• Journal of Korea Multimedia Society
• /
• v.16 no.1
• /
• pp.19-28
• /
• 2013

In this research, we presented an effective clustering method based on ICA for the analysis of huge Raman hyperspectral dental data. The hyperspectral dataset captured by HR800 micro Raman spectrometer at UMKC-CRISP(University of Missouri-Kansas City Center for Research on Interfacial Structure and Properties), has 569 local points. Each point has 1,005 hyperspectal dentin data. We compared the clustering effectiveness and the clustering time for the case of using all dataset directly and the cases of using the scores after PCA and ICA. As the result of experiment, the cases of using the scores after PCA and ICA showed, not only more detailed internal dentin information in the aspect of medical analysis, but also about 7~19 times much shorter processing times for clustering. ICA based approach also presented better performance than that of PCA, in terms of the detailed internal information of dentin and the clustering time. Therefore, we could confirm the effectiveness of ICA for the analysis of Raman hyperspectral dental data.

• Journal of the Korea Institute of Military Science and Technology
• /
• v.22 no.3
• /
• pp.433-440
• /
• 2019

In order to detect toxic chemical spread on field ground, we developed stand-off Raman spectrometer system which employed a deep UV laser. In this paper, the design and specification of various components in the spectrometer system are described. Some results when the detection system was tested on the outdoor roads are shown, which may help researching stand-off chemical detectors based on Raman spectroscopy.

• The Bulletin of The Korean Astronomical Society
• /
• v.44 no.1
• /
• pp.85.2-85.2
• /
• 2019

We developed a new grid-based Monte Carlo code to trace far UV He II line photons that are incident on a thick H I region and subsequently transferred through Rayleigh and Raman scattering with atomic hydrogen. In particular, we consider a neutral region that is moving away from the He II emission source which is either monochromatic or is described by a Gaussian profile. The resultant Raman scattered He II line profiles from a monochromatic source are characterized by a double peaked core part with an extended Raman red tail that is attributed to multiple re-entry events. Complicated behaviors are observed in the case of a Gaussian He II source including the formation of a secondary red peak near the Balmer center dependent on the H I column density. A preliminary application of our results to the CFHT data of the planetary nebula IC 5117 is presented.

• Bulletin of the Korean Chemical Society
• /
• v.11 no.4
• /
• pp.286-290
• /
• 1990

The surface enhanced Raman scatterings of Zn(Ⅱ) tetrakis (4-N-methyl pyridyl) porphyrins were studied in silver sol. Zn(Ⅱ) tetrakis (4-N-methyl pyridyl) porphyrin was found to be adsorbed on silver surface via flat-on geometry with some inhomogeneous distribution in the orientation of pyridyl groups. Both the selective enhancement of Raman modes depending on the mode character and the theoretical arguments of SERS are utilized to support the above conclusion. The surface induced substitution reaction of Mn(Ⅲ) tetrakis (4-N-methyl pyridyl) porphyrin chloride to Ag(Ⅱ) tetrakis (4-N-methyl pyridyl) porphyrin was detected via surface enhanced Raman spectrum.

• The Bulletin of The Korean Astronomical Society
• /
• v.46 no.2
• /
• pp.40.1-40.1
• /
• 2021

Hydrogen is the most abundant element in the universe, which is, in the cosmological context, attributed to its simplest structure consisting of a proton and an electron. Hydrogen interacts with an electromagnetic wave in astrophysical environments. Rayleigh scattering refers to elastic scattering, where the frequencies of the incident and scattered photons are the same. Rayleigh and resonance scattering is a critical role study Lyman Alpha objects in the early universe. The scattering causes the frequency and spatial diffusion of Lyα. In the case of Raman scattering, the energies of the incident and scattered photons are different. The photons near Lyβ convert to the optical photons near Hα through Raman scattering. The photon scattered by atomic hydrogen can carry both of the properties of the H I region and the emission region. I adopt a Monte Carlo approach to investigate the formation of the various spectral line features through Rayleigh and Raman scattering in highly thick media of atomic hydrogen. In this thesis, I present my works on radiative transfer involving the scattering processes between far UV photon and atomic hydrogen. I introduce scattering processes with atomic hydrogen and the spectral, spatial, and polarized information originating from the scattering.

• Journal of the Korean Chemical Society
• /
• v.68 no.3
• /
• pp.146-150
• /
• 2024

Precise molecular configuration elucidation of poly(3-hexylthiophene) (P3HT) through advanced spectroscopic techniques is pivotal for enhancing P3HT-based photovoltaic device efficiencies since its high charge-carrier mobility is directly correlated to its well-ordered structure. In this study, we examine Raman depolarization ratios of annealed and non-annealed P3HT films to elucidate their intermolecular π-π configurations. Our findings suggest that the backbone of the annealed film possesses stronger π-π conjugation overlaps than that of the non-annealed film owing to the greater depolarization ratio of the annealed film. In addition, the depolarization ratios are also supported by theoretical calculations, where parallel-stacked thiophene structures display a higher depolarization ratio compared with that of twisted-stacked structures, as calculated by the Møller-Plesset perturbation theory. This study highlights the utility of polarized Raman spectroscopy as a versatile tool for assessing the degree of molecular order in highly conjugated polymer films.

• Bulletin of the Korean Chemical Society
• /
• v.28 no.10
• /
• pp.1639-1640
• /
• 2007

• Polymer Science and Technology
• /
• v.9 no.5
• /
• pp.431-437
• /
• 1998

• Bulletin of the Korean Chemical Society
• /
• v.23 no.4
• /
• pp.633-636
• /
• 2002

• Bulletin of the Korean Chemical Society
• /
• v.30 no.1
• /
• pp.242-244
• /
• 2009