• 산업기술연구
• /
• 제7권
• /
• pp.27-47
• /
• 1987

Fine anthracite is very difficult to upgrade by conventional processes such as gravity concentration or froth flotation, because large quantities of fine coals are generated at the mining and preparation stages and a significant portion of these fine coals are mixed with gangue minerals. This study, therefore, was carried out for the purpose of improving recovery of low ash clean coal, effective beneficiation of low-grade coking coal and removal of sulphur from high-sulphur coals by employing the method of selective agglomeration using oil or polystrene flocculants, for coals which are generally hydrophobic in nature will be extracted by using flocculants. Studies were performed by varying solid concentration, concetration of bridging liquid, mixing speed and mixing time, balling speed and balling time, dispersant dosage, flocculant dosage, pulp pH, and particle size. The results were : when the methods of the oil agglomeration and selective flocculation were employ(in the two process the sample was ground to the size of -74 micron), 1) ash content of the agglomerated coal was 9.85, 7.83%, 2) combustibel recovery of it was 98.5%, 93.5%, respectively. It was observed in selective flocculation that polystyrene is an effective flocculant for coal, De-entrapment of shale from the concentrate flocculated by mechanical agitation was necessary for substantional reductions in final ash content.

• 임산에너지
• /
• 제23권1호
• /
• pp.45-68
• /
• 2004

The word of lignin is derived from the Latin word 'ligum' meaning wood. Lignin is complex polymer consisting of coniferyl alcohol, sinapyl alcohol and p-coumaryl alcohol unit and has an amorphous, three dimensional network structure which is hard to be hydrolyzed by acid. Lignin is found in the cell wall of plants lignified. The mode of polymerization of these alcohols in the cell wall lead to a heterogeneous branched and cross-linked polymer in which phenyl propane units are linked by carbon-carbon and carbon-oxygen bonds. This polymerization of precursors, p-coumaryl alcohol, coniferyl alcohol and sinapyl alcohol to lignin is formed by enzymic dehydrolyzation. The reaction is initiated by an electron transfer which results in the formation of resonance-stabilized phenoxy radical. The combination of these radicals produces a variety of dimers, trimers and oligomers and so on. Lignin research has been divided into basic and practical application field. The basic studies contains biosynthesis, chemical structure, distribution in the cell wall and reactivity by reductants, oxidants and organic solvents. The application research will be approached the reaction of lignin in various pulp making involving pulp bleaching and its effect on pulp qualities. Lignin also will be studied for the production of fine chemicals, polymer products and the conservation into an energy source like petroleum oil because the amount of lignin produced in pulp making process is more than 51,000,000 tons per year in the world. Both basic and application research must lay emphasis on the development for the utilization of lignin and the pulping process. But these researches can not be completed without understanding lignin structure containing functional groups. Therefore, this paper was focused on the review of lignin formulation which has been studied since 1948 in chronological order. This review was based on monomers, dimers, trimers and tetramers of phenyl propane unit structures which were isolated and identified by different methods from various wood.ious wood.

• 기술혁신학회지
• /
• 제8권1호
• /
• pp.209-219
• /
• 2005

o Korea consumed total 198.5 million TOE and the portion of crude oil n was 100.4 million TOE in 2002 which marked the 10th largest energy consuming country and ranks the $4^{th}$ crude oil consumer in the world. o Industries consumed 51.5% of the total energy and 93% of industrial energy was used at the manufacturing industries such as steel, textile, chemical, food and beverage, pulp and paper, and timber industries, which lead to energy intensive industries numbered 110,000. o Also Korea ranks the $10^{th}$ greenhouse gas emission countries of the world (134.9 million TC) which may cause Korean industries to suffer severely during the implementation of United Nations Framework Convention on Climate Change (UNFCCC). o Therefore, the target of the study is to develop a model for the analysis and design of industrial complex by integration of the energy usage and environmental problems. o The research work contents are as followings: -Analysis of Korea energy consumption -Concept of the integration of energy and environment problems - Basic concept of industrial complex planning - Case study (1) - Recommendation and conclusion

