• Title/Summary/Keyword: pseudo order

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Effects of Acid Modification on Pb(II) and Cu(II) Adsorption of Bamboo-based Activated Carbon (대나무 활성탄의 산 개질이 납과 구리 이온의 흡착에 미치는 영향)

  • Lee, Myoung-Eun;Chung, Jae-Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.1
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    • pp.3-10
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    • 2016
  • Effects of acid ($HNO_3$ and HCl) modification on the adsorption properties of Pb(II) and Cu(II) onto bamboo-based activated carbon (BAC) were investigated through a series of batch experiments. The carbon content increased and oxygen content decreased with acid treatment. $HNO_3$ induced carboxylic acids and hydroxyl functional groups while HCl added no functional group onto BAC. The pseudo-second order model better described the kinetics of Pb(II) and Cu(II) adsorption onto experimented adsorbents, indicating that the rate-limiting step of the heavy metal sorption is chemical sorption involving valency forces through sharing or exchange of electrons between the adsorbate and the adsorbent. The equilibrium sorption data followed both Langmuir and Freundlich isotherm models. The adsorption capacities of BAC were affected by the surface functional groups added by acid modification. The adsorption capacities were enhanced up to 36.0% and 27.3% for Pb(II) and Cu(II), respectively by the $HNO_3$ modification, however, negligibly affected by HCl.

The Electrical Characteristics of SRAM Cell with Stacked Single Crystal Silicon TFT Cell (단결정 실리콘 TFT Cell의 적용에 따른 SRAM 셀의 전기적 특성)

  • Lee, Deok-Jin;Kang, Ey-Goo
    • Journal of the Korea Computer Industry Society
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    • v.6 no.5
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    • pp.757-766
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    • 2005
  • There have been great demands for higher density SRAM in all area of SRAM applications, such as mobile, network, cache, and embedded applications. Therefore, aggressive shrinkage of 6T Full CMOS SRAM had been continued as the technology advances, However, conventional 6T Full CMOS SRAM has a basic limitation in the cell size because it needs 6 transistors on a silicon substrate compared to 1 transistor in a DRAM cell. The typical cell area of 6T Full CMOS SRAM is $70{\sim}90F^{2}$, which is too large compared to $8{\sim}9F^{2}$ of DRAM cell. With 80nm design rule using 193nm ArF lithography, the maximum density is 72M bits at the most. Therefore, pseudo SRAM or 1T SRAM, whose memory cell is the same as DRAM cell, is being adopted for the solution of the high density SRAM applications more than 64M bits. However, the refresh time limits not only the maximum operation temperature but also nearly all critical electrical characteristics of the products such as stand_by current and random access time. In order to overcome both the size penalty of the conventional 6T Full CMOS SRAM cell and the poor characteristics of the TFT load cell, we have developed $S^{3}$ cell. The Load pMOS and the Pass nMOS on ILD have nearly single crystal silicon channel according to the TEM and electron diffraction pattern analysis. In this study, we present $S^{3}$ SRAM cell technology with 100nm design rule in further detail, including the process integration and the basic characteristics of stacked single crystal silicon TFT.

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Control Gain Optimization for Mobile Robots Using Neural Networks and Genetic Algorithms (신경회로망과 유전알고리즘에 기초한 이동로봇의 제어 이득 최적화)

  • Choi, Young-kiu;Park, Jin-hyun
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.20 no.4
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    • pp.698-706
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    • 2016
  • In order to move mobile robots to desired locations in a minimum time, optimal control problems have to be solved; however, their analytic solutions are almost impossible to obtain due to robot nonlinear equations. This paper presents a method to get optimal control gains of mobile robots using genetic algorithms. Since the optimal control gains of mobile robots depend on the initial conditions, the initial condition range is discretized to form some grid points, and genetic algorithms are applied to provide the optimal control gains for the corresponding grid points. The optimal control gains for general initial conditions may be obtained by use of neural networks. So the optimal control gains and the corresponding grid points are used to train neural networks. The trained neural networks can supply pseudo-optimal control gains. Finally simulation studies have been conducted to verify the effectiveness of the method presented in this paper.

