• Korean Journal of Materials Research
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• v.17 no.6
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• pp.318-322
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• 2007

Porous ${\beta}-tricalcium$ phosphate $({\beta}-TCP)$ bioceramic was fabricated by pressureless sintering using commercial HAp and different volume percentages of PMMA powders (30-60 vol.%). The range of spherical pore size was about $200-250\;{\mu}m$ in diameter. By increasing the PMMA content, the number of pores and their morphology were dramatically changed as well as decreased the material properties. In case of using 60 vol.% PMMA content, network-type pores were found, due to the necking of the PMMA powders. The values of relative density, elastic modulus, bending strength and hardness of the 60 vol.% PMMA content sample, sintered at $1500^{\circ}C$, were about 46%, 22.2 GPa, 5MPa and 182 Hv respectively. Human osteoblast-like MG-63 cells and osteoclast-like Raw 264.7 cells were well grown and fully covered all of the porous ${\beta}-TCP$ bodies sintered at $1500^{\circ}C$.

• Structural Engineering and Mechanics
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• v.19 no.4
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• pp.425-440
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• 2005

In this paper, the behavior of a crack between two half-planes of functionally graded materials subjected to arbitrary tractions is resolved using a somewhat different approach, named the Schmidt method. To make the analysis tractable, it is assumed that the Poisson's ratios of the mediums are constants and the shear modulus vary exponentially with coordinate parallel to the crack. By use of the Fourier transform, the problem can be solved with the help of two pairs of dual integral equations in which the unknown variables are the jumps of the displacements across the crack surfaces. To solve the dual integral equations, the jumps of the displacements across the crack surfaces are expanded in a series of Jacobi polynomials. This process is quite different from those adopted in previous works. Numerical examples are provided to show the effect of the crack length and the parameters describing the functionally graded materials upon the stress intensity factor of the crack. It can be shown that the results of the present paper are the same as ones of the same problem that was solved by the singular integral equation method. As a special case, when the material properties are not continuous through the crack line, an approximate solution of the interface crack problem is also given under the assumption that the effect of the crack surface interference very near the crack tips is negligible. It is found that the stress singularities of the present interface crack solution are the same as ones of the ordinary crack in homogenous materials.

• Earthquakes and Structures
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• v.8 no.1
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• pp.275-304
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• 2015

The objective of this paper is to investigate the validity of transmitting boundaries in dynamic analysis of soil-structure interaction problems. As a case study, the proposed Baghdad metro line is considered. The information about the dimensions and the material properties of the concrete tunnel and surrounding soil were obtained from a previous study. A parametric study is carried out to investigate the effect of several parameters including the peak value of the horizontal component of earthquake displacement records and the frequency of the dynamic load. The computer program (Mod-MIXDYN) is used for the analysis. The numerical results are analyzed for three conditions; finite boundaries (traditional boundaries), infinite boundaries modelled by infinite elements (5-node mapped infinite element) presented by Selvadurai and Karpurapu, 1988), and infinite boundaries modelled by dashpot elements (viscous boundaries). It was found that the transmitting boundary absorbs most of the incident energy. The distinct reflections observed for the "fixed boundaries" disappear by using "transmitted boundaries". This is true for both cases of using viscous boundaries or mapped infinite elements. The type and location of the dynamic load represent two controlling factors in deciding the importance of using infinite boundaries. It was found that the results present significant differences when earthquake is applied as a base motion or a pressure load is applied at the surface ground. The peak value of the vertical displacement at nodes A, B, E and F (located at the tunnel's crown and side walls, and at the surface above the tunnel and at the surface 6.5 m away from tunnel's centre respectively) increases with the frequency of the surface pressure load for both cases 1 and 2 (traditional boundaries and mapped infinite elements respectively) while it decreases for case 3 (viscous boundaries). The modular ratio Ec/Es (modulus of elasticity of the concrete lining to that of the surrounding soil) has a considerable effect on the peak value of the horizontal displacement at node B (on the side wall of the tunnel lining) increase about (17.5) times, for the three cases (1, 2, and 3).

• Macromolecular Research
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• v.11 no.6
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• pp.410-417
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• 2003

Poly(methyl methacrylate-co-acrylonitrile) [P(MMA-co-AN)]/Na-MMT nanocomposites were synthesized through emulsion polymerization with pristine Na-MMT. The nanocomposites were exfoliated up to 20 wt% content of pristine Na-MMT relative to the amount of MMA and AN, and exhibited enhanced storage moduli, E', relative to the neat copolymer. The exfoliated morphology of the nanocomposite was confirmed by XRD and TEM. 2-Acryla-mido-2-methyl-1-propane sulfonic acid (AMPS) widened the galleries between the clay layers before polymerization and facilitated the comonomers, penetration into the clay to create the exfoliated nanocomposites. The onset of the thermal decomposition of the nanocomposites shifted to a higher temperature as the clay content increased. By calculating areas of tan$\delta$ of the nanocomposites, we observed that the nanocomposites show more solid-like behavior as the clay content increases. The dynamic storage modulus and complex viscosity increased with clay content. The complex viscosity showed shear-thinning behavior as the clay content increased. The Young's moduli of the nano-composites are higher than that of the neat copolymer and they increase steadily as the silicate content increases, as a result of the exfoliated structure at high clay content.

