• Title/Summary/Keyword: purge interval

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Effect of Hydrogen Recirculation on the Performance of Polymer Electrolyte Membrane Fuel Cell with Dead Ended Mode (Dead ended 모드에서 수소 재순환이 고분자전해질연료전지의 성능에 미치는 영향)

  • Kim, Junseob;Kim, Junbom
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.531-538
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    • 2019
  • As the performance of PEMFC has been improved, the water and heat generated by reaction have increased so, the water and heat management of PEMFC is becoming more important. In this study, hydrogen recirculation was applied as the water management technique and the effect of recirculation flow rate, purge interval and duration on the performance of PEMFC was investigated. Anode pressure, fuel humidity and utilization, water discharge amount was measured to check the effect of purge conditions on performance. As the recirculation flow rate has increased, the performance of PEMFC became lower due to decrease of anode outlet pressure. According to the purge conditions, instantaneous voltage drop has occurred because of accumulated water. In frequent purge conditions, the performance of PEMFC gradually decreased due to fuel humidity control failure. Stable performance and high fuel utilization was achieved on this work by analyzing the effect of purge conditions.

Performance Enhancement and Recovery Method of Open Cathode PEMFC (오픈 캐소드형 고분자전해질 연료전지의 성능향상과 회복기법)

  • Lee, Kitaek;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.118-124
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    • 2017
  • An air cooling, open cathode type polymer electrolyte membrane fuel cell (PEMFC) has the advantages of system simplification and cost effectiveness. Open cathode PEMFC could suffer from reduced performance due to the membrane dehydration in low humidity of air. Effects of the cathode air flow rate, anode purge interval and long term storage on PEMFC performance were investigated in this work. Fan voltage is an important factor on air cooling PEMFC performance because the cathode air flow rate and stack temperature were controlled by fan voltage. The dead ended anode (DEA) method was applied to increase hydrogen usage. Periodical purge was used to discharge accumulated water and gas. The influence of long term non-operating condition on PEMFC performance degradation due to the membrane dehydration was also studied and the quick recovery method was developed.

A study on the characteristic of the anodic dead-end mode PEM fuelcell and performance improvement by pulsation effect (수소 데드 앤드 연료전지의 특성 및 맥동을 이용한 성능 향상에 관한 실험적 연구)

  • Choi, Jong-Won;Hwang, Yong-Sheen;Kim, Sung-Il;Ha, Jeong-Hoon;Park, Joon-Ho;Cha, Suk-Won;Kim, Min-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.336-340
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    • 2009
  • This paper presents experimental results carried out on the purge characteristic of the anodic dead-end mode fuelcell and how to improve the cell performance by pulsation effects. The dead-end mode fuelcell has some merits that a fuel supplying device is not needed and the cell power is higher than that in the open mode fuelcell. However, the purge is necessary for preventing the porous media from being flooded by liquid water formed in the channel. At this time, the un-reacted fuel is discharged with the liquid water together in purge process. The discharged fuel can make the fuel efficiency lower. Therefore, the number of purge times should be decreased for the better fuel efficiency. In this study, the outlet of the anode channel was equipped with a purge solenoid valve and a pulsation generator. The purge times was decreased when the current density decreased and operation pressure increased without the pulsation effects. In addition, when the pulsation effects such as various frequencies or amplitudes were applied, purge times was alleviated up to 40%.