Mass transfer kinetics using two-site interface model for removal of Cr(VI) from aqueous solution with cassava peel and rubber tree bark as adsorbents

  • Vasudevan, M.;Ajithkumar, P.S.;Singh, R.P.;Natarajan, N.
    • Environmental Engineering Research
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    • v.21 no.2
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    • pp.152-163
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    • 2016
  • Present study investigates the potential of cassava peel and rubber tree bark for the removal of Cr (VI) from aqueous solution. Removal efficiency of more than 99% was obtained during the kinetic adsorption experiments with dosage of 3.5 g/L for cassava peel and 8 g/L for rubber tree bark. By comparing popular isotherm models and kinetic models for evaluating the kinetics of mass transfer, it was observed that Redlich-Peterson model and Langmuir model fitted well ($R^2$ > 0.99) resulting in maximum adsorption capacity as 79.37 mg/g and 43.86 mg/g for cassava peel and rubber tree bark respectively. Validation of pseudo-second order model and Elovich model indicated the possibility of chemisorption being the rate limiting step. The multi-linearity in the diffusion model was further addressed using multi-sites models (two-site series interface (TSSI) and two-site parallel interface (TSPI) models). Considering the influence of interface properties on the kinetic nature of sorption, TSSI model resulted in low mass transfer rate (5% for cassava peel and 10% for rubber tree bark) compared to TSPI model. The study highlights the employability of two-site sorption model for simultaneous representation of different stages of kinetic sorption for finding the rate-limiting process, compared to the separate equilibrium and kinetic modeling attempts.

Adsorption Behavior and Kinetic Characteristic of Cibacron Brilliant Red 3B-A by Granular Activated Carbon (입상활성탄에 의한 Cibacron Brilliant Red 3B-A의 흡착거동 및 동력학적 특성)

  • Lee, Jong Jib
    • Korean Chemical Engineering Research
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    • v.52 no.4
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    • pp.486-491
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    • 2014
  • In this paper, the adsorption behavior and kinetic characteristics of cibacron brilliant red 3B-A from aqueous solution using granular activated carbon were investigated. The effect of various parameters such as adsorbent dose, pH, initial concentration, contact time and temperature on the adsorption system were studied. Base on the estimated Langmuir constant ($R_L$) and Freundlich constant (1/n), This process could be employed as effective treatment method. From the Temkin constant (B) and Dubinin-Radushkevich constant (E), This adsorption process is physical adsorption. From kinetic experiments, the adsorption process followed the pseudo second order model with good correlation. Base on the Gibbs free energy and enthalpy, the adsorption of cibacron brilliant red 3B-A onto granular activated carbon was physisorption and endothermic in nature.

Experimental and Modeling Studies for the Adsorption of Phenol from Water Using Natural and Modified Algerian Clay

  • Djemai, Ismahane;Messaid, Belkacem
    • Korean Chemical Engineering Research
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    • v.58 no.4
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    • pp.624-634
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    • 2020
  • The ability of natural and modified clay to adsorb phenol was studied. The clay samples were analyzed by different technical instruments, such as X-ray fluorescence (XRF), X-ray diffraction (XRD) and FT-IR spectroscopy. Surface area, pore volume and average pore diameter were also determined using B.E.T method. Up to 73 and 99% of phenol was successfully adsorbed by natural and activated clay, respectively, from the aqueous solution. The experiments carried out show that the time required to reach the equilibrium of phenol adsorption on all the samples is very close to 60 min. The amount of phenol adsorbed shows a declining trend with higher pH as well as with lower pH, with most extreme elimination of phenol at pH 4. The adsorption of phenol increases proportionally with the initial phenol concentration. The maximum adsorption capacity at 25 ℃ and pH 4 was 29.661 mg/g for modified clay (NaMt). However, the effect of temperature on phenol adsorption was not significant. The simple modification causes the formation of smaller pores in the solid particles, resulting in a higher surface area of NaMt. The equilibrium results in aqueous systems were well fitted by the Freundlich isotherm equation (R2 > 0.98). Kinetic studies showed that the adsorption process is best described by the pseudo-second-order kinetics (R2 > 0.99). The adsorption of phenol on natural and modified clay was spontaneous and exothermal.

Electrical Characteristics of SRAM Cell with Stacked Single Crystal Silicon TFT Cell (Stacked Single Crystal Silicon TFT Cell의 적용에 의한 SRAM 셀의 전기적인 특성에 관한 연구)

  • Kang, Ey-Goo;Kim, Jin-Ho;Yu, Jang-Woo;Kim, Chang-Hun;Sung, Man-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.4
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    • pp.314-321
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    • 2006
  • There have been great demands for higher density SRAM in all area of SRAM applications, such as mobile, network, cache, and embedded applications. Therefore, aggressive shrinkage of 6 T Full CMOS SRAM had been continued as the technology advances. However, conventional 6 T Full CMOS SRAM has a basic limitation in the cell size because it needs 6 transistors on a silicon substrate compared to 1 transistor in a DRAM cell. The typical cell area of 6 T Full CMOS SRAM is $70{\sim}90\;F^2$, which is too large compared to $8{\sim}9\;F^2$ of DRAM cell. With 80 nm design rule using 193 nm ArF lithography, the maximum density is 72 Mbits at the most. Therefore, pseudo SRAM or 1 T SRAM, whose memory cell is the same as DRAM cell, is being adopted for the solution of the high density SRAM applications more than 64 M bits. However, the refresh time limits not only the maximum operation temperature but also nearly all critical electrical characteristics of the products such as stand_by current and random access time. In order to overcome both the size penalty of the conventional 6 T Full CMOS SRAM cell and the poor characteristics of the TFT load cell, we have developed S3 cell. The Load pMOS and the Pass nMOS on ILD have nearly single crystal silicon channel according to the TEM and electron diffraction pattern analysis. In this study, we present $S^3$ SRAM cell technology with 100 nm design rule in further detail, including the process integration and the basic characteristics of stacked single crystal silicon TFT.

