• 펄프종이기술
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• 제47권5호
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• pp.134-140
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• 2015

This study was carried out to evaluate whether EVAc, acryl latex and biobinder could substitute the part of SB latex for pre-coating color formula or not. Different coating colors prepared through the substitution of 30% SB latex with EVAc, acryl latex, and biobinder were applied for pre-coating layer. 100% SB latex is used as a binder for top coating color. The optical properties, gloss, roughness, stiffness, dry- and wet-pick strength were measured. There were no significant differences in the brightness, whiteness, opacity, roughness, ink set-off and gloss of paper coated with 5 different coating colors. However the stiffness, dry- and wet-pick strength were somewhat lower than those of conventional coating color which 100% SB latex was used as a binder. Although the part of SB latex could be substituted with EVAc, acryl latex and biobinder without sacrificing the qualities of coated paper. Further researches on the improvement of stiffness, dry- and wet-pick strength, and the optimization of rheology of coating color in order to improve the qualities of coated paper are strongly recommended.

• 펄프종이기술
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• 제33권4호
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• pp.7-14
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• 2001

Recycled fibers usually give slow drainage in the paper forming process, which limits the application of more refining to the recycled fibers for improving paper strength and formation. To use recycled fibers more effectively, especially OCC, developing very efficient handling technique of short fibers and fines is inevitable. We tried to make hard flocs of fractionated short fibers and fines, which were the main cause of slow drainage, by adding excessive amount of retention aid selectively on them. This technique was proved to increase drainage considerably, but to decrease strength properties, compared to the conventional technique of adding the same amount of polymers to the whole furnish in the lab test. The bonding capability of short fibers and fines in Korean OCC was very poor. Various chemical treatment on the short fibers and fines of the Korean OCC did not improve their bonding and optical properties. One of the reasons of no improvement in their properties was their high amount of ashes.

• 펄프종이기술
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• 제47권2호
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• pp.70-79
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• 2015

This study was carried out to analyze deterioration characteristics of color-pigments painted Hanji to preserve and restore the cultural properties. On the traditional painting technique, glue was used with pigments in various ways for painting, but it eventually caused the deterioration of paintings. Thus, five colors were selected and analyzed for this study for investigating their characteristics of deteriration. Three kinds of glues (Wugyo, Nokgyo, and Togyo) and two kinds of pigments (Chinese and Gilsang) were painted on the Hanji for the accelerated aging test. And then color fastness of pigments and tensile strength of painted Hanji were measured for the estimation of deterioration degree. The results of SEM-EDS showed that Chinese pigments including blue, yellow, green, and red were composed of inorganic substances but the brown was organic substance. Gilsang pigments were composed mainly of Si and Ti ions. Color fastness of the Gilsang pigment blue, yellow, green, and brown were better than those of Chinese. Chinese pigment brown with organic substance showed the worst color fastness. Generally, Chinese pigments painted Hanji showed higher tensile strength than Gilsang in the accelerated aging test. Hanji treated with Chinese pigment and Nokgyo (antler glue) blends and Gilsang pigment and Togyo (rabbit pelt glue) blends showed higher tensile strength than the others. And Andong Hanji showed the highest tensile strength.

• 펄프종이기술
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• 제47권2호
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• pp.53-60
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• 2015

The effects of stirring speed during filler modification by dual polymers on flocculation and reflocculation of PCC (precipitated calcium carbonate) particles and its effect on handsheet properties were elucidated. PCC surface was modified by adsorbing A-PAM (anionic polyacrylamide) and C-starch (cationic starch) in series at various stirring speeds. It was found that increasing stirring speed during filler modification decreased the initial floc size of PCC. Continuous stirring with the same speed for filler modification resulted in the decrease of a floc size, eventually reached a steady state. The variations in a floc size was influenced by the stirring speed during filler modification: the lower the stirring speed during filler modification, the larger the floc size variations. Conclusively, the stability of PCC floc could be improved by increasing the stirring speed. In addition, the stirring speed influenced the handsheet properties. The smaller the PCC floc, the lower the strength of handseet. However, too much larger floc size also deteriorated paper strength. There exists an optimum floc size in term of paper strength which shall be controlled by stirring speed during filler modification.

• 펄프종이기술
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• 제42권5호
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• pp.37-46
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• 2010

This study was carried out to develop new application field and obtain the basic data of mixed paper with wood pulp and chitosan fiber for producing functional paper. Two types of wood pulp, such as SwBKP and HwBKP, were mixed with chitosan fiber. Physical and optical properties, water vapor absorption, air permeability, antibacterial activity and ash were measured. And the surface morphology of manufactured paper was observed using SEM. The results are as follows. It was revealed that density, breaking length, burst index, tear index, folding endurance and brightness were reduced but water vapor absorption and air permeability were on the rise in the structural view of SwBKP according to increasing the chitosan fiber ratio. Those HwBKP added chitosan fiber were great not only in the strength but also water vapor absorption and air permeability except for brightness. The water vapor absorption was lower and the air permeability was higher in the HwBKP added various chitosan fiber ratios than those with no chitosan fiber. It is estimated that these properties were related with various mixed rate of chitosan fiber. Particularly, air permeability was strongly dependent on the mixed rate of chitosan fiber. The chitosan fiber has superior antibacterial property, comparing with wood fiber. Adding chitosan fiber to the wood pulp was found to have an excellent antibacterial activity, more than 90%. The ashes were determined within 0.5%. Special bonds between chitosan fiber and wood pulp was observed by SEM and it means that the chitosan fiber were combined equally in the interior of wood pulp. In conclusion, mixing wood pulp with chitosan fiber can not only improves the quality of paper but also extend the usage of paper as a functional paper by using inherent property of chitosan. After all, production of functional paper added chitosan fiber is expected for new valuable industry of paper.