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Effect of Porous Flow Field on PEMFC Performance with Dead Ended Anode System (Dead ended anode 시스템에서 다공성 유로가 연료전지 성능에 미치는 영향)

  • Kim, Junseob;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.646-652
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    • 2022
  • The dead-end anode (DEA) system is a method that closes the anode outlet and supplies fuel by pressure. The DEA method could improve fuel usage and power efficiency through system simplification. However, flooding occurs due to water and nitrogen back diffusion from the cathode to the anode during the DEA operation. Flooding is a cause of decreased fuel cell performance and electrode degradation. Therefore, tthe structure and components of polymer electrolyte membrane fuel cell (PEMFC) should be optimized to prevent anode flooding during DEA operation. In this study, the effect of a porous flow field with metal foam on fuel cell performance and fuel efficiency improvement was investigated in the DEA system. As a result, fuel cell performance and purge interval were improved by effective water management with a porous flow field at the cathode, and it was confirmed that cathode flow field structure affects water back-diffusion. On the other hand, the effect of the porous flow field at the anode on fuel cell performance was insignificant. Purge interval was affected by metal foam properties and shown stable performance with large cell size metal foam in the DEA system.

Effect of Hydrogen Purge Mode on the Polymer Electrolyte Membrane Fuel Cell (PEMFC) Performance under Dead-ended Anode Operation (양극 닫힌계 작동에서 수소 배출 방법에 의한 고분자전해질 연료전지 성능 영향)

  • Kim, Junseob;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.30 no.6
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    • pp.687-693
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    • 2019
  • As the hydrogen fuel cell market is expanded starting from hydrogen electric vehicle and power generation field, the demand for fuel cells and hydrogen increases recently. Therefore, research works on fuel cell durability and fuel efficiency are required in order to activate the fuel cell market and commercialization. A dead-ended anode system was used in this study to optimize the fuel cell performance and fuel efficiency. The effect of purge condition according to the applied current and hydrogen supply pressure on the fuel cell performance were evaluated. In addition, the influence of water back diffusion on the different electrolyte membrane thickness was analyzed. The accumulated water was purged with a solenoid valve in the case of 3% voltage decrease in the dead-ended anode system. The experiment was performed with the hydrogen supply pressure of 0.1~0.5 bar and purge duration of 0.1~1 second. A maximum fuel efficiency of 98.9% was achieved under the purge duration of 0.1 s and hydrogen supply pressure of 0.1 bar with a NR 211 (25.4 um) membrane. However, the fuel cell performance decreased in a long-term operation due to some frequent flooding. The fuel efficiency and purge interval increased due to decreased back diffusion rates of the water and nitrogen with a NR 212 (50.8 um) membrane.

Development of Gas Generator for Liquid Rocket Engine to prevent of damage for LOx post (가스 발생기 분사기 LOx post 손상 방지를 위한 분사기 개발)

  • Song Ju-Young;Kim Jong-Gyu;Moon Il-Yoon;Han Yeoung-Min;Choi Hwan-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.353-357
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    • 2005
  • LOx post damage occurs from the development process of the full-scale gas generator which is necessary to 30 tonf class engine development was described. The cause and analysis for damage was described. The combustion test result of 4 injector, the full-scale gas generator and redesigned injector was described. Combustion instability, purge, the low momentum of LOx spray, small recess number, the low flow of LOx, and the high spray angle is main reason the possibility of knowing. The redesign for the injector in the direction of increase of recess number, increase of LOx and fuel spray angle, decrease of gap interval between the LOx post outer wall and fuel screen and increase of LOx post wall thick became accomplished.

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Composition and Physico-Chemical Properties of Vacuum Packaged Korean Pork Loins for Export during Cold Storage (수출용 진공포장 냉장 돈육 등심의 일반성분 및 물리화학적 품질변화)

  • 최염순;박범영;이성기;김일석;김병철
    • Food Science of Animal Resources
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    • v.22 no.2
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    • pp.151-157
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    • 2002
  • The Korean fresh pork loins in vacuum packaged were obtained from three different Korean export companies and investigated for their proximate composition and physico-chemical characteristics. The fresh pork loins were stored at 2$^{\circ}C$ for 50 days and analyzed with an interval of 5∼10 days. In proximate analyses, the moisture contents of pork loins from the company I were higher, the protein contents from the company II were higher, and fat contents from the companies II and III were higher compared to those from the other companies. The pH of loins increased as storage period increased. The shear value of loins from company II showed significantly lower level and tended to decrease during storage. However, the water holding capacity and the purge loss of loins from company II increased during storage periods.

