• Title/Summary/Keyword: pulp fiber

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Analysis of Effects of Fiber's Collapse Index on Physical Properties of Paper Using CLSM (종이의 물리적 특성에 미치는 섬유의 찌그러짐 특성의 영향에 대한 CLSM 분석)

  • 김서환;박종문;김철환
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.1
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    • pp.46-51
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    • 1999
  • The most important effect of refining is believed as the internal fibrillation. The internal fibrillation is the separation of the fiber wall into several lamellae. The internal fibrillation results in fiber swelling as water penetrates the fiber wall. The increase in paper strength as a result of refining was due to delamination which made the fiber more flexible. Pulp fibers are refined to 20, 40, and 70$^{\circ}$SR freeness at Valley beater. Changes of Physical paper properties are analyzed depending on fiber wall thickness and fiber's collapse index at 2.5 and 5.6kg$_f$ refining load. At same $^[\circ}$SR freeness with 2.5kg$_f$ refining load, fiber wall thickness is increased further than at high 5.6kg$_f$ refining load. With higher fiber wall thickness by lower intensity refining load, higher internal fibrillation, flexibility, collapsability of fibers are achieved. Those effects improve WRV, tensile strength, and burst strength. Tear strength shows opposite trend to tensile and burst strength as usual.

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Change of Chemical Pulp Fiber Properties with Cellulase Component($C_1$, $C_{x}$) Treatment (CelIulase 구성 요소별 처리에 의한 펄프 섬유의 특성 변화)

  • Kim, Byung-Hyon;Jeon, Yang
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.2
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    • pp.13-23
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    • 1998
  • Two major cellulase components purified with sephadex G-75 and DEAE sepharose were applied to bleached kraft pulp to inverstigate the change of fiber properties. Cellulose viscosity was very sensitive to $C_x$ component treatment (more than 15% drop was observed) while being little influenced by $C_1$, component (only 2% drop). Fiber fraction longer than 2mm was reduced by $C_x$ treatment while short fiber fraction was increased greatly by more than 15%. There was little change in fiber length distribution by combined treatment of $C_1$ 1 and $C_x$ at equal. In this case, fine contents increased by more than 2.5% at equivalent refining time. WRV and Density were increased as the amount of $C_1$ or $C_x$ treatment was increased. $C_{x}$ was main cause for increasing them. But the effect fell as enzyme dosage.

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The Effects of Fiber Source on Organ Weight, Digesta pH, Specific Activities of Digestive Enzymes and Bacterial Activity in the Gastrointestinal Tract of Piglets

  • Ma, Yongxi;Li, Defa;Qiao, S.Y.;Huang, C.H.;Han, In K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.10
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    • pp.1482-1488
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    • 2002
  • The aim of this study was to explore the effects of fiber sources on gut development and bacterial activity in the gastrointestinal tract of piglets. Eighteen crossbred (Duroc${\times}$Landrace${\times}$Yorkshire) barrows were fed a basal diet based on corn plus soybean meal or similar diets in which a portion of the corn and soybean was replaced by 5% wheat bran or 5% sugar beet pulp. The results indicate that pigs fed diets containing 5% wheat bran or 5% sugar beet pulp had lower liver weights than control pigs (p<0.01). The relative weight of the pancreas in pigs fed diets containing 5% sugar beet pulp was greater than that of control pigs or pigs fed diets containing 5% wheat bran (p<0.05). The pH of the ileal digesta of pigs fed the diet containing 5% wheat bran was higher than that of control pigs or pigs fed the diet containing 5% sugar beet pulp (p<0.05). The lipase activity in the distal jejunum, proximal, and distal ileum of pigs fed the control diet was higher than that of pigs fed the diets containing 5% wheat bran or 5% sugar beet pulp (p<0.05). The concentration of volatile fatty acids anterior to the caecum was greater for the pigs fed the diet containing 5% sugar beet pulp, while the concentration of volatile fatty acids posterior to the ileum was greater for the pigs fed the diet containing 5% wheat bran. This means that sugar beet pulp increased the bacterial fermentation precaecum, while wheat bran increased the bacterial fermentation post-ileum. The concentration of bacterial nitrogen and bacterial protein/total protein in ileal digesta of pigs fed the control diet was higher (p<0.05) than that of pigs fed the diets contained either fiber source. Bacterial protein/total protein in the feces of pigs fed the diet containing 5% sugar beet pulp was higher than that of pigs fed the control diet. This means that inclusion of 5% wheat bran or sugar beet pulp in diets influenced the development of the digestive tract of piglet. The mechanism by which dietary fiber reduced specific activity of lipase needs further consideration. Dietary fiber influenced the bacterial activity in the digestive tract of piglets, sugar beet pulp increased the fermentation in the upper gastrointestinal tract, and while wheat bran increased the fermentation in the lower gastrointestinal tract.

