• Carbon letters
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• v.11 no.4
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• pp.325-331
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• 2010

This study investigates the effect of filler content (wt%), presence of interphase and agglomerates on the effective Young's modulus of polypropylene (PP) based nanocomposites reinforced with exfoliated graphite nanoplatelets ($xGnP^{TM}$) and carbon nanotubes (CNTs). The Young's modulus of the composites is determined using tensile testing based on ASTM D638. The reinforcement/polymer interphase is characterized in terms of width and mechanical properties using atomic force microscopy which is also used to investigate the presence and size of agglomerates. It is found that the interphase has an average width of ~30 nm and modulus in the range of 5 to 12 GPa. The Halpin-Tsai micromechanical model is modified to account for the effect of interphase and filler agglomerates and the model predictions for the effective modulus of the composites are compared to the experimental data. The presented results highlight the need of considering various experimentally observed filler characteristics such as agglomerate size and aspect ratio and presence and properties of interphase in the micromechanical models in order to develop better design tools to fabricate multifunctional polymer nanocomposites with engineered properties.

• Advances in nano research
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• v.9 no.2
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• pp.83-90
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• 2020

This research investigates the effect of single walled carbon nanotubes (SWCNTs) dimensions in terms of diameter on the mechanical properties (longitudinal and transverse Young's modulus) of the simulated nanocomposites by molecular dynamics (MDs) method. MDs utilized to create nanocomposite models consisting of five case studies of SWCNTs with different chiralities (5, 0), (10, 0), (15, 0), (20, 0) and (25, 0) as the reinforcement and using polymethyl methacrylate (PMMA) as the common matrix. The results show that with increasing of SWCNTs diameter, the mechanical and physical properties increase. It is important that with the increasing of SWCNTs diameter, density, longitudinal and transverse Young's modulus, shear modulus, poisson's ratio, and bulk modulus of simulated nanocomposite from (5, 0) to (25, 0) approximately becomes 1.54, 3, 2, 1.43, 1.11 and 1.75 times more than (5, 0), respectively. Then to validate the results, the stiffness matrix is obtained by Materials studio software.

• Journal of Forest and Environmental Science
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• v.31 no.4
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• pp.267-271
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• 2015

The variations of wood density and mechanical properties of Juniperus polycarpos trees were studied in a natural forest in Iran. Sample disks were taken from each tree to examine wood density and mechanical properties (MOE and MOR) from pith to bark at breast height, 50%, and 75% of total tree height. The analysis of variance (ANOVA) indicated that radial position and height significantly affected all wood properties. The wood density, MOE and MOR were decreased along horizontal position from the pith to the bark and vertical direction from base upwards. Regression analysis showed that modulus of elasticity (MOE) and modulus of rupture (MOR) had a positive correlation with wood density.

• Proceedings of the KSR Conference
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• 2007.11a
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• pp.852-858
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• 2007

The durability of carbon/epoxy composites under salt water environment was investigated through salt water spray tester. Salt water environment was obtained through salt spray and salt immersion. 5% NaCl solution was used for salt water as natural salt water. Mechanical test was performed to obtain tensile properties, flexural properties, and shear properties of carbon/epoxy composite over 12 months under salt water environment. Dynamic mechanical analyzer was used to investigate thermal analysis properties such storage modulus, loss modulus, and tan ${\delta}$. Also FT/IR test was conducted to investigate a change in chemical structure. According to the results, mechanical properties were found to be slowly degraded as a function of exposure times. Regarding to thermal analysis properties, storage modulus was insensitive to exposure times, but loss modulus was shown to be slightly decreased. Although the shape and location of peak in FT/IR were not much changed, the intensity of peak in FT/IR was affected on exposure times. We also found that salt water immersion was more severe to the durability of carbon/epoxy composite rather than salt water spray.

• Journal of the Korean Wood Science and Technology
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• v.33 no.5 s.133
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• pp.7-12
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• 2005

The objective of this study is to estimate the mechanical behavior in bending and the anatomical changes of wood under several deflection rates. Sample specimens of water-saturated Japanese cedar (Cryptomeria japonica) were stressed to rupture under several deflection rates. Mechanical properties of wood such as modulus of elasticity, modulus of rupture and stress at proportional limit, and anatomical changes affected by deflection rates were estimated. Microscopic observations on compression side of the test specimens when the specimen was loaded to rupture were carried out by the SEM (scanning electron microscopy). The results are summarized as follows: 1. The mechanical properties of wood were affected by variations of the deflection rates. The modulus of elasticity (MOE), modulus of rupture (MOR) and stress at proportional limit were in proportion to the logarithm of deflection rates. 2. The deflection of wood at rupture in bending increased as deflection rates decreased. 3. The variations of the microscopic deformations of sample specimens were closely related to the deflection of wood at rupture. In case of largely deflected wood by maximum bending load, severe and abundant microscopic deformations were observed.

