• Title/Summary/Keyword: pseudo order

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The Fabrication and Magnetoresistance of Nanometer-sized Spin Device Driven by Current Perpendicular to the Plane (수직전류 인가형 나노 스핀소자의 제조 및 자기저항 특성)

  • Chun, M.G.;Lee, H.J.;Jeung, W.Y.;Kim, K.Y.;Kim, C.G.
    • Journal of the Korean Magnetics Society
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    • v.15 no.2
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    • pp.61-66
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    • 2005
  • In order to make submicron cell for spin-injection device, lift-off method using Pt stencil and wet etching was chosen. This approach allows batch fabrication of stencil substrate with electron-beam lithography. It simplifies the process between magnetic film stack deposition and final device testing, thus enabling rapid turnaround in sample fabrication. Submicron junctions with size of $200nm{\times}300nm$ and $500nm{\times}500nm$ 500 nm and pseudo spin valve structure of $CoFe(30{\AA})/Cu(100{\AA})/CoFe(120{\AA}$) was deposited into the nanojunctions. MR ratio was 0.8 and $1.1{\%}$, respectively and spin transfer effect was confirmed with critical current of $7.65{\times}10^7A/cm^2$.

Reduction of Nitrate-nigrogen by Zero-valent Iron Adhered in Mesoporous Silicas (메조기공 실리카에 부착된 영가철을 이용한 질산성 질소의 환원)

  • Yeon, Kyeong-Ho;Lee, Seunghak;Lee, Kwanyong;Park, Yong-Min;Kang, Sang-Yoon;Lee, Jae-Won;Choi, Yong-Su;Lee, Sang-Hyup
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.1
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    • pp.139-147
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    • 2007
  • For environmental remediation of a contaminated groundwater plume, the use of zero-valent metal represents one of the latest innovative technologies. In this study, the effects of denitrification by zero-valent iron adsorbed in mesoporous silicas have been studied for groundwater contaminant degradation. The mesoporous silica was functionalized with 3-mercaptopropyltrimethoxysilane (MPTS) ligands and the zero-valent iron precipitated in the mesopore of granular silica was made by $FeCl_2$ and $NaBH_4$. Hydrogen was exchanged with $Fe^{2+}$ ions in the granular silicas. And then the ions were reduced by sodium borohydride in the mesoporous silicas. The surface area of the silica determined via the BET method ranged from 858 to $1275m^2/g$. The reductive reaction of nitrate-nitrogen indicated that the degradation of nitrate-nitrogen appeared to be pseudo first-order with the observed reaction rate constant kobs ($0.1619h^{-1}$) and to be directly proportional to the specific surface area. Therefore, the mesoporous silica with nano zero-valent iron proposed as a novel treatment strategy for contaminated groundwater was successfully implemented herein for the removal of nitrate-nitrogen.

Thermoelectric characteristics depend on compositions of $Bi_2Te_3$ in mixed alloy with PbTe

  • Jung, Kyoo-Ho;Yim, Ju-Hyuk;Kim, Jin-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03a
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    • pp.11-11
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    • 2010
  • In order to design for nano structured materials with enhanced thermoelectric properties, the alloys in the pseudo-binary $Bi_2Te_3$-PbTe system were investigated for their micro structure and thermal properties. For this synthesis the liquid alloys were cooled by water quenching method. The micro structure images were taken by using electron probe micro analyzer (EPMA). Dendritic and lamellar structures were clearly observed with the variation in the composition ratio between $Bi_2Te_3$ and PbTe. It was confirmed that a metastable compounds is $PbBi_2Te_4$ in the The $Bi_2Te_3$-PbTe system. The change in the composition increasing $Bi_2Te_3$ ratio causes to change structure from dendritic to lamellar. Seebeck coefficient of alloys 5 which the mixture rate of $Bi_2Te_3$ is 83% was measured as the highest value. In contrast, the others decreased by increasing $Bi_2Te_3$. n-type characteristics was observed at all condition except alloy 6 which $Bi_2Te_3$ ration is 91%. The power factors of all samples were calculated with Seebeck coefficient and resistivity. Also the thermal conductivity was measured by using laser flash analyzer (LFA). In this work, the microstructures and thermal properties have been measured as a function of ratio of $Bi_2Te_3$ in the $Bi_2Te_3$-PbTe system.

