• Title/Summary/Keyword: raman

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Accretion Flow and Disparate Profiles of Raman Scattered O $VI{\lambda}{\lambda}1032$ and 1038 in the Symbiotic Star V1016 Cygni

  • Heo, Jeong-Eun;Lee, Hee-Won
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.2
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    • pp.88.2-88.2
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    • 2014
  • The symbiotic star V1016 Cygni shows the Raman scattered O VI features at $6825{\AA}$ and $7088{\AA}$. These are formed through inelastic scattering of O VI 1032, 1038 by atomic hydrogen. They exhibit characteristic double peak profiles with a stronger red peak, which is explained by the accretion flow around the white dwarf. In addition, the two Raman features have different profiles in such a way that the blue part of the Raman 7088 feature is relatively more suppressed than the Raman 6825 counterpart. We produced the Doppler maps of the two Raman features in order to trace the origin of the disparate profiles. We conclude that the profile difference is due to various O VI 1032 to O VI 1038 flux ratios in the accretion region. This is consistent with the picture where the slow stellar wind from the giant interacts with the accretion flow around the white dwarf.

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Raman characteristics of polycrysta1line 3C-SiC thin films grown on AlN buffer layer (AlN 버퍼층위에 성장된 다결정 3C-SiC 박막의 라만 특성)

  • Lee, Yun-Myung;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.93-93
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    • 2008
  • This paper presents the Raman scattering characteristics of poly (polycrystalline) 3C-SiC thin films deposited on AlN buffer layer by atmospheric pressure chemical vapor deposition (APCVD) using hexamethyldisilane (MHDS) and carrier gases (Ar + $H_2$).The Raman spectra of SiC films deposited on AlN layer of before and after annealings were investigated according to the growth temperature of 3C-SiC. Two strong Raman peaks, which mean that poly 3C-SiC admixed with nanoparticle graphite, were measured in them. The biaxial stress of poly 3C-SiC/AlN was calculated as 896 MPa from the Raman shifts of 3C-SiC deposited at $1180^{\circ}C$ on AlN of after annealing.

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Forward Raman amplification for the narrow band Stokes line by double-pass fiber Raman scheme in multi-mode fiber

  • Hwang, In-Duk;Lee, Choo-Hie
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.02a
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    • pp.238-239
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    • 2000
  • The optical fibers are an interesting medium for effective tunable optical frequency conversion in the spectral range of UV, Visible, and near-IR through the nonlinear processes. A number of papers for developing the wideband and flat-gain amplifier for the WDM system applications through the combination of EDFA or thulium-doped fluoride fiber amplifier and Raman amplifier, are reported$^{(1)}$ . Even though a variety of papers related to Raman amplifications are published, the amplification with the feedback of the residual pump is not investigated yet. Accordingly, in this paper, we report the characteristics of forward Raman amplification by the simple and double-pass fiber Raman configuration through the feedback of residual pump beam. (omitted)

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Raman Scattering Characteristics with Varying Liquid Water Temperature (유체온도 변화에 따른 Raman 산란 특성)

  • An, Jeongsoo;Yang, Sunkyu;Chun, Seyoung;Chung, Moonki;Choi, Youngdon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.5
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    • pp.621-627
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    • 1999
  • This paper presents Raman scattering of liquid water to obtain the characteristics with variation of temperature. Very clear Stokes-Raman signals were observed, which shows H-O vibration stretching and H-O-H vibration bending. The obtained spectrum were processed by FFT filter to extract the noise and base. The spectral shape of the H-O stretching provided a various sensitive signature which allowed temperature to be determined by a curve-fitting technique. Those are Maximum Intensity, Maximum Wave Length, FWHM(Full Width at Half Maximum), PMCR(Polymer Monomer Concentration Ratio) and TSIR(Temperature Sensitive Intensity Ratio). TSIR method shows the highest accuracy of $0.1^{\circ}C$ in mean error and $0.32^{\circ}C$ In maximum error.