Valuation of Air Quality in the Metropolitan Seoul (3중양분선택·개방형 CVM을 이용한 수도권 대기질의 편익가치)

  • Rhee, Hae-Chun;Chung, Hyun-Sik;Kim, Tae-Yung
    • Environmental and Resource Economics Review
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    • v.13 no.3
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    • pp.387-415
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    • 2004
  • This paper is intended to valuate air quality of the Seoul Metropolitan Area using triple-bound dichotomous choice (TBDC) contingent valuation method (CVM), supplemented by open-ended (OE) questionnaires. In the OE questionnaires, some respondents would state their willingness to pay (WTP) outside the limits of the WTP interval. It implies that WTP estimates based on the customary dichotomous choice (DC) questionnaires can be biased. We argue that the TBDC-CVM refined with OE questions is more efficient, because the latter helps purge the former of corrupted data that may have been collected by the TBDC interview process.

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Experimental Evaluation of an Analytical Method for Chlorofluorocarbons (CFSs) in Air and Water Using Gas Chromatography (가스 크로마토그래피를 이용한 대기와 물시료의 CFCs(chlorofluorocarbons) 분석법의 실험적 평가)

  • Koh, Dong-Chan;Choi, Beom-Kyu;Kim, Yong-Je
    • Economic and Environmental Geology
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    • v.40 no.1 s.182
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    • pp.129-140
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    • 2007
  • CFC(CFC-12, CFC-11 and CFC-113) analytical system for air and water was constructed using a customized purge and trap extraction device and a gas chromatograph with an electron capture detector. Sampling methods of air and water for CFCs were also established. The analytical system was experimentally optimized to result in reproducibilities of triplicates less than 2% for current air samples and less than 5% for groundwater samples with CFC-12 concentration of 160 to 180 pg/kg, and verified with respect to the CFC system in USGS, which showed analytical results were in agreement within 10%. CFCs in air were monitored at three sites over 19-month period in the central part of South Korea, and the result indicates no significant local sources of CFCs in those areas. For groundwater in Jeju Island, CFCs were measured over a year with a two-month interval. The time-series data showed seasonal fluctuations which could be interpreted by the effect of recharge pulse derived from large amount of rainfall during monsoon period with a few month delay, which indicates high permeability of basaltic rocks in Jeju Island.

Influence of Rotation Number in the Effect of PC6 on the Heart Rate: A Pilot Study (내관 자침 시 염전 횟수가 심박 변이도에 미치는 영향: 예비연구)

  • Lee, Bong Hyo;Chung, Jae Hwan;Son, Jigook;Heo, Jeong Hyeon;Park, Ji Ha;Kim, Hee Young;Lee, Sang Nam;Lee, Young Joon;Kim, Mi Ryeo;Lim, Sung Chul;Kim, Jae Su;Lee, Yun Kyu;Lee, Hyun Jong;Jung, Hyun Jung;Jung, Tae Young
    • Korean Journal of Acupuncture
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    • v.30 no.2
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    • pp.88-96
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    • 2013
  • Objectives : In the acupuncture treatment of Korean Medicine, the Tonifying or Purging depending on how many times the needle is rotated has been used widely. However, there is little evidence about the optimal number of rotation. This study, therefore, was aimed to investigate the optimal number of rotation. Methods : Heart rate variation was measured before and after exercise in 20 healthy adults. Acupuncture was performed at PC6 immediately after exercise according to the protocol of each group without remaining. Pre-exercise and post-exercise measurements were compared and the rotation number that produced statistically significant difference was investigated. Results : Significant differences were found in the heart rate variation and R-R interval Average, between non-rotation group (control) and both of 15 times rotation group of tonifying and 6 times rotation group of purging. Conclusions : Significantly effective number of rotation in the effect of PC6 on the HR and RRAv was 15 times in the tonifying and 6 in the purging respectively.