• Structural Engineering and Mechanics
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• v.38 no.4
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• pp.503-516
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• 2011

Uncertainty in concrete properties, including concrete modulus of elasticity and modulus of rupture, are predicted by developing a microstructural homogenization model. The homogenization model is developed by analyzing a concrete representative volume element (RVE) using the finite element (FE) method. The concrete RVE considers concrete as a three phase composite material including: cement paste, aggregate and interfacial transition zone (ITZ). The homogenization model allows for considering two sources of variability in concrete, randomly dispersed aggregates in the concrete matrix and uncertain mechanical properties of composite phases of concrete. Using the proposed homogenization technique, the uncertainty in concrete modulus of elasticity and modulus of rupture (described by numerical cumulative probability density function) are determined. Deflection uncertainty of reinforced concrete (RC) beams, propagated from uncertainties in concrete properties, is quantified using Monte Carlo (MC) simulation. Cracked plane frame analysis is used to account for tension stiffening in concrete. Concrete homogenization enables a unique opportunity to bridge the gap between concrete materials and structural modeling, which is necessary for realistic serviceability prediction.

• Bulletin of the Korean Chemical Society
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• v.34 no.7
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• pp.2171-2175
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• 2013

The electronic structure and elastic properties of the 4d transition metal carbides MC (M = Y, Zr, Nb, Rh) were studied by means of extended H$\ddot{u}$ckel tight-binding band electronic structure calculations. As the valence electron population of M increases, the bulk modulus of the MC compounds in the rocksalt structure does not increase monotonically. The dominant covalent bonding in these compounds is found to be M-C bonding, which mainly arises from the interaction between M 4d and C 2p orbitals. The bonding characteristics between M and C atoms affecting the variation of the bulk modulus can be understood on the basis of their electronic structure. The increasing bulk modulus from YC to NbC is associated with stronger interactions between M 4d and C 2p orbitals and the successive filling of M 4d-C 2p bonding states. The decreased bulk modulus for RhC is related to the partial occupation of Rh-C antibonding states.

• Korea-Australia Rheology Journal
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• v.20 no.4
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• pp.227-233
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• 2008

High impact polystyrene (HIPS)/organoclay nanocomposites via in situ polymerization were synthesized and their rheological properties were investigated. For the study, two types of organoclays were used: a commercially available organoclay, Cloisite 10A (C10A), and a laboratory-prepared organoclay having a reactant group, vinylclay (ODVC). The X-ray diffraction and transmission electron microscopy experiments revealed that the HIPS/ODVC nanocomposite achieved an exfoliated structure, whereas the HIPS/C10A nanocomposite achieved an intercalated structure. In the small-amplitude oscillatory shear experiments, both storage modulus and complex viscosity increased with increasing organoclay. A pronounced effect of the organoclay content was observed, resulting in larger storage modulus and stronger yield behavior in the low frequency region when compared to neat HIPS. The crossover frequencies associated with the inverse of a longest relaxation time decreased as the organoclay content increased. Over a certain value of ODVC content, a change of pattern in rheological properties could be found, indicating a solid-like response with storage modulus greater than loss modulus at all frequencies.

• The Journal of Korean Academy of Prosthodontics
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• v.44 no.1
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• pp.10-19
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• 2006

Statement of problem : The various kinds of properties of post and core may affect the stress distribution to the root of endodontically treated teeth Purpose: To evaluate the influence of various kinds of properties of post and core to the stress distribution to the root of endodontically treated teeth. Material and methods: Mandibular first premolar, prepared by general shape of post and core with gold crown, was used to two dimensional axisymmetric modeling for finite element analysis. Then property values of 8 different kinds of post and core was substituted for each. Finally, stress distribution shown areas around the root of post and core was analysed after applying 50N of vortical and oblique load. Results: 1. Stress value of oblique load was much higher than the maximum stress value of vertical load. 2. Under oblique load, very concentrated stress was located on post periapical area and variations in stress were very severe. Contrary to this, stress distribution was relatively uniform in vertical load. 3. Post materials with higher elastic modulus showed relatively more apically focused stress, and post materials with lower elastic modulus showed stress focused on cervical area on the axial wall of post. 4. Stress change according to the properties of core was shown only in the cervical area of post and below core as the higher elastic modulus, then increased in stress. 5. Post and core with medium value of elastic modulus showed relatively uniform stress distribution. Conclusions: Post materials with higher elastic modulus showed relatively more apically focused stress, and post materials with lower elastic modulus showed stress focused on cervical area on the axial wall of post. Stress change according to the properties of core was shown only in the cervical area of post and below core.

• Journal of the Korean Society for Nondestructive Testing
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• v.9 no.2
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• pp.18-24
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• 1989

Computer-aided high frequency ultrasonic is applied to aluminum oxide(85w%, 94w%, 96w%, and 99w%) MOR(modulus of rupture) samples to evaluate mechanical properties such as density variation, pore content, elastic modulus, shear modulus, and poisson's ratio. Ultrasonic wave velocity and attenuation measurement techniques were used as an evaluator of such properties. Pulse-echo C-Scan images with different fate setting method using 50MHz center frequency 1 inch focal length transducer allows evaluation of density variation and pore content. Elastic modulus calculated with the relation of density and ultrasonic velocity. It shows good reliability as compared with resonance method. Sintered density variation of $0.025g/cm^{3}$, that is 0.6% of theoretical density in $Al_{2}O_{3}$ samples can be observed by ultrasonic velocity measurement. Attenuation measurement method qualitatively agree with 4-point fracture testing result concerning of porosity content.