• Journal of the Korean Wood Science and Technology
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• v.33 no.3 s.131
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• pp.30-37
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• 2005

This study aimed at offering basic data to develop a new use of sawdust and rice husk. Research investigated the variation of density, weight loss and dimensional decreasing rate by the percentage of resin impregnation and carbonization temperature of ceramics, which were formed by the percentage of resin impregnation of 40~80% and carbonization of $600{\sim}1200^{\circ}C$ with board impregnated with phenolic resin made from sawdust and rice husk. The results of this study were as follows:1) As the percentage of resin impregnation increased, the thickness shrinkage and weight loss were decreased; on the other hand, density and modulus of rupture increased. Meanwhile, the carbonization temperature at $1200^{\circ}C$ showed the highest values, as the density was $0.81g/cm^3$ and the bending strength was $77.9kgf/cm^2$ in the percentage of resin impregnation at 70%. 2) As the carbonization temperature grew higher the linear shrinkage, thickness shrinkage and weight loss increased while the density increased until the carbonization temperature of $1000^{\circ}C$; but then decreased slightly at $1200^{\circ}C$.

• Rubber Technology
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• v.9 no.1
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• pp.1-12
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• 2008

Effects of silane modifier, bis(triethoxysilylpropyl) tetrasulfide (TESPT(S4)) and bis(triethoxysilylpropyl) disulfide (TESPD(S2)), on silica filled compound were investigated upon processability, dynamic, mechanical, heat build-up, blowout properties, and silica dispersion in natural rubber (NR). The temperature of the S2 treated silica compound generated higher than that of the S4 treated compound during internal mixer compounding. The shear viscosity of the S2 compound exhibited lower than that of the S4 compound and the viscosity measured in dynamic mode was close to each other. The elongation modulus of the S2 compound exhibited lower than that of the S4; however, the tear resistance strength of the S2 compound exhibited higher than that of the S4 compound. The loss tan$\delta$ values of the S2 compound exhibited higher than those of the S4 at room temperature. The augmentation of the test temperature lowered the tan$\delta$ values of each compound, which results in close tan$\delta$ values to each other at $100^{\circ}C$. The S2 compound deformed less than the S4 compound, and the blowout time of each compound was close to each other. The S2 compound generated more heat build-up than the S4 compound. The abrasion loss of the S2 compound was less than that of the S4 compound. The size of the silica agglomerate reduced on both S4 and S2 compounds upon vulcanization. The addition of the bifunctional silanes (S2 and S4) on silica filled NR compound improved the processability of each compound and their effects were more significant on the S2 compound than the S4 compound. After vulcanization the silica agglomerate size of each compound reduced compared with before vulcanization.

• Korean Journal of Materials Research
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• v.20 no.4
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• pp.217-222
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• 2010

Zirconium diboride (ZrB2) and mixed diboride of (Zr0.7Ta0.3)B2 containing 30 vol.% silicon carbide (SiC) composites were prepared by hot-pressing at $1800^{\circ}C$. XRD analysis identified the high crystalline metal diboride-SiC composites at $1800^{\circ}C$. The TaB2 addition to ZrB2-SiC showed a slight peak shift to a higher angle of 2-theta of ZrB2, which confirmed the presence of a homogeneous solid solution. Elastic modulus, hardness and fracture toughness were slightly increased by addition of TaB2. A volatility diagram was calculated to understand the oxidation behavior. Oxidation behavior was investigated at $1500^{\circ}C$ under ambient and low oxygen partial pressure (pO2~10-8 Pa). In an ambient environment, the TaB2 addition to the ZrB2-SiC improved the oxidation resistance over entire range of evaluated temperatures by formation of a less porous oxide layer beneath the surface SiO2. Exposure of metal boride-SiC at low pO2 resulted in active oxidation of SiC due to the high vapor pressure of SiO (g), and, as a result, it produced a porous surface layer. The depth variations of the oxidized layer were measured by SEM. In the ZrB2-SiC composite, the thickness of the reaction layer linearly increased as a function of time and showed active oxidation kinetics. The TaB2 addition to the ZrB2-SiC composite showed improved oxidation resistance with slight deviation from the linearity in depth variation.