SIA-LVC : Scalable Interworking Architecture for Military L-V-C Training Systems Based on Data Centric Middleware (SIA-LVC: 데이터 중심 미들웨어 기반 확장성 있는 국방 L-V-C 훈련체계 연동 아키텍쳐)

  • Kim, Won-Tae;Park, Seung-Min
    • KIPS Transactions on Computer and Communication Systems
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    • v.5 no.11
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    • pp.393-402
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    • 2016
  • A Military L-V-C system consists of distributed complex systems integrating Live systems working on physical wall-clock time, Virtual systems ruled by virtually pseudo realtime events on a computer, and Constructive systems only depending on the causal relationship between the continuous events. Recently many needs for L-V-C training systems are increasing in order to achieve the maximum training effects with low costs. While theoretical/logical researches or only partially interworking technologies have been proposed, there are few perfect interworking architectures for totally interoperating L-V-C systems in world-wide. In this paper, we design and develop a novel interworking architecture based on data centric middleware for the consistent global time with the same states on the entire L-V-C data and events by means of integrating the heterogeneous distributed middleware standards of each L-V-C system. In addition, simulated L-V-C systems based on real systems will be used for the efficiency and performance of the developed interworking architecture.

Analysis of the anti-microbial susceptibility of Clostridium isolated on clinical specimens from captive wild animals in Seoul Zoo (서울동물원 야생동물의 임상 검체 내 Clostridium 균의 항생제 내성 분석)

  • Lee, Hany;Yeo, Yong-Gu;Ahn, Sangjin;Kim, Jong-Taek
    • Korean Journal of Veterinary Service
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    • v.43 no.1
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    • pp.31-37
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    • 2020
  • Clostridial bacteria are zoonotic agents, which cause severe necrotizing enteritis, pseudo-membrane colitis, enterotoxemia to both humans and animals. The objective of this study was to monitor the antibiotic resistance of Clostridium isolates on clinical specimens from wild animals in Seoul zoo for 5 years. Clostridium isolates were verified by using Vitek2 compact machine. Antibiotic susceptibility was assessed by antibiotic disc diffusion test, which was followed by Kirby-Bauer disc diffusion test method. The frequency of Antimicrobial resistance of Clostridium isolate was the greatest in gentamicin (87%), then in order of amikacin (80%). There were 55.6% of Clostridium isolates showed multiple drug resistance (MDR). These results showed that a lot of Clostridial bacteria from wild animals in Seoul zoo were acquired antibiotic resistance. Because of the wild animal's aggressive manner, it has been hard to collect clinical samples from wild animals in a zoo to exam antibiotic susceptibility. For these reasons, empirical use of antibiotics has been performed in frequently. It may cause to increase the emergence of antibiotic resistance bacteria. In addition, the antibiotic resistance bacteria from zoo animals can be spread to other wild animals which inhabit around the zoo. Therefore, regular monitoring of antibiotic resistance Clostridial bacteria is important to protect animals and humans from Clostridial diseases.

A code acquisition method using signed-rank statistics in frequency-selective channels (주파수선택적 감쇄 채널에서 부호순위 통계량을 쓴 부호 획득 방법)

  • Kim, Hong-Gil;Jeong, Chang-Yong;Song, Ik-Ho;Gwon, Hyeong-Mun;Kim, Yong-Seok
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.39 no.2
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    • pp.69-80
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    • 2002
  • In this paper, signed-rank based nonparametric detectors are used for direct sequence code division multiple access pseudo-noise code acquisition systems in frequency-selective Rician fading channels. We first derive the locally optimum rank detector, and then propose the locally suboptimum rank (LSR) and k-th order modified signed-rank (MSRk) detectors using approximate score functions. We compare the serial and hybrid parallel double-dwell schemes using the LSR and MSRk detectors with those using the conventional squared-sum (SS) using the cell averaging constant false alarm rate processor and modified sign detectors. From the simulation results, it is shown that the LSR and MSRk detectors perform better than the SS detector using the cell averaging constant false alarm rate processor.