Changes in Fiber Characteristics by Low Concentration Sodium Hydroxide Swelling and Beating (저농도 NaOH 팽윤과 고해에 따른 섬유특성 변화)

  • Kim, Ah-Ram;Choi, Kyoung-Hwa;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.3
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    • pp.65-72
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    • 2014
  • In this study, effects of alkali swelling at low concentration below 2 percent on properties of hardwood bleached kraft pulp (HwBKP) were elucidated. Swelling treatment of HwBKP was performed at various NaOH concentrations with/without beating. Then, the swelling characteristics of pulp fiber was evaluated by measuring the solvent retention values such as water retention value (WRV) and isopropyl alcohol retention value (LRV). It was found that fiber characteristics were influenced by NaOH swelling even at low alkali concentration and beating treatment as well. The values of WRV and LRV were decreased when the alkali concentration was increased. It is the result from the decreased acidic groups of pulp which were formed during beating. The acidic groups could be neutralized and then removed by alkali. The difference between WRV and LRV was decreased with increasing alkali concentration while the difference was increased when the alkali swollen pulp was beaten. In addition, the crystalline structure of HwBKP was almost not changed while the crystallinity was influenced by swelling treatment at a low alkali concentration.

REACTION OF PAPER PULP AND ALKYL KETENE DIMER BY AGING TREATMENT DURING PAPERMAKIN PROCESS

  • Shin, Young-Doo;Seo, Won-Sung;Cho, Nam-Seok
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.11a
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    • pp.83-83
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    • 2000
  • Alkylketene dimer was known as a cellulose reactive or alkaline size because it does not require to fix to the fiber as do the traditional rosin sizes. A proposed sizing mechanism of AKD was the formation of P -ketoester bond between AKD and cellulose which provides the permanent attachment and the orientation of the hydrophobic alkylchains outward. However, some questions about the reaction had arisen and thus, the sizing mechanism of AKD has been a subject of controversy for several decades. The major concern of the controversy is that AKD is really reactive with cellulose or not in the papermaking conditions. In this study, reaction between AKD and pulp fiber was investigated, in order to find out whether AKD forms P-ketoester with pulp fiber during aging under no catalyzed neutral condition with obvious spectroscopic evidence. In addition, effect of aging treatment on the sizing development was studied. It has been disclosed that, in absence of water, AKD reacted with cellulose to form P -ketoester linkage under no catalyzed neutral condition, while, in presence of water, most of AKD was hydrolyzed to a dialkyl ketone or P -ketoacid. In addition, during the aging treatment of AKD-sized paper, its typical IR spectra bands gradually were reduced, completely disappeared after 6hr aging, and formed new absorption bands at 1707cm-' and shoulder peak at 1700cm-' which refer to the typical dialkylketone absorption bands. Therefore, the formation of P -ketoester between AKD and pulp fiber is impossible in the practical papermaking process. It could be suggested that the sizing development of AKD-sized paper is obtained by next two mechanism: 1) formation of a thin-layer of AKD on the fiber surface through melting and spreading of AKD emulsion particles by heat and 2) the hydrolysis of AKD to dialkyl ketone which has higher melting point, during drying and storage of AKD sized papers.

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Recycling of Waste Paper with Alkaline Cellulolytic Enzyme (II) - Purification of alkaline cellulolytic enzymes and characteristics of reaction with fiber - (호알칼리성 목질분해 효소를 이용한 폐지 재생(제2보) - 알칼리성 목질분해 효소 정제 및 섬유 반응 특성 -)

  • 강석현;이중명;박성배;엄태진
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.1
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    • pp.24-29
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    • 2004
  • Alkaline cellulolytic enzymes from cultured medium of Coprinus cinereus 2249 were purified with gel and ion-exchange chromatography and characteristics of those enzyme proteins were investigated. A fiber length distribution and a crystallinity of cellulose and sugar composition of enzyme treated Mixed Office Wastepaper(MOW) and Unbleached Kraft Pulp(UKP) were analysed. The conclusion could summarized as follows; \circled1 Alkaline and acidic, endo- and exo-glucanases were purified from cultured medium of Coprinus cinereus 2249. \circled2 The approximate molecular weight of alkaline endo-glucanase was 42 kDa, and also that of alkaline exo-glucanase was 50 kDa. A fiber length distribution and a crystallization of cellulose and sugar composition of enzyme treated MOW and UKP were not so much changed with original paper and pulp.