• 펄프종이기술
• /
• 제47권1호
• /
• pp.24-34
• /
• 2015

Domestic companies supplying electricity must increase obligatory duty to use renewable energy annually. If not met with obligatory allotment, the electricity-supply companies must pay RPS (Renewable Portfolio Standards) penalty. Although the power plants using a pulverizing coal firing boiler could co-fire up to around 3 per cent with wood pellets mixed in with coal feedstock without any major equipment revamps, they recorded only about 60 per cent fulfillment of RPS. Consequently, USD 46 million of RPS penalty was imposed on the six power supplying subsidiaries of GENCOs in 2014. One of the solutions to reduce the RPS penalty is that the power supply companies adopt the co-firing of torrefied lignocellulosic biomass in coal plants, which may contribute to the use of over 30 per cent of torrefied biomass mixed with bituminous coals. Extra binder was required to form pellets using torrefied biomass such as wood chips, PKS (Palm Kernel Shell) and EFB (Empty Fruit Bunch). Instead of corn starch, 30, 50 and 70 per cent of Larix saw dusts were respectively added to the torrefied feedstocks such as Pinus densiflora chips, PKS and EFB. The addition of saw dusts led to the decrease of the calorific values of the pellets but the forming ability of the pelletizer was exceedingly improved. Another advantage from the addition of saw dusts stemmed from the reduction of ash contents of the pellets. Finally, it was confirmed that torrefied oil palm biomass such as PKS and EFB could be valuable feedstocks in making pellets through improved binding ability.

• 공업화학
• /
• 제10권5호
• /
• pp.726-730
• /
• 1999

잉크조성분의 차이, 탈묵약품 및 열화기간에 따른 신문지의 탈묵성을 비교하였다. 잉크조성분으로 용제, 즉 대두유 30%(A), 대두유 50%(B), 광물유 45%(C) 및 아마인유 42%(D)를 각각 넣어 잉크를 제조하고 신문용지에 인쇄하였다. 신문지를 6개월 동안 자연 열화시키면서 열화기간에 따른 탈묵성을 비교하였다. 또한 탈묵약품의 차이에 따른 동일시료의 탈묵성을 비교하였다. 신문지 탈묵펄프의 백색도는 잉크조성분, 열화기간과 탈묵약품에 따라 영향을 받았다. 즉 탈묵펄프의 백색도는 열화기간의 연장에 따라 낮아지며, 광물유 잉크, 대두유 잉크(30%), 대두유 잉크(50%), 아마인유 잉크 순으로 낮아졌다. 또한 탈묵약품에 따라서는 주어진 수율에서 lipase, cellulase, 기존 화학약품 탈묵방법 순으로 백색도가 감소하였다. 주어진 백색도에서 탈묵 수율은 백색도 변화와 동일한 경향을 나타내었다. 탈묵펄프의 강도는 열화기간에 따라 1개월까지는 조금 증가하고 그 후에는 감소하거나 현상태를 유지하였다. 인쇄 잉크의 조합 즉, 광물유, 아마인유, 대두유 잉크 순으로 탈묵펄프의 제반 강도가 낮아졌다. 탈묵약품에 따라서는 lipase, 기존 화학약품, cellulase 순으로 탈묵펄프의 제반 강도가 낮아졌다.

• 한국펄프종이공학회:학술대회논문집
• /
• 한국펄프종이공학회 2011년도 춘계학술발표회 논문집
• /
• pp.171-178
• /
• 2011

During the last decades, global warming from the increased amount of greenhouse gases, mainly carbon dioxide has become a major political and scientific issue. Burning fossil fuels (natural gas, coal and oil) releases $CO_2$, which is also a major cause of global warming. Among the clean environment, wood pellets are considered as promising renewable fossil fuels because of clean burning characteristics, reduction of particulate and NOx emission from combustion. In Korea, more than 50% pellets have to be imported every year because of shortage of feedstocks. On the other hand, about 80% of wood pulps are greatly dependent upon overseas products due to limited forest resources. Under this situation, this study explored how efficiently we have to use forest biomass instead of total dependence on wood as raw materials for pellets.

• 펄프종이기술
• /
• 제45권2호
• /
• pp.13-20
• /
• 2013

In this study, two biodegradable polymer(PLA, PBS) emulsions were treated on agricultural packaging paper such as fruit bagging paper. Water-repellency, mechanical properties, and SEM image with thermal aging were measured on the emulsion treated fruit bagging paper. Biodegradable polymers(such as poly lactic acid, poly butylene succinate) emulsion treated fruit bagging paper had higher water-repellency and strength than other water-repellent(such as acrylic repellent, linseed oil and paraffin wax) treated fruit bagging paper. According to FE-SEM results of polymer emulsion coated fruit bagging paper, the colloidal particles of emulsion after thermal treatment (looks like being) were adhered to the fibers. Thus, using biodegradable polymer emulsion is expected to protect a fruit for a long time.