• Proceedings of the International Microelectronics And Packaging Society Conference
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• 2001.04a
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• pp.35-43
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• 2001

Flip chip assembly on organic substrates using ACAs have received much attentions due to many advantages such as easier processing, good electrical performance, lower cost, and low temperature processing compatible with organic substrates. ACAs are generally composed of epoxy polymer resin and small amount of conductive fillers (less than 10 wt.%). As a result, ACAs have almost the same CTE values as an epoxy material itself which are higher than conventional underfill materials which contains lots of fillers. Therefore, it is necessary to lower the CTE value of ACAs to obtain more reliable flip chip assembly on organic substrates using ACAs. To modify the ACA composite materials with some amount of conductive fillers, non-conductive fillers were incorporated into ACAs. In this paper, we investigated the effect of fillers on the thermo-mechanical properties of modified ACA composite materials and the reliability of flip chip assembly on organic substrates using modified ACA composite materials. Contact resistance changes were measured during reliability tests such as thermal cycling, high humidity and temperature, and high temperature at dry condition. It was observed that reliability results were significantly affected by CTEs of ACA materials especially at the thermal cycling test. Results showed that flip chip assembly using modified ACA composites with lower CTEs and higher modulus by loading non-conducting fillers exhibited better contact resistance behavior than conventional ACAs without non-conducting fillers. Microwave model and high-frequency measurement of the ACF flip-chip interconnection was investigated using a microwave network analysis. ACF flip chip interconnection has only below 0.1nH, and very stable up to 13 GHz. Over the 13 GHz, there was significant loss because of epoxy capacitance of ACF. However, the addition of $SiO_2filler$ to the ACF lowered the dielectric constant of the ACF materials resulting in an increase of resonance frequency up to 15 GHz. Our results indicate that the electrical performance of ACF combined with electroless Wi/Au bump interconnection is comparable to that of solder joint.

• The Journal of Advanced Prosthodontics
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• v.7 no.2
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• pp.98-107
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• 2015

PURPOSE. The aim of this study was to appraise the some mechanical properties of polymethyl methacrylate based denture base resin polymerized by copolymerization mechanism, and to investigate the cytotoxic effect of these copolymer resins. MATERIALS AND METHODS. 2-hydroxyethyl methacrylate (HEMA) and isobutyl methacrylate (IBMA) were added to monomers of conventional heat polymerized and injection-molded poly methyl methacrylate (PMMA) resin contents of 2%, 3%, and 5% by volume and polymerization was carried out. Three-point bending test was performed to detect flexural strength and the elasticity modulus of the resins. To determine the statistical differences between the study groups, the Kruskall-Wallis test was performed. Then pairwise comparisons were performed between significant groups by Mann-Whitney U test. Agar-overlay test was performed to determine cytotoxic effect of copolymer resins. Chemical analysis was determined by FTIR spectrum. RESULTS. Synthesis of the copolymer was approved by FTIR spectroscopy. Within the conventional heat-polymerized group maximum transverse strength had been seen in the HEMA 2% concentration; however, when the concentration ratio increased, the strength decreased. In the injection-molded group, maximum transverse strength had been seen in the IBMA 2% concentration; also as the concentration ratio increased, the strength decreased. Only IBMA showed no cytotoxic effect at low concentrations when both two polymerization methods applied while HEMA showed cytotoxic effect in the injection-molded resins. CONCLUSION. Within the limitations of this study, it may be concluded that IBMA and HEMA may be used in low concentration and at high temperature to obtain non-cytotoxic and durable copolymer structure.

• Journal of The Korean Society of Agricultural Engineers
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• v.61 no.3
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• pp.31-41
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• 2019

More than 90% of roadway in the world are paved as asphalt concrete pavement due to its excellent properties compared with other paving materials; excellent riding quality, flexibility, anti-icing property and easy maintenance-ability. In this study, to make best use of the softer property of the asphalt mixture, the flexible sand asphalt mixture (FSAM) was developed for pedestrian ways. The mix design was conducted to prepare FSAM using PG64-22 asphalt, screenings (sand) less than 5mm, crumb rubber, hydrated lime and limestone powder without coarse aggregate. The deformation strength ($S_D$), indirect tensile strength (ITS) and tensile strength ratio (TSR) tests were conducted to make sure durability of FSAM performance. The impact energy absorption and flexibility were measured by drop-boll test and the resilient modulus ($M_R$) test. The impact energy absorption of FSAM was compared with normal asphalt pavement, concrete pavement, stone and concrete block for pedestrian way. As a result of drop-boll test, FSAM showed higher impact energy absorption compared with other paving materials with the range of 18% to 43%. Impact energy absorption of FSAM increased with increasing test temperature from 5 to $40^{\circ}C$. The results of $M_R$ test at $5^{\circ}C$ showed that the flexibility of FSPA was increased further, because the $M_R$ value of the sand asphalt was measured to be 38% lower than normal dense-graded asphalt mixture (WC-1). Therefore, it was concluded that the FSAM could provide a high impact absorbing characteristics, which would improve walking quality of the pedestrian ways.