EVALUATIN OF NALITA WOOD(Trema orientalis) AS SOURCE OF FIBER FOR PARERMAKING

  • Jahan, M. Sarwar;Mun, Sung-Phil
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2003.11a
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    • pp.17-26
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    • 2003
  • Nalita wood(Trema orientalis) is one of the fastest growing woods in the world. It may be a viable species for pulpwood. The physical, chemical and morphological properties of Nalita were studied. The total lignin, pentosan and holocellulose content in Nalita wood were 24.7%, 22% and 81.2%, respectively. Its fiber length was about 0.92 mm, which are comparable to Acacia mangium. Nitrobenzene oxidation of Nalita wood meal indicated that the guaciayl and syringyl unit were the major constituent of Nalita lignin. Nalita produced 50% pulp yield at Kappa number 21 in soda-anthraquinone process. The strength properties of Nalita pulp were comparable to other tropical hardwood pulp. At $40_{\circ}$ SR, the breaking length, burst index, tear index and total energy absorption were 6000 m, $3.5kPa{\cdot}m^2/g\;and\;7.0mN{\cdot}m^2/g\;and\;75J/m^2$, respectively.

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New Korean Traditional Papermaking from Paper Mulberry(III)-Properties of the Hanjis Mixed with Bast Part and Whole Stalk Pulps- (닥나무를 이용한 새로운 한지의 제조(제3보)-인피부 및 전간부 펄프 혼합초지 한지의 특성-)

  • 최태호;조남석
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.2
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    • pp.85-95
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    • 1998
  • Traditionally, Hanji had been made only with the bast fiber of paper mulberry (Broussonetia kazinoki). Nowadays, Hanji has been made mainly in the mixed forms of paper mulberry bast fiber and waste paper, and consequently it has raised many problems using them. This study was carried out to investigate the characteristics of Hanji mixed with paper mulberry bast part and whole stalk pulps. Hanjis made from the solfomethylated pulp were shown higher brightness and sheet strengths than those from alkali and alkali-hydrogen peroxide pulps. The brightness of solfomethylated pulp was found to be high enough not to need additional bleaching. The sheet formations were improved as the increase of whole stalk pulp contents, while the sheet strengths were decreased. In the physical properties of the Hanji mixed with bast part and whole stalk pulps, the handsheet strengths were decreased as the increase of the whole stalk pulp contents. The tensile strength and folding endurance of the Hanji containing 40∼60% of whole stalk pulps were higher as compared to the others.

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DEINKING OF COLORED OFFSET NEWSPRINT WITH ENZYME TREA TMENT IN COOPERATION WITH ULTRASONIC WAVE

  • Yimin XIE;U, Hong-W;Yanming LAI
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.149-152
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    • 1999
  • A new process for deinking of colored offset newsprint, i.e. enzyme treatment in cooperation with ultrasonic wave was developed in the present study. The physical characteristics such as fiber length, coarseness, crystallinity index of the deinked pulps were investigated and the sugar residues released from the treatment were analyzed. It was found that colored offset newsprint could be deinked effectively by cellulase treatment when ultrasonic wave was applied. The brightness increased by 5% ISO over that of control experiment and the pigment content was reduced markedly. Though the ultrasonic wave had little effect on the strength and crystallinity of the pulp, the treatment of enzyme combined with ultrasonic wave reduced the coarseness and fiber length to some extent. It was also found that ultrasonic wave could accelerate the hydrolysis of cellulose and hemicellulose during the cellulase treatment.

Effect of Combined Refining Plates with Different Bar Angles on Paper Properties during Mixed Pulp Refining

  • GUO, Xiya;DONG, Jixian;LIU, Huan;DUAN, Chuanwu;YANG, Ruifan;QI, Kai
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.5
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    • pp.581-590
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    • 2020
  • Pulp refining is the major way to alter the properties of fibers and formed paper. Different combinations of the bar profile of the rotor and stator during low consistency refining processes directly affect the properties of the paper. In this study, a mixture of softwood and hardwood pulp was refined by varying the bar angle of the stator while that of the rotor is fixed at 0º. The pulp samples were collected at different refining times. Then, the pulp and paper properties, such as beating degree, fiber external fibrillation, and tensile and tear indexes were measured to explore the effects of the combined refining plates at different bar angles on paper properties. The results of the experiment show that the combined refining plate of 0º and 5º recorded the most significant improvement in the pulp beating degree and fiber external fibrillation. This consequently increased the fiber bonding area, which in turn, improved both the tensile and the tear indexes of the paper. Also, the influence of the combined refining plates with a larger bar angle on the paper properties was weaker compared to that of smaller angles. This study not only provides ideas for the bar profile design but also improves the optimal selection of refining plates.