직 특성)

  • Kim, Myung-Ho;Bae, Cha-Hurn;Lee, Ho-In
    • Journal of Korea Foundry Society
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    • v.9 no.1
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    • pp.73-79
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    • 1989
  • Microstructural characteristics of Al-3.63wt.%Pb hyper-monotectic alloy rapidly-solidified by melt spinning were examined. Possibility of forming a planar liquid -solid interface during rapid solidification of this alloy was also considered with a morphological stability theory, and a mechanism of forming banded structure observed at the bottom parts of melt-spinned specimens was considered as well. Application of the absolute stability criterion predicts the liquid-solid interface of the primary aluminium phase to be able to maintain a planar interface during the early stage of rapid solidification. Formation of banded structure was supposed to be resulted from the release of latent heat during solidification, which affect the stability of a planar liquid-solid interface.

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Development of High Strength Mg-Zn-Gd Alloys by Rapid Solidification Processing

  • Kim, Min-Chul;Yamasaki, Michiaki;Kawamura, Yoshihito
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1048-1049
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    • 2006
  • Rapidly solidified ribbon-consolidation processing was applied for preparation of high strength bulk Mg-Zn-Gd alloys. Mg alloys have been used in automotive and aerospace industries. Rapid solidification (RS) process is suitable for the development of high strength Mg alloys, because the process realizes grain-refinement, increase in homogeneity, and so on. Recently, several nanocrystalline Mg-Zn-Y alloys with high specific tensile strength and large elongation have been developed by rapidly solidified powder metallurgy (RS P/M) process. Mg-Zn-Y RS P/M alloys are characterized by long period ordered (LPO) structure and sub-micron fine grains. The both additions of rare earth elements and zinc remarkably improved the mechanical properties of RS Mg alloys. Mg-Zn-Gd alloy also forms LPO structure in -Mg matrix coherently, therefore, it is expected that the RS Mg-Zn-Gd alloys have excellent mechanical properties. In this study, we have developed high strength RS Mg-Zn-Gd alloys with LPO structure and nanometer-scale precipitates by RS ribbon-consolidation processing. $Mg_{97}Zn_1Gd_2$ and $Mg_{95.5}Zn_{1.5}Gd_3$ and $Mg_{94}Zn_2Gd_4$ bulk alloys exhibited high tensile yield strength (470 MPa and 525 MPa and 566 MPa) and large elongation (5.5% and 2.8% and 2.4%).

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The Effect of Misch Metal on the Microstructure of Rapidly solidified Ag-Sn-In Alloys (급속응고한 Ag-Sn-In 합금의 미세조직에 미치는 Misch Metal의 영향)

  • Chang, Dae-Jung;Nam, Tae-Woon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.6
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    • pp.561-565
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    • 2007
  • Because of a good wear resistance and a stable contact resistance, Ag-CdO is widely used as electrical contact material. But, the Cd-oxide mainly exists as a coarse particle and adversely affected to environment. As a reason, $Ag-SnO_2$ alloy has been developed. The Sn-oxide maintains stable and fine particle even at high temperature. In order to investigate the effect of Misch metal (Mm) additional that affects the formation of the oxide and the formation of fine matrix Ag, we studied the microstructures and properties of Ag-Sn-In(-Mm) material fabricated by rapid solidification process. The experimental procedure were melting using high frequency induction, melt spinning, and internal oxidation. The Mm addition makes Ag matrix more fine than no Mm addition. The reason is that the addition of Misch metal decreased a latent heat of fusion of alloy, as a result the rapid solidification effect of alloy is increased. The maximum hardness shows at 0.3 wt%Mm. after that the hardness is decreased until 0.4 wt% Mm, but still larger than no Mm addition alloy. At 0.5 wt% Mm alloy, the precipitation of Misch metal causes a decrease of hardness than no Mm addition alloy.

Solidification Cracking Behavior in Austenitic Stainless Steel Laser Welds (Part 2) -Effects of δ-ferrite Crystallization and Solidification Segregation Behavior on Solidification Cracking Susceptibility- (오스테나이트계 스테인리스강 레이저 용접부의 응고균열 거동 (Part 2) - δ 페라이트 정출 및 응고편석 거동에 따른 응고균열 민감도 변화 -)

  • Chun, Eun-Joon;Lee, Su-Jin;Suh, Jeong;Kang, Namhyun;Saida, Kazuyoshi
    • Journal of Welding and Joining
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    • v.34 no.5
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    • pp.61-69
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    • 2016
  • A numerical simulation of the solid/liquid coexistence temperature range, using solidification segregation model linked with the Kurz-Giovanola-Trivedi model, explained the mechanism of the BTR shrinkage (with an increase in welding speed) in type 310 stainless steel welds by reduction of the solid/liquid coexistence temperature range of the weld metal due to the inhibited solidification segregation of solute elements and promoted dendrite tip supercooling attributed to rapid solidification of laser beam welding. The reason why the BTR enlarged in type 316 series stainless welds could be clarified by the enhanced solidification segregation of impurity elements (S and P), corresponding to the decrement in ${\delta}-ferrite$ crystallization amount at the solidification completion stage in the laser welds. Furthermore, the greater increase in BTR with type 316-B steel was determined to be due to a larger decrease in ${\delta}-ferrite$ amount during welding solidification than with type 316-A steel. This, in turn, greatly increases the segregation of impurities, which is responsible for the greater temperature range of solid/liquid coexistence when using type 316-B steel.

Analysis on the non-equilibrium dendritic solidification of a binary alloy with back diffusion (역확산을 고려한 이원합금의 비평형 수지상응고 해석)

  • Jeong, Jae-Dong;Yu, Ho-Seon;Lee, Jun-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.10
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    • pp.3361-3370
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    • 1996
  • Micro-Macro approach is conducted for the mixture solidification to handle the closely linked phenomena of microscopic solute redistribution and macroscopic solidification behavior. For this purpose, present work combines the efficiency of mixture theory for macro part and the capability of microscopic analysis of two-phase model for micro part. The micro part of present study is verified by comparison with experiment of Al-4.9 mass% Cu alloy. The effect of back diffusion on the macroscopic variables such as temperature and liquid concentration, is appreciable. The effect, however, is considerable on the mixture concentration and eutectic fraction which are indices of macro and micro segregation, respectively. According to the diffusion time, the behavior near the cooling wall where relatively rapid solidification permits short solutal diffusion time, approaches Scheil equation limit and inner part approaches lever rule limit.