• 한국주조공학회지
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• 제22권6호
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• pp.288-292
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• 2002

Ni-base amorphous alloys were manufactured using melt-spinning and Cu-mold die casting methods. Amorphous formability, the supercooled liquid region before crystallization and mechanical properties were examined. The reduced glass transition temperature and the supercooled liquid region of $Ni_{51} Nb_{20} Zr_9 Ti_9 Co_8 Cu_3$alloy were 0.621 and 46 K respectively. $Ni_{51} Nb_{20} Zr_9 Ti_9 Co_8 Cu_3$ alloy was produced in the rod shape 3mm diameter using the Cu-mold die casting. Hardness, compression strength, elongation and elastic modulus of the alloy were 850 DPN, 2.75 GPa, 1.8% and 150 GPa respectively. Moreover, compression strength of 2.75 GPa was the highest value in the amorphous bulk alloy produced up to now.

• 한국표면공학회지
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• 제29권1호
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• pp.36-44
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• 1996

Fe-Cr-Al and Fe-Cr-Al-Hf alloys prepared either by arc melting or by single roll casting(melt spinning) were exposed to air isothermally at 900~$1100^{\circ}C$. Whisker-like alumina was observed on the surface of the specimens when oxidized at $900^{\circ}C$, but convoluted alumina above $1000^{\circ}C$. All the Hf-free specimens and Hf-added specimens produced by single roll casting formed only external scale mainly composed of $Al_2O_3$ after oxidation at 900~$1100^{\circ}C$ for 100 hours, but Hf-added specimen produced by arc melting formed Hf-rich internal oxides below the thin external $Al_2O_3$ scale except at $900^{\circ}C$. Most of the rapidly solidified Fe-Cr-Al alloys showed smaller weight gains than conventionally casted ones besides Hf-added one oxidized at $1100^{\circ}C$.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1041-1042
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• 2006

High heat-resistant Al-Fe-V-Si and Al-Fe-V-Si-X rapidly solidified powder metallurgy (RS P/M) alloys have been developed under well-controlled high purity argon gas atmosphere. The $Al_{90.49}Fe_{6.45}V_{0.68}Si_{2.38}$ (at. %) RS P/M alloy exhibited high elevated-temperature strength exceeding 300 MPa and good ductility with elongation of 6 % at 573 K. Reduction of $H_2O$ partical pressure in P/M processing atmosphere led to improvement in mechanical properties of the powder-consolidated alloys under elevated-temperature service conditions. Ti addition to the Al-Fe-V-Si conduced to enhancement of the strength at room temperature. The tensile yeild strength and ultimate strenght were 545 MPa and 722 MPa, respectively.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1045-1047
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• 2006

Fabrication of $Mg_{95.75}Zn_1Y_3Yb_{0.25}$ bulk alloy has been performed through the consolidation of rapidly solidified ribbons. The $Mg_{95.75}Zn_1Y_3Yb_{0.25}$ bulk alloy exhibited excellent mechanical properties, high tensile yield strength of 530 MPa, and large elongation of 3 %. Microstructure of the alloy was characterized by equiaxed fine grains that consist of -Mg, long period ordered (LPO) structure phase, and $Mg_5RE$-type cubic compound. The strengthening of the alloys may be due to fine grains with LPO structure phase and $Mg_5RE$-type compound.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1039-1040
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• 2006

Vacuum degassing is essential in the preparation of RS P/M aluminum alloys to remove adsorbates and for the decomposition of hydrated-$Al_{2}O_3$ on the powder surface. Changes in the surface characteristics during vacuum degassing were investigated by X-ray photoelectron spectroscopy and temperature-programmed desorption measurement. Hydrated-$Al_{2}O_3$ decomposition to crystalline-$Al_{2}O_3$ and hydrogen desorption on the surface of argon gas-atomized aluminum powder occurred at 623 K and 725 K, respectively. This temperature difference suggests that the reaction converting hydrated-$Al_{2}O_3$ to crystalline-$Al_{2}O_3$ during vacuum degassing should be divided into the two reactions $"2Al+Al_{2}O_3{\cdot}3H_2O\;2Al_{2}O_3+6H_{surf}"and"6H_{surf}3H_2"$.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1266-1267
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• 2006

[ $MgZn_{4.3}Y_{0.7}$ ] alloy powders were prepared using an industrial scale gas atomizer, followed by warm extrusion. The powders were almost spherical in shape. The microstructure of powders as atomized and bars as extruded was examined as a function of initial powder size distribution using Scanning Electron Microscope (SEM), Energy Dispersive X-ray Spectroscope (EDS) and X-ray Diffractometer (XRD). The grain sizes were decreased with extruding as well as decreasing the initial powder sizes. Both the ultimate strength and elongation were enhanced as the initial powder sizes were decreased.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1268-1268
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• 2006

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1269-1270
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• 2006

Mg-Zn-RE alloys had a novel lond period stacking ordered (LPO) structure. Their rapidly solidified powder metallurgy (RS P/M) alloys exhibited a combination of high strength and god ductility (tensile yield strength above 550 MPa and elongation above 5%). The LPO Mg-Zn-RE RS P/M alloys had high elevated temperature strength (tensile yield strength above 380 MPa at 473 K) and exhibited a high-strain-rate superplasticity at higher temperatures. In Japan, a national project for developing high strength LPO Mg-Zn-RE RS P/M alloys has started at 2003 for 5 years, which is founded by the Ministry of Economy, Trade and Industry (METI) of Japan. In the national project, project targets in materials performances have been achieved. The developed LPO Mg-Zn-RE RS P/M alloys exhibited higher tensile yield strength, fatigue strength and corrosion resistance than high strength aluminum alloys of extra-super-duralumin (7075-T6).

• 한국분말재료학회지
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• 제2권1호
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• pp.53-62
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• 1995

TLP(Transient-Liquid-Phase) bonding of Fe-base MA956 ODS alloy was performed. As insert metal a commercially available Ni-base alloy(MBF50) and an MA956 alloy with additive elements of 7wt% Si and 1wt% B were used. To confirm the idea that a concurrent use of MA956 powder with Insert metals can enhance the homogenization of constituent elements and thereby reduce the thickness of joint interface, MA956 powder was also inserted In a form of sheet. SEM observation and EDS analysis revealed that Cr-rich phase was formed in the bonded interface in initial stage of isothermal solidification during the bonding process, irrespective of kind of insert metals. Measurement of hardeness in the region of bonded interface and EDS analysis showed that a complete homogenization of composition could not be obtained especially in case of MBF50. Joints using either BSi insert metals only or BSi insert together with MA956 powder interlayer showed, however, a remarkable improvement in a compositional homogenization, even though a rapid grain growth in the bonded interface could not be hindered.

• 한국분말재료학회지
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• 제2권1호
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• pp.36-43
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• 1995

Rapidly solidified and mechanically alloyed Al-Ti base alloys were prepared by gas atomization and attritor milling separately. The gas atomized and the mechanically alloyed powders were consolidated after preheating at $450^{\circ}C$, and then heat treated isochronally for 1 hour to observe the microstructures and to investigate the mechanical properties. Stable phases of precipitates in the Al-Ti-Si and the Al-Ti-Zr alloys were identified as DO22-$(Al,Si)_3Ti$ and $Do_{23}-Al_3(Ti, Zr)$ each. Among the alloys, the mechanically alloyed Al-l0Ti-2Si alloy showed superior thermal stability and mechanical properties at elevated temperature. The additions of third elements, such as Si and Zr, to Al-Ti alloys seemed to improve the mechnical properties remarkably by stabilizing the microstructure and the precipitate phases in the consolidated alloys.