• Nuclear Engineering and Technology
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• 제33권2호
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• pp.166-174
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• 2001

An apparatus for detecting remote real-time uranium concentration using an optrode was developed. An optrode to detect uranium fluorescence as remote real-time control was designed. Fluorescence intensity at time 2ero was derived by the fluorescence signal processing and the algorithm to exclude the quenching effect of various quenchers and temperature fluctuations. This apparatus employing the above deriving method and the optrode has an error range within 6% in spite of serious fluorescence lifetime changes due to the quenching effect and temperature fluctuations. The detection limit is 0.06 ppm and the linearity is excellent between 0.06 ppm and 2 ppm on the aqueous uranium solution.

• Bulletin of the Korean Chemical Society
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• 제12권6호
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• pp.686-691
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• 1991

Emission quenching of photoexcited tris(${\alpha},{\alpha} '$-diimine)-ruthenium(II) complex cations, $RuL_3^{2+}$ (L: 2,2'-bipyridine, 4,4'-dimethyl-2,2'-bipyridine; 4,4'-diphenyl-2,2'-bipyridine; 1,10-phenanthroline; 5-methyl-1,10-phenanthroline; 5,6-dimethyl-1,10-phenanthroline or 4,7-diphenyl-1,10-phenanthroline) by $Cu^{2+}$, dimethylviologen $(MV^{2+})$, nitrobenzene (NB), and oxygen was studied in aqueous homogeneous and sodium dodecyl sulfate (SDS) micellar solutions. The apparent bimolecular quenching rate constants $k_q$ were determined from the quenching data and life-times of $^{\ast}RuL_3^{2+}$. In homogeneous media, the quenching rate was considerably slower than that for the diffusion-controlled reaction. The decreasing order of quenching activity of quenchers was $NB>O_2>MV^{2+}>Cu^{2+}$. The rate with $Cu^{2+}$ was faster as the reducing power of $^{\ast}RuL_3^{2+}$ is greater. On the other hand, the rates with NB and $O_2$ were faster as the ligand is more hydrophobic. This was attributed to the stabilization of encounter pair by van der Waals force. The presence of SDS enhanced the rate of quenching reactions with $Cu^{2+}$ and $MV^{2+}$, whereas it attenuated the quenching activity of NB and $O_2$ toward $RuL_3^{2+}$. The binding affinity of quenchers to SDS micelle and binding sites of the quenchers and $RuL_3^{2+}$ in micelle appear to be important factors controlling the micellar effect on the quenching reactions.

• 대한기계학회논문집B
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• 제26권7호
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• pp.919-926
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• 2002

Down scaled combustor undergoes increased heat loss that results in incomplete combustion or quenching of the flame as a consequence. Therefore, effect of enhanced heat loss should be understood to design a MEMS scale combustion devices. Existing combustion models are inadequate for micro combustors because they were developed for analysis of regular scale combustor where heat loss can be ignored during the flame propagation. In this research a combustion model is proposed in order to estimate the heat loss and predict quenching limit of flame in a down scaled combustor. Heat loss in the burned region is expressed in a convective form as a product of wall surface area, heat transfer coefficient and temperature difference. Comparison to the measurements showed satisfactory agreement of the pressure and temperature drop. Quenching is accounted for by introducing a correlation of quenching parameter and heat loss. The present model predicted burnt fraction of gases with reasonable accuracy and proved to be applicable in thermal design of a micro combustor.

• 대한치과재료학회지
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• 제43권4호
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• pp.317-322
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• 2016

The effect of ice-quenching after degassing on the hardness change during simulated porcelain firing in a metal-ceramic Pd-Au-Ag alloy was investigated by means of hardness test, field emission scanning electron microscopic observations, and X-ray diffraction analysis. The hardness decreased by ice-quenching after degassing, which was induced by the homogenization of the ice-quenched specimen. The decreased hardness by ice-quenching after degassing was recovered from the 1st opaque stage which was the first stage of the remaining firing process for bonding porcelain. The microstructural change showed that the increase in hardness during the remaining firing process was caused by precipitation. The ice-quenching after degassing did not affect the hardness change during the subsequent porcelain firing process.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2000년도 제31회 춘계학술대회
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• pp.48-53
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• 2000

