• 제목/요약/키워드: property change

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분해성 계면활성제에 관한 연구(제2보);1, 3-Dioxlane고리를 갖는 분해성계면활성제의 합성 (Studies on the Destructible Surfactants(2);Surface-Active Properties of Cleavable Surfactant with 1, 3-Dioxolane Ring)

  • 김진현;하재웅;정노희;남기대
    • 한국응용과학기술학회지
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    • 제12권1호
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    • pp.101-107
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    • 1995
  • 케탈이나 아세탈반응에 의하여 이루어진 1, 3-디옥솔란 고리가 산수용액 중에서 불안정해 쉽게 가수분해되는 성질을 이용하여 소수부로는 지방산의 탄화수소사슬을 친수부로는 소디움 카르복시산(Soap)을 도입하여 분해 후 계면활성을 띠지 않는 분해성 계면활성제이다. 이 화합물의 수용액에 대한 표면장력은 31dyne/cm였고, 임계미셀농도는 $1.0{\times}10^{-3}mol/L$이었다. 기포력은 비교적 좋지 않았으며, 유화력은 콩기름보다 벤젠에서 양호하였다. 또한 이 화합물의 산분해 특성을 1wt% 수용액과 벤젠 사이의 계면장력 변화에 의하여 측정한 결과 pH 1 ${\sim}$ 4범위에서 약 300분 안에 모두 가수분해됨을 확인하였다.

정부 부동산규제 강화와 기준금리 인상이 대형건설사 신용등급에 미치는 영향과 개선방향에 관한 연구 (A Study on the Effect and Improvement Direction of the Credit Rating of Large Construction Firms by the Reinforced Real Estate Regulations and the Raising of the Base Rate)

  • 이윤홍
    • 한국건설관리학회논문집
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    • 제19권1호
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    • pp.90-102
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    • 2018
  • 2000년 정부는 가계부채 증가와 미국 기준금리 인상을 대비하여 2017년부터 부동산규제를 강화하였고, 이로 인해 대형건설사 민간개발사업 수주확대는 위축될 것으로 예상된다. 해외플랜트 사업에서도 계속된 원가상승으로 부실이 이어지고 있어 대형건설사의 신용등급은 현 상태를 유지하기는 어려울 것으로 예상된다. 본 연구는 정부의 부동산정책과 국내외 적인 경제상황으로 앞으로 변화할 수 있는 문제점을 짚어보았다. 정부정책과 대내외적인 경제 환경 요소는 부동산정책, 기준금리, 부동산가격 상승률, 미분양을 연구하였고, 대형건설사 재무제표에서는 매출액, 시공능력, 민간개발사업 매출액, 영업이익, PF우발채무를 종합하여 외부 신용등급의 변화를 나타냈다. 본 연구는 실무 전문가 30명의 설문조사를 통해 위험요소가 대형건설사의 외부 신용등급에 미치는 영향을 분석하였다.

고랭지 영농방법이 비점원오염 물질의 유출과 토양의 물리적 변화에 미치는 영향 (The Impacts of Runoff the Nonpoint Source Pollution and Soil Physical Change for Mountainous Management Practice)

  • 최중대;강태영;김도찬
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 1998년도 학술발표회 발표논문집
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    • pp.521-526
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    • 1998
  • This study was initiated to build runoff plots, install soil and water quality monitoring systems and collect background data from the plots and soils to assess runoff the nonpoint source pollution and soil physical change in mountainous soils. Eleven 3 $\times$ 15 m runoff plots and monitoring systems were installed at a field of National Alpine Agricultural Experiment Station to monitor soil physical change, and discharge of nonpoint source pollutant. Corn and potato were cultivated under different fertilizer, tillage and residue cover treatments. The soil has a single-layered cluster structure that has a relatively good hydrologic properties and can adsorb a large amount of nutrient. 11 runoff plots were treated and monitored with respect to physical property of the soil, runoff and sediment discharge.

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중소도시 교통사고의 실태분석과 교통경찰의 대응전략 - 안동시를 중심으로 (The characteristics of traffic accidents and Its Counter-measures in Small-Medium City - With the case of Andong City -)

  • 박동균;이상광
    • 시큐리티연구
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    • 제7호
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    • pp.155-189
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    • 2004
  • The mission of the police as described by law is to guard the life, body and property of all citizens. Such duties should be accurately performed based on legal and democratic procedures because the works of the police are directively influencing the overall lives of the citizens by restricting their freedom. We are frequently watching the traffic police on the street or road. Traffic policing aims to reduce crime and the opportunities for criminal activity in relation to the use of roads, that is to improve road user behavior in order to reduce accidents. The characteristics of traffic accident change is not similar in each traffic condition. The purpose of this study is to analysis a type characteristics of traffic accident change, such as number of deaths and wounded persons by the time, the vehicle, the type the road, the age group. Based on the characteristics of traffic accident change, traffic accident countermeasures are proposed, in which some variable of traffic policies such as traffic facilities, traffic regulation, and traffic safety education.