• 펄프종이기술
• /
• 제47권6호
• /
• pp.5-21
• /
• 2015

The common production methods of nanocellulosic (cellulosic nanofibrils, CNF) materials from wood are being reviewed, together with large scale applications and particularly papermaking applications. The high energy demand for producing CNF has been one particular problem, which has been addressed over the years and can now be considered solved. Another problem was the clogging of homogenizers/microfluidizers, and the different routes to decrease the energy demand. The clogging tendency, related to the flocculation tendency of fibres is discussed in some detail. The most common methods to decrease the energy demand are TEMPO-oxidation, carboxymethylation and mechanical/enzymatic pre-treatments in the order of increased energy demand for delamination. The rheology characteristics of CNF materials, i.e. the high shear viscosity, shear thinning and the thixotropic properties are being illuminated. CNF materials are strength adjuvants that enhance the relative bonded area in paper sheets and, hence increase the sheet density and give an increased strength of the paper, particularly for chemical pulps. At the same time papers obtain a lower light scattering, higher hygroexpansion and decreased air permeability, similar to the effects of beating pulps. The negative effects on drainage by CNF materials must be alleviated through the appropriate use of microparticulate drainage aids. The use of CNF in films and coatings is interesting because CNF films and coatings can provide paper/board with good oxygen barrier properties, particularly at low relative humidities. Some other high volume applications such as concrete, oil recovery applications, automotive body applications and plastic packaging are also briefly discussed.

• Journal of the Korean Wood Science and Technology
• /
• 제16권2호
• /
• pp.79-89
• /
• 1988

본(本) 실험(實驗)은 리기다소나무(Pinus rigida Mill)를 petroleum ether로 추출(抽出)한 추출액(抽出被)과 흑액(黑液)으로부터 얻은 tall oil과의 조성(組成)의 변화(變化)를 조사(調査)하기 위하여 실시(實施)하였다. 생재(生材)의 유기용매(有機溶媒) 추출액(抽出液)과 tall oil 을 DEAE-Sephadex 칼럼과 aluminum oxide 칼럼을 사용하여 수지산(樹脂酸)과 지방산(脂肪酸)으로 분리(分離)한 후 이를 개스크로마토 그래프로 분석(分析)하였다. 본(本) 실험(實驗)에서 얻는 결과(結果)는 다음과 같다. 생재(生材)의 유기용매(有機溶媒) 추출액(抽出液힘)과 tail oil은 주로 수지산(樹脂酸)으로 구성(構成)되어 있고 특히 abietic-type acide의 함량(含量)이 매우 높게 나타났으며, tall oil의 조성(組成)은 생재(生材)의 유기용매(有機溶媒) 추출물(抽出物)에 비(比)해 지방산(脂肪酸)의 함량(含量)이 증가(增加)한 반면 수지산(樹脂酸)은 감소(減少)하였고, 증해시(蒸解時) 고온(高溫)과 증해약품(蒸解藥品)에 의하여 불포화(不飽和) 지방산(脂肪酸)의 이중결합(二重結合) 위치(位置)의 변화(變化) 및 이성질화(異性質化)에 의하여 미확인(未確認) 물질(物質)의 양(量)이 증가(增加)하였다.

• Food Science and Biotechnology
• /
• 제16권1호
• /
• pp.37-42
• /
• 2007

The biotransformation of monoterpenic agro-industrial wastes (turpentine oil and essential orange oil) was studied. More than 40 fungal strains were isolated from Brazilian tropical fruits and eucalyptus trees and screened for biotransformation of the waste substrates. Solid phase microextraction was used to monitor the presence of volatile compounds in the headspaces of sporulated surface cultures. The selected strains were submitted to submerged liquid culture. The biotransformation of R-(+)-limonene and ${\alpha},\;{\beta}-$ pinenes from the oils resulted in ${\alpha}-terpineol$ and perillyl alcohol, and verbenol and verbenone, respectively, as the main products. The selected strains were also placed in contact with ${\alpha}-$ and ${\beta}-$ pinenes standards. It was confirmed that verbenol, verbenone, and ${\alpha}-terpineol$ were biotransformation products from the terpenes. A concentration of 90 mg/L of verbenone was achieved by Penicillium sp. 2360 after 3 days of biotransformation.