• Clean Technology
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• v.29 no.2
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• pp.87-94
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• 2023

The recovery of valuable metals from waste lithium-based secondary batteries is very important in terms of efficiently utilizing earth's limited number of resources. Currently, the cathode material of a LiFePO₄ battery, a type of battery which is widely used in automobiles, contains approximately 5% lithium. After use, the lithium in these batteries can be used again as a raw material for new batteries through lithium recycling. In this study, low-concentration sulfuric acid, a commonly used type of inorganic acid, was used to selectively leach the lithium contained in a waste LiFePO₄ cathode material powder. In addition, in order to compare and analyze the leaching efficiency and separation efficiency of each component, the optimalleaching conditions were derived by applying a two-step leaching process with pulp density being used as a variable during leaching. When leaching with pulp density as a variable, it was confirmed that at a pulp density of 200 g/L, the separation efficiency was approximately 200 times higher than at other pulp densities because the iron and phosphorus components were hardly leached at this pulp density. Accordingly, the pulp density of 200 g/L was used tooptimize the leaching conditions for the selective leaching and recovery of lithium.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.31 no.3
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• pp.10-18
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• 1999

The influence of simple electrolyte or anionic trashes on cationic starch adsorption was examined using deinked pulp and bleached thermomechniical pulp. Adsorbed amounts of cationic starches increased slightly , then decreased abruptly as the concentration of simple electrolyte increased. This phenomenon was discussed based on the compression of electrical double layer and conformation change of starch molecules. Also, the effect of the type of simple electrolytes on starch adsorption was examined and discussed. Addition of sodium slilicate increased starch adsorption since it increased surface charge density of fibers. On the other hand, addition of kraft lignin decreased cationic demand of the pulp slurries and adsorbed amounts of cationic starches. Nonionic surfactant did not show any significant effect on the cationic demand of pulp slurries. When simple electrolytes were added to the stock , grater adsorption or cationic starches was obtained with starches of lower degree of substitution . On t도 other hand, amount of adsorbed starches decreased for lower DS starches when the concentration of anionic trashes increased.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06a
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• pp.153-159
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• 2006

Red algae were used to make bleached pulp, from which paper handsheet samples were made. Red algae consists of rhizoidal filaments, epidermal tissues whose color were reddish, mucous carbohydrates, and other minor elements. Rhizoidal filaments of high brightness were obtained after extracting out mucous carbohydrates, and bleaching the remainder by using bleaching chemicals. The sizes and shapes of several rhizoidal filaments (or red algae pulp) from different red algae species were examined, and their handsheet properties were compared. Transparent and transluscent high density paper samples were made without applying refining process from the red algae pulp. White paper samples with good printability and excellent formation were made. We are developing pilot scale pulping and papermaking facilities at this time.

• Resources Recycling
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• v.23 no.1
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• pp.64-69
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• 2014

For the recovery of Co and Cu, bioleaching behavior of Co, Cu, Fe, Mg, Al by Aspergillus niger culture from the molasses growth medium was investigated. Series of leaching tests have been conducted by varying Aspergillus niger's type, molasses concentration in the growth medium, pulp density and reaction time. The results showed that increase of the molasses concentration in the growth medium from 1% to 4% increased the leaching percentage of Co and Cu and the optimal molesses concentration was found to be 4% in the growth medium. Maxinum 90% of Co and 70% of Cu were dissolved from the leaching test at the 10 g/L pulp density, 4 % of molasses concentration in the growth medium after 21 days by Aspergillus niger KCTC 6985. But in case of using Aspergillus niger KCTC 6144, the maxium leaching percentage of Co and Cu was reached 90% respectively at a pulp density 5 g/L and 4% of molasses concentration.

• Journal of Microbiology and Biotechnology
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• v.26 no.11
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• pp.1871-1880
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• 2016