• 펄프종이기술
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• 제48권3호
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• pp.14-22
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• 2016

Pulping is a stage that can change fibrous raw materials into pumpable slurry. Recovered paper can be defibrated to individual fibers by shear stress generated by rotation of a rotor and water. Disintegration of recovered paper is more complicated than that of chemical pulp. When disintegration of recovered paper is poor, screening and cleaning efficiency will be worse and properties of paper will also be deteriorated. Therefore, pulping is an important treatment for improvement of availability of recovered paper and process runnability. In this study, degrees of disintegration of KOCC obtained from a linerboard mill was analyzed with a pilot-scale screen. Flake removal of KOCC slurry was performed by a pilot screen. Simple pumping action gave a positive effect on disintegration of KOCC. After pumping for 10 minutes, paper strength increased without the change of water retention value and fibrillation of KOCC slurry. This phenomena can be explained by modification of hornified surface of KOCC fibers by shear stress generated by pumping. Consequently, disintegration efficiency of KOCC can be enhanced by control of retention time at pulper or an agitation power at chests of papermaking process.

• 펄프종이기술
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• 제43권5호
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• pp.60-67
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• 2011

Hemicelluloses pre-extracted from Korean mixed wood chip were investigated as a wet-end additive. Hemicelluloses dissolved in hot water and alkali solution were isolated by ethyl alcohol precipitation from pre-extractives. They showed molecular weight of 9,000 ~ 27,000 g/mol as revealed by size exclusion chromatography. The reduction of molecular weight through hot water extraction was caused by autohydrolysis. Chemical composition of the hemicelluloses were analyzed with high-performance liquid chromatography and UV-Vis spectroscopy. As the surface charge of isolated hemicelluloses were negative, the adsorption of hemicelluloses onto softwood unbleached kraft pulp fiber was promoted by poly-DADMAC. The physical properties of handsheets increased as the molecular weight of hemicellulose increased. On the other hands, the optical property decreased with hemicellulose adsorption.

• 펄프종이기술
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• 제42권4호
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• pp.39-44
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• 2010

To increase the fracture toughness of paper made of Sw-BKP, refining and kneading conditions were analyzed. Curl and kink was known to increase the strain at break and the fracture touhness. Sequence of multiple stage beating, beating load and kneading were compared. When we applied a kneading treatment using a kneader at the final step, the most of the fiber transformation such as curl and kink occurred, the more the bulk and air-permeability improved. Physical strength and TEA(tensile energy absorption) were increased higher when kneading treatment before refining than only refining treatment was performed. TEA was increased because of higher elongation. It was found that the highest fracture toughness was obtained when applying the kneading treatment to the fibers in the pre-treatment step rather than in the middle step of beating or in the final step of beating.

• 펄프종이기술
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• 제37권4호통권112호
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• pp.38-43
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• 2005

Natural Com Starch(NCS) spray system has been widely used In multiply board mill for the better bonding strength between board layers. However the unsuitable NCS spray system could lead to a drop in plybond efficiency of multiply board. It could also result in the accumulation of unretained-starch in the white water system, which could not only rise in BOD and COD level but also reduce the effects of rosin-alum sizing system and other additives. In this study, the simple and rapid method by UV-spectroscopy for measuring the starch contents in the white water was proposed, and the quantitative analysis for dissolved starch content in white water was carried out in two kinds of board production process. It could be confirmed that about 150 ppm of oxidized starch was retained in white water dewatered from undertop ply of multiply board process, and about 470 ppm of natural starch was dissolved in white water originated from unsuitable spraying system in the multiply board production lines for cup base paper.

• 펄프종이기술
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• 제44권1호
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• pp.24-30
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• 2012

This study was carried out in order to analyze a repletion possibility about color change of base paper after elevated heat exposure when wooden fillers were added. Fillers may reduce production cost because its price is usually inexpensive than pulp with higher bulkiness. Wooden fillers have lower density than inorganic fillers, so they may increase bulk more than inorganic fillers. Never the less wooden fillers have disadvantage of yellow color by heat exposure, so the addition level should be carefully controlled. Brightness and whiteness changes after elevated heat exposure depending on coating weight were analyzed. With wooden fillers addition, breaking length and surface strength decreased but bulkiness increased. As the exposure time of elevated heat increased the coating paper with wooden fillers addition had higher brightness and whiteness values than those of inorganic fillers.