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Adsorption Properties of Cadmium onto Granite Soil and Calcium Sand (화강풍화토 및 칼슘샌드에 의한 카드뮴 흡착특성 연구)

  • Lee, Myoung-Eun;Kwon, Min-Seok;Ahn, Yong-Tae;Chung, Jae-Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.2
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    • pp.27-34
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    • 2014
  • Kinetic and isotherm properties of the cadmium adsorption onto calcium sand and granite soil were evaluated by batch experiments. The pHs of calcium sand and granite soil were 9.51 and 6.33, respectively, showing that the precipitation of heavy metals can be occurred due to the increase of pH when the calcium sand is used as an adsorbent. The pseudo-second-order model described the adsorption kinetics satisfactory with correlation coefficients over 0.999. The equilibrium adsorption capacities of calcium sand and granite soil were 2.10 and 2.16 mg/g, respectively. The adsorption isotherm followed the Freundlich isotherm model, indicating the cadmium adsorbed onto the heterogeneous surfaces of adsorbents.

Development & Verification of On-Board Flight Software on Software-based Spacecraft Simulator (소프트웨어 기반의 위성 시뮬레이터를 이용한 위성 탑재소프트웨어 개발 및 검증 방안)

  • Choi, Jong-Wook;Shin, Hyun-Kyu;Lee, Jae-Seung;Cheon, Yee-Jin
    • Journal of Satellite, Information and Communications
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    • v.5 no.2
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    • pp.1-7
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    • 2010
  • For many years the development and verification of on-board flight software have been essentially performed on STB (Software Test Bed) environments which consist of real hardware in KARI. During development of on-board flight software on STB, we experienced many difficulties such as the late delivery of target hardware and limitation to access STB simultaneously by multiple developers. And it takes too much time and cost to build up multiple STBs. In order to successfully resolve this kind of problems, the software-based spacecraft simulator has been developed. The simulator emulates the on-board computer, I/O modules and power controller units and it supports the debugging and test facilities to software engineers for developing flight software. Also the flight software can be loaded without any modification and can be executed as pseudo real-time. This paper presents the architecture and design of software-based spacecraft simulator, and flight software development and verification under this environment.

Adsorption of Cu(II) from Aqueous Solutions Using Pine (Pinus densiflora) Wood (소나무(Pinus densiflora) 목질을 이용한 수용액 중의 Cu(II) 흡착)

  • Kim, Ha-Na;Park, Se-Keun;Yang, Kyung-Min;Kim, Yeong-Kwan
    • Journal of Industrial Technology
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    • v.27 no.A
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    • pp.195-202
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    • 2007
  • Milled Korean pine (Pinus densiflora) wood was used to evaluate its adsorption capacity of Cu(II) ions from aqueous solution by running a series of batch experiments. Prior to the tests, the milled woods were pretreated with 1N NaOH, 1N $HNO_3$, and distilled water, respectively, to examine the effect of pretreatment. Within the tested pH range between 3 and 6, copper adsorption efficiency of NaOH-treated wood(96~99%) was superior to the $HNO_3$-treated wood(19~31%) and distilled water-treated wood(18~35%). The efficiency of copper removal by wood enhanced with increasing solution pH and reached a maximum copper ion uptake at pH 5~6. Adsorption behavior of copper onto both raw and $HNO_3$-treated woods was mainly attributed to interaction with carboxylic acid group. For NaOH-treated wood, carboxylate ion produced by hydrolysis or saponification was a major functional group responsible for Cu sorption. NaOH treatment of wood changed the ester and carboxylic acid groups into carboxylate group, whereas $HNO_3$ treatment did not affect the production of functional groups which could bind copper. A pseudo second-order kinetic model fitted well for the sorption of copper ion onto NaOH-treated wood. A batch isotherm test using NaOH-treated wood showed that equilibrium sorption data were better represented by the Langmuir model than the Freundlich model.

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The Sorption Kinetic Studies and Development of Mixed Culture for Removal of Nonpoint Pollution Source (비점오염원 처리를 위한 혼합여재의 개발 및 흡착 Kinetic 연구)