Bio-oxidation is an effective technology for treatment of refractory gold concentrates. However, the unsatisfactory oxidation rate and long residence time, which cause a lower cyanide leaching rate and gold recovery, are key factors that restrict the application of traditional bio-oxidation technology. In this study, the oxidation rate of refractory gold concentrates and the adaption of microorganisms were analyzed to evaluate a newly developed two-step pretreatment process, which includes a high temperature chemical oxidation step and a subsequent bio-oxidation step. The oxidation rate and recovery rate of gold were improved significantly after the two-step process. The results showed that the highest oxidation rate of sulfide sulfur could reach to 99.01 % with an extreme thermophile microbial community when the pulp density was 5%. Accordingly, the recovery rate of gold was elevated to 92.51%. Meanwhile, the results revealed that moderate thermophiles performed better than acidophilic mesophiles and extreme thermophiles, whose oxidation rates declined drastically when the pulp density was increased to 10% and 15%. The oxidation rates of sulfide sulfur with moderate thermophiles were 93.94% and 65.73% when the pulp density was increased to 10% and 15%, respectively. All these results indicated that the two-step pretreatment increased the oxidation rate of refractory gold concentrates and is a potential technology to pretreat the refractory sample. Meanwhile, owing to the sensitivity of the microbial community under different pulp density levels, the optimization of microbial community in bio-oxidation is necessary in industry.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.30 no.4
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• pp.69-78
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• 1998

Papers loaded with 10-40% $TiO_2$ by dry weight were calendered under the various combinations of calendering conditions such as calender type, linear pressure, and roll temperature. After being calendered, light scattering coefficient, surface roughness, density, and tensile strength of the papers were measured and the results were summerized as follows: 1. To increase the light scattering coefficient of $TiO_2$-highly-loaded paper further by calendering, the calender roll pressure and temperature should be kept low. Under these conditions, the physical strength of the paper was not significantly affected. 2. At low roll temperature, soft nip calender and machine calender type showed the same relationship between paper density and its roughness. At high roll temperature, soft nip calender type gave much lower roughness than machine calender type at the same density. 3. At high roll temperature of both calenders, the density as well as the tensile strength of the TiO$_2$-loaded paper was increased significantly.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.32 no.1
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• pp.26-32
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• 2000

The impact of major surface chemical properties of silica sols on the retention and drainage performance of the silica based micrparticle system, Compozil was investigated using four different silica sols. And the effect of silica properties on the interactions with cationic starch and cationic plyacrylamide has also been identified. The surface charge density and the stability over pH of silica sols were increased by introducing aluminosilicate anions at surface. It was found that the charge density of silica sols determined the addition level necessary to attain the maximum retention and drainage. When silica sols were combined with cationic starch, the change density of the product was the critical properties and the degree of microagregation was of minor importance. In the cationic polyacrylamide system the degree of colloid structure appeared to be a more critcial property than the charge density of silica sols.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.38 no.5 s.118
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• pp.66-73
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• 2006

The effects of active packaging on the surface stiffness, mass, volume, density and weight changes of fresh as well as stored eggplant were studied at 11 and $25^{\circ}C$ for 10 days with active packaging material Type 1 and 2 and control. Mass, volume, and surface stiffness of eggplant decreased linearly throughout the storage period regardless of storage conditions; while the mass density showed a reverse trend in the ease of $11^{\circ}C$ storage. Reduction rate of mass, mass density and weight was observed minimum at $25^{\circ}C$ storage temperature with active packaging Type 1. The weight of eggplant decreased at a higher rate in the initial 4 days compared to that in the later period of storage regardless of storage temperature and type of packaging.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.1
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• pp.38-44
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• 2001

The effects of refining load on the paper properties were investigated. HwBKP, SwBKP and SwUKP were refined with PFI mill at the load of 3.33 N/mm and 6.00 N/mm. Higher Scott bond was obtained at the higher refining load for three pulp used in this study. However any changes in the light scattering coefficient with the change of refining load were not observed. Although the effect of refining load on the formation index for SwUKP was not observed, higher refining load gave the better formation for HwBKP and SwBKP. The fiber mass and fiber crowding factor were not affected by the refining load. Higher apparent density and tensile index were obtained with the higher refining load. However, the higher refining load did not improve the tensile index at the same apparent density. The tear index was decreased with the increase of refining load.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.35 no.3
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• pp.79-84
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• 2003

Oriental painting paper (Hwaseonji) was prepared from various kinds of plant fibers and its physical properties were investigated. The fibers used were classified into three different length of fibers; long fiber (<1.8 mm), medium fiber (1.4-1.8 mm) and short fiber (>1.4 mm). The fibers were mixed in the ratio of 15% long fiber, 25% medium fiber and 60% short fiber. The Hwaseonji prepared from mixing of the bamboo or rice straw pulp as a short fiber with the long and medium fibers showed excellent physical properties with a high smoothness and uniformity of Chinese ink blot. Mixing with LBKP as a short fiber was resulted in low physical properties, smoothness and wide ink blot. The properties of Hwaseonji, such as ink absorption, roughness and smoothness, may be predicted from the correlation of density with Chinese ink blot and smoothness.