The 1320-nm Excited FT-Raman Spectra of Lightly Iodine-Doped trans-Polyacetylene

  • Kim, Jin-Yeol;Yukio Furukawa;Akira Sakamoto;Mitsuo Tasumi
    • Macromolecular Research
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    • v.10 no.5
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    • pp.286-290
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    • 2002
  • The FT-Raman spectra of trans-polyacetylene films doped lightly with iodine were obtained with the 1320-nm laser line. The observed Raman bands are attributed to positively charged domains created by acceptor doping. The observed Raman wavenumbers of the V$_2$, (CC stretch), V$_3$, and V$_4$ bands (mixed of CC stretch and CH in-plan bending) of iodine-doped form are slightly higher than those of the corresponding bands of pristine trans-polyacetylene, whereas the contrary is the case for V$_1$, and (C=C stretch) of iodine-doped form. In particular, these upshifts of the V$_2$ and V$_3$ bands are distinguished from the downshifts of these bands in donor doping. The origin of doping induced Raman bands is discussed in terms of solitons and polarons.

Comparison of Near-Infrared Spectroscopy with Raman Spectroscopy from the Point of Nondestructive Analysis of Biological Materials

  • Takeyuki Tanaka;Hidetoshi Sato;Jung, Young-Mee;Yukihiro Ozaki
    • Near Infrared Analysis
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    • v.1 no.2
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    • pp.9-20
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    • 2000
  • Recently, near-infrared (NIR) spectroscopy and Raman spectroscopy have received keen interest as powerful techniques for nondestructive analysis of biological materials. The purpose of this review paper is to compare the advantages of NIR and Raman spectroscopy in the nondestructive analysis. Both methods are quite unique and often complementary. For example. NIR spectroscopy is very useful in monitoring in situ the content of components inside biological materials while Raman spectroscopy is very suitable for identifying micro-components on the surface of biological materials. In this article specific characters of the two spectroscopic methods are discussed first and then several examples of applications of NIR and Raman spectroscopy to the biological nondestructive analysis are introduced.

Feasibility Study for the Monitoring of Urea in Dialysate Solution using Raman Spectroscopy

  • Kim, Jae-Jin;Hwang, Jin-Young;Kim, Yong-Dan;Chung, Ho-Eil
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.805-808
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    • 2011
  • We have determined the urea concentration in an aqueous solution using Raman spectroscopy by incorporating a Teflon tube as an effective intensity correction standard as well as sample container. A non-overlapping Teflon band was used as the reference peak to correct Raman intensity variations that occasionally resulted from changes in laser power. To increase the sensitivity, we positioned a copper reflector inside the Teflon tube to maximize the collection of Raman scattering. The obtained accuracy using Raman spectroscopy was 0.53 mM, close to the range of accuracy of previous NIR studies (0.15-0.52 mM).

Raman Frequencies Calculated at Various Pressures in Phase I of Benzene

  • Tari, Ozlem;Yurtseven, Hamit
    • Journal of the Korean Chemical Society
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    • v.57 no.2
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    • pp.204-209
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    • 2013
  • We calculate in this study the pressure dependence of the frequencies for the Raman modes of A ($A_g$), B ($A_g$, $B_{2g}$) and C ($B_{1g}$, $B_{3g}$) at constant temperatures of 274 and 294K (room temperature) for the solid phase I of benzene. Using the mode Gr$\ddot{u}$neisen parameter of each lattice mode, which correlates the pressure dependence of the crystal volume and the frequency, the Raman frequencies of those modes are computed for phase I of benzene. Our results show that the Raman frequencies of the three lattice modes (A, B and C) increase as the pressure increases, as expected. The temperature effect on the Raman frequencies is not significant, which can be explained by the experimental measurements.

In-situ Raman Spectroscopy of Amorphous Hydrous $RuO_2$ Thin Films

  • Hyeonsik Cheong;Jung, Bo-Young;Lee, Se-Hee
    • Journal of the Korean Vacuum Society
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    • v.12 no.S1
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    • pp.49-51
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    • 2003
  • Amorphous hydrous ruthenium oxide thin films have attracted much interest owing to the possibility of using this material in electrochemical supercapacitors. Recently, it was found that this material is also electrochromic: during the charging/discharging cycle, the optical transmittance of the thin film is modulated. The physical and chemical origin of this phenomenon is not fully understood yet. In this work, we performed in-situ Raman spectroscopy measurements on amorphous hydrous ruthenium oxide thin films during the charging/discharging cycles. Unambiguous changes in the Raman spectrum were observed as protons were injected or extracted from the thin film. When the samples were annealed to reduce the water content, there is a consistent trend in the Raman spectrum. The origins of the Raman features and their relation to the electrochromic and/or supercapacitor characteristics is discussed.