  • Chung, Woojin;Lee, Sijin
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.4
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    • pp.37-44
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    • 2012
  • This study investigated on the adsorption of nonpoint pollution source using the Sand, hydroxyapatite(HAP), Zeolite and mixed culture. The adsorption of nonpoint pollution source on Sand, hydroxyapatite(HAP), Zeolite and mixed culture was investigated during a series of batch adsorption experiments. After the batch absorption experiments analysed COD, T-N, T-P on adsorption water. The experimental data was analysed using the pseudo-first-order adsorption kinetic models. Langmuir and Freundlich isotherm models were tested for their applicability. The maximum adsorbed amount $(Q_{max})$ of COD were found to be sand 0.0511mg/g, HAP 0.1905mg/g, Zeolite 1.0366mg/g and Mixed media 0.7444mg/g. The maximum adsorbed amount $(Q_{max})$ of T-N were found to be sand 0.0159mg/g, HAP 0.0537mg/g, Zeolite 0.5496mg/g and Mixed media 0.1374mg/g. The maximum adsorbed amount $(Q_{max})$ of T-P were found to be sand 0.0202mg/g, HAP 0.1342mg/g, Zeolite 0.0462mg/g and Mixed media 0.1180mg/g. As a result, the mixed media was effective to remove nonpoint pollution source.

Wet Etching of Stainless Steel Foil by Aqueous Ferric Chloride Solution (염화제이철 수용액에 의한 스테인레스 강판의 식각에 관한 연구)

  • Lee, Hyung Min;Park, Mooryong;Park, Gwang Ho;Park, Chinho
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.211-216
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    • 2012
  • Wet chemical etching of stainless steel foil by aqueous ferric chloride solution was investigated in this study. Effects of various process parameters (e.g. etchant agitation rate, etchant temperature, $Fe^{3+}$ ion concentration, free HCl concentration, specific gravity, etc.) on the etch rate was first studied, and it was found that the etch rate of AK (aluminum-killed) steel, chromium metal and stainless steel (STS430J1L alloy) follows the pseudo-first order reaction equation. When the fatigue ratio of etchant was kept under 16%, sludge was not formed in the solution, and the etched surface showed smooth roughness. The etch rate decreases as Baume of etchant increases, but the effect of free HCl concentration on the etch rate turned out to be minimal. Experimental data were compared with the calculated results from modeled equation, showing very good agreement.

Performance evaluation of diversity reception of underwater acoustic code division multiple access using lake experiment (저수지 실험을 통한 수중 음향 코드 분할 다중 접속 방식의 다이버시티 수신 성능 검증)

  • Seo, Bo-Min;Cho, Ho-Shin
    • The Journal of the Acoustical Society of Korea
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    • v.36 no.1
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    • pp.39-48
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    • 2017
  • CDMA (Code Division Multiple Access) is promising medium access control schemes for underwater acoustic sensor networks because of its robustness against frequency-selective fading and high frequency-reuse efficiency. In this paper, we design diversity schemes of underwater CDMA transceiver for the forward and reverse links. User data are multiplexed by Walsh code and a pseudo random noise code acquisition process is added for phase error correction before decoding the user data at the receiver. Then, the diversity reception using equal gain combining and maximal ratio combining is performed in order to minimize performance degradation caused by rich multipath fading of underwater acoustic channel. We evaluated the performance of diversity transceiver through lake experiment, which was performed at Lake Kyungcheon, Mungyeong city using two transmitters and two receivers placed 460 m apart at an average depth of 40 m. The lake experiment results show that user data are recovered with error-free in both of the forward and reverse links.

Community Type and Stand Structure of the Korean Pine(Pinus koraiensis) Natural Forest in Seoraksan National Park (설악산 국립공원 잣나무 천연림의 군락유형 및 임분구조)

  • Song, Youn-Hee;Yun, Chung-Weon
    • Korean Journal of Environment and Ecology
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    • v.20 no.1
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    • pp.29-40
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    • 2006
  • This study was conducted to obtain the fundamental data for the ecological management in the Pinus koraiensis natural forest in Seoraksan National Park. The community types of the P. koraiensis forest were divided into Ainsliaea acerifolia group and Rhododendron schlippenbachii group. A. acerifolia group was subdivided into Acer tschonoskii var. rubripes subgroup and Calamagrostis arundinacea subgroup. The importance value of major species showed higher value in the order like Pinus koraienses, Abies nephrolepis, Acer barbinerve, Betula ermani, Acer pseudo-sieboldianum, Sorbus commixta and Quercus mongolica. The value of species diversify ranged from 0.44 to 0.86, and showed stronger competition in the interspecific association than in the intraspecific one. The number of individuals of P. koraiensis below 10 centimeters in the 15 study sites was 35, and it was considered that the population of P. koraiensis could be succeeded to the other species in the present situation because of lower frequency in the low layer though the canopy of tree layer was dominated with P. koraiensis. The radial growth patterns of P. koraiensis individuals were mainly fluctuated for the entire life time, which was considered to be caused by frequent disturbance.