The effects of added elements, such as Co or Nb, on wear properties of high speed steel by powder metallurgy(PM-HSS) had been evaluated in previous paper. The wear properties of materials, in fact, have been a]so influenced by heat-treating conditions. In this paper, the effects of heat-treating conditions on wear properties of PM-HSS have been evaluated. The wear tests have been performed as same conditions as previous paper using PM-HSS(5%Co-1%Nb) heat-treated under different quenching and tempering temperature. The result of this paper shows that wear resistance of PM-HSS is improved with relatively high quenching temperature. However tempering temperature is not sensitve to the wear resistance in range of high quenching temperature. It may be deduced by the fact that the shear strength of matrix by strengthening mechanisms of quenching aging in addition to dispersion-hardening is improved.

• 한국정밀공학회지
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• 제27권11호
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• pp.84-91
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• 2010

Heat treatment with carburized quenching process is widely used for automotive helical gear to improve its surface properties of hardness and strength. However, the gear can be deformed with the process over the allowable tolerance, which possibly makes noise, vibration and heat problems in operation. In this study, deformation of helical gear during heat treatment of carburized quenching was analyzed with a numerical method, incorporating coupled calculations of thermal conduction, carbon diffusion, phase transformation and thermal stresses. With the analysis, the effect of coolant temperature in quenching on the deformation was investigated. The result of the analysis revealed that the higher the coolant temperature became, the more change of helix angle and the more compressive stresses in the surface generated, because of delayed generation of martensite in the part.

• Journal of the Optical Society of Korea
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• 제14권4호
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• pp.298-304
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• 2010

The pair-induced quenching (PIQ) effect in a highly doped bismuth oxide-based erbium-doped fiber amplifier (EDFA) was theoretically and experimentally investigated. In the theoretical investigation, the bismuth oxide-based EDFA was modeled as a 6-level amplifier system that incorporated clustering-induced concentration quenching, cooperative up-conversion, pump excited state absorption (ESA), and signal ESA. The relative number of paired ions in a highly doped bismuth oxide EDF was estimated to be ~6.02%, determined by a comparison between the theoretical and the experimentally measured gain values. The impacts of the PIQ on the gain and the noise figure were also investigated.

• 열처리공학회지
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• 제12권3호
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• pp.206-214
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• 1999

The effect of cooling rate on carbide precipitation during quenching of austenitic manganese steel was investigated by optical microscopy, image analyzer and numerical analysis. A computer program based on the finite difference method for analyzing heat treatment processes was developed in order to evaluate cooling rates and the possibility of carbide precipitation during quenching. The area ratio of carbide precipitated in the austenite matrix was measured by the image analyzer, and used to determine the critical point of carbide precipitation. Temperature-dependent critical cooling rates at the critical points were calculated using the present simulation program, The calculated results showed a good agreement with the experimental ones.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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• pp.601-604
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• 2004

Precise position and attitude control of pico-satellite requires huge number of impulses of the order of 10$^{-6}$ Ns. MEMS solid rocket array is a promising propulsion system but the higher degree of miniaturization causes unreliable operation mainly due to quenching. In order to breakthrough this situation, a novel design of solid micro-rocket is proposed, which generates tiny impulses repetitively from a single rocket not from array. This unique micro-rocket is based on the utilization of quenching, which causes propellant reaction to sustain only in a small area. A test chip of a micro solid propellant tank and micro heater array is fabricated and ignition test is conducted. Obtained results show the feasibility of this concept and future direction of this quenching-based propulsion is discussed.

• 대한기계학회논문집
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• 제13권3호
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• pp.419-423
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• 1989

본 연구에서는 담금유의 냉각능에 관한 상세한 연구는 우리나라에서는 아직 미비한 상태에 있으나, 저자 등은 제1보에서 서술한 실험장치 및 은시편을 사용하여 여러 광.식물성유의 냉각곡선을 구하고, 이로부터 냉각성능을 나타내는 파라미터들을 구하여, 객관적인 냉각성능을 평가하였다.