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Theoretical study on electrical behavior of carbon chain inserted single-walled carbon nanotubes compared with Pt doped one

  • Cui, Hao;Zhang, Xiaoxing;Xiao, Hanyan;Tang, Ju
    • Carbon letters
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    • 제25권
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    • pp.55-59
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    • 2018
  • Carbon chain inserted carbon nanotubes (CNTs) have been experimentally proven having undergone pronounced property change in terms of electrical conductivity compared with pure CNTs. This paper simulates the geometry of carbon chain inserted CNTs and analyzes the mechanism for conductivity change after insertion of carbon chain. The geometric simulation of Pt doped CNT was also implemented for comparison with the inserted one. The results indicate that both modification by Pt atom on the surface of CNT and addition of carbon chain in the channel of the tube are effective methods for transforming the electrical properties of the CNT, leading to the redistribution of electron and thereby causing the conductivity change in obtained configurations. All the calculations were obtained based on density functional theory method.

철도차량 운행중 제동디스크의 표면 온도변화 및 디스크 재료의 온도변화에 따른 피로특성 연구 (A Study of the Change of Temperature on Brake Disk Surface during the Service and The Fatigue Characteristic of disk material due to Temperature)

  • 김재훈;구병춘;석창성
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2007년도 춘계학술대회 논문집
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    • pp.792-797
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    • 2007
  • This study investigates the change of the temperature and fatigue property of the braking disk (GC25-30 material) for the railway vehicle. The average temperature is measured about $100^{\circ}C$ and the maximum temperature is measured over $200^{\circ}C$ by non-contact sensor from Seoul to Chun-an. In the $20^{\circ}C-300^{\circ}C$. The Fatigue tests did for new and used disk specimens. The fatigue test results of new disk specimens were similar due to the temperature change. But the compare of specimens between new disk and old disk, The fatigue life of old disk specimens was smaller than new disk specimens about 10%.

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The Apparent Mass Capacity Method for Transient Diffusion Problems with Change of Phase

  • Kim, Yongsoo;Wonmok Jae;D. R. Olander
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1995년도 춘계학술발표회논문집(2)
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    • pp.643-650
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    • 1995
  • A numerical method for treating transient diffusion Involving change of phase is presented. In other methods of dealing with this class of problems, the mass flux balance at the moving phase boundary requires explicit treatment of two distinct phases. The technique, originating from the apparent heat capacity method in transient heat conduction with the phase change, avoids the difficulty by transferring the concentration discontinuity at the boundary to smoothed physical property variations near the moving front. This technique accomodates the nonlinearities which preclude use of analytical solutions. It was tested against known analytical solutions for simple cases and turned out to be quite accurate.

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폴리머 재료에서의 광학적 물성의 온도의존성 (Temperature Dependence of Optical Properties on Polymer Materials)

  • 정승묵;신영곤;이상훈;송국현;김영진;이낙규;나경환
    • 반도체디스플레이기술학회지
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    • 제3권4호
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    • pp.5-11
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    • 2004
  • Optical properties of PET(Polyethylene terephthalate), PC(Polycarbonate), Acrylic resin and PE(Polyethylene) sheets were studied as a function of heat treating temperature of $60^{\circ}C$ to $150^{\circ}C$. By the heat treatment, optical properties of transmittance, absorbance, and reflectance showed a considerable change with different ways according to the materials. To understand the reason of optical property change, X-ray diffraction and surface morphology were also investigated. It was observed that small crystallite and pore that can cause scattering largely affect the transmittance. It was suggested that change of surface chemical bond induce the reflectance variation.

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열처리에 따른 치과도재용 합금의 표면특성에 관한 연구 (The Surface Property Change of the Heat Treated Dental Porcelain Alloy)

  • 남상용;김치영
    • 대한치과기공학회지
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    • 제19권1호
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    • pp.13-19
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    • 1997
  • The purpose of this study was carried out by oberserving to composition of an oxide on the surface of Dental porcelain alloy according to the conditions of its heat treatment and analysing the change composition on its surface. Morphological change of the heat treated dental porcelain alloy have been investigated with SEM and EDX. The result of this study is summarized ad follows. The surface indium concentration of specimens increased as the heat treatment temperature and the oxygen partial pressure increased.

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The study on the thickness change of tantalum oxide as voltage drop in electrolyte

  • Hur, Chang-Wu;Lee, Kyu-Chung
    • Journal of information and communication convergence engineering
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    • 제8권4호
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    • pp.453-456
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    • 2010
  • Tantalum oxide ($Ta_2O_5$) films are of considerable interest for a range of application, including optical waveguide devices, high temperature resistors, and oxygen sensors. In this paper, we establish an anode oxidation process of tantalum thin film. The voltage drop in the electrolyte is affected not in voltage change but in current change. If the voltage drop in the electrolyte is same with cathode oxidation voltage, the current changes logarithmically in proportion to the voltage drop in interface of tantalum oxide and electrolyte. As a result of the measurement on the electrical property of tantalum oxide thin film, when the thickness of the insulator film is $1500{\AA}$, the breakdown voltage is 350volts and dielectric constant is 29.