• Bulletin of the Korean Chemical Society
• /
• 제32권5호
• /
• pp.1527-1533
• /
• 2011

The reaction of gas-phase atomic hydrogen with oxygen atoms chemisorbed on a silicon surface is studied by use of the classical trajectory approach. We have calculated the probability of the OH formation and energy deposit of the reaction exothermicity in the newly formed OH in the gas-surface reaction H(g) + O(ad)/Si${\rightarrow}$ OH(g) + Si. All reactive events occur in a single impact collision on a subpicosecond scale, following the Eley-Rideal mechanism. These events occur in a localized region around the adatom site on the surface. The reaction probability is dependent upon the gas temperature and shows the maximum near 1000 K, but it is essentially independent of the surface temperature. The reaction probability is also independent upon the initial excitation of the O-Si vibration. The reaction energy available for the product state is carried away by the desorbing OH in its translational and vibrational motions. When the initial excitation of the O-Si vibration increases, translational and vibrational energies of OH rise accordingly, while the energy shared by rotational motion varies only slightly. Flow of energy between the reaction zone and the solid has been incorporated in trajectory calculations, but the amount of energy propagated into the solid is only a few percent of the available energy released in the OH formation.

• 한국에너지공학회:학술대회논문집
• /
• 한국에너지공학회 2003년도 춘계 학술발표회 논문집
• /
• pp.703-706
• /
• 2003

일반적인 연구개발투자 사업은 기술개발 단계에 머물러 현실 적용을 통한 부가가치 창출에 어려움을 겪어왔다. 기술개발이 단순히 연구에서 그칠 것이 아니라 보다 현실적인 결과 도출을 유도하기 위해서 상용화 및 해당 수요 산업에 대한 체계적인 접근이 요구된다. 본 연구에서는 현재 진행중인 국가 지원 R&D 사업을 대상으로 해당 대상의 구체적인 수요산업을 파악하고 기술제품산업연관분석이라는 개념에서의 접근을 통해 기술개발지원의 체계적 사용화 전략에 대한 기초 정보를 제공한다.(중략)

• Bulletin of the Korean Chemical Society
• /
• 제33권2호
• /
• pp.589-596
• /
• 2012

In this paper, the reactive dynamics properties of the reactions Ba + $C_6H_5Br$ and Ba + m-$C_6H_4CH_3Br$ were studied by means of the quasi-classical trajectory method based on the London-Eyring-Polanyi-Sato potential energy surfaces. The vibrational distributions, reaction cross sections, rotational alignments of the products BaBr all were obtained. The peak values of the vibrational distributions are located at $\nu$ = 0 for the reactions Ba + $C_6H_5Br$ and Ba + m-$C_6H_4CH_3Br$ when the collision energies are 1.09 and 1.10 eV, respectively. The reaction cross sections increase with the increasing collision energy, which changes from 0.6 to 1.5 eV. The product rotational alignments deviate from -0.5 and firstly increase and then decrease while the collision energy is increasing, just like that of Heavy+Light-Light system.

• Bulletin of the Korean Chemical Society
• /
• 제23권12호
• /
• pp.1737-1743
• /
• 2002

We have studied the dynamics of energy-rich hydrogen molecules produced on a graphite surface through H(g) + H(ad)/C(gr) → $H_2$ + C(gr) at thermal conditions mimicking the interstellar medium using a classical trajectory procedure. The recombination reaction of gaseous H atom at 100 K and the adsorbed H atom on the interstellar graphite grains at 10 K efficiently takes place on a subpicosecond time scale with most of the reaction exothermicity depositing in the product vibration, which leads to a strong vibrational population inversion. The molecules produced in nearly end-on geometry where H(g) is positioned below H(ad) rotate clockwise and are more highly rotationally excited. but in low-lying vibrational levels. The rotational axis of most of the molecule rotating clockwise is tilted from the surface normal by more than 30°, the intensity peaking at 35°. The molecules produced when H(ad) is close to the surface rotate counter-clockwise and are weakly rotationally excited, but highly vibrationally excited. These molecules tend to align their rotational axes parallel to the surface. The number of molecules rotating clockwise is eight times larger than that rotating counter-clockwise.

• 한국생산제조학회지
• /
• 제21권3호
• /
• pp.459-464
• /
• 2012

The point of impact, the shot group, and the flight traces depend on the combination of unique features which decide moving traces of the arrow (paradox of the archer, length of the arrow shaft, weight, angle of the feather, and spline of the arrow shaft). The more dense the impact points in the shot group and the earlier elimination of paradox of the archer, the higher assessment is given for the product. However, there is no way to objectively assess the efficiency and quality of the arrow, and there is no numeric data to be used as the basis for comparison with other products. Although capturing the images of flying arrow using a high-speed motion picture camera is possible, we are limited to observation from specific view angle only. Hence, the criteria for efficiency and quality assessment are mostly based on subjective opinions of experts or hunters, or review on consumers' remarks. In this paper, we propose a hardware composition that are based on three detection frames consisting of line lasers and photo diode arrays without the high-speed motion picture camera. Predicated on measured coordinates data, a nobel method for the archer's paradox measurement, a key parameter that determine the arrow's trajectory, and corresponding numerical analysis model is proposed.

• International Journal of Aeronautical and Space Sciences
• /
• 제18권3호
• /
• pp.512-521
• /
• 2017

This paper reports development process of a university-based sounding rocket using simplified hybrid rocket propulsion system for low-altitude flight application. A hybrid propulsion system was tried to be designed with as few components as possible for more economical, simpler and safer propulsion system, which is essential for the small scale sounding rocket operation as a CanSat carrier. Using blow-down feeding system and catalytic ignition as combustion starter, 250 N class hybrid rocket system was composed of three components: a composite tank, valves, and a thruster. With a composite tank filled with both hydrogen peroxide($H_2O_2$) as an oxidizer and nitrogen gas($N_2$) as a pressurant, the feeding pressure was operated in blowdown mode during thruster operation. The $MnO_2/Al_2O_3$ catalyst was fabricated for propellant decomposition, and ground test of propulsion system showed the almost theoretical temperature of decomposed $H_2O_2$ at the catalyst reactor, indicating sufficient catalyst efficiency for propellant decomposition. Auto-ignition of the high density polyethylene(HDPE) fuel grain successfully occurred by the decomposed $H_2O_2$ product without additional installation of any ignition devices. Performance test result was well matched with numerical internal ballistics conducted prior to the experimental propulsion system ground test. A sounding rocket using the developed hybrid rocket was designed, fabricated, flight simulated and launch tested. Six degree-of-freedom trajectory estimation code was developed and the comparison result between expected and experimental trajectory validated the accuracy of the developed trajectory estimation code. The fabricated sounding rocket was successfully launched showing the effectiveness of the simplified hybrid rocket propulsion system.

• 대한임베디드공학회논문지
• /
• 제14권6호
• /
• pp.339-346
• /
• 2019

Multi-axis servo systems are widely used in various fields such as industiral systems for improving production efficiency, robotics and complex systems where many mechanical devices and sensor systems are connected. Such a servo system requires that the servo control technique to realize the synchronization of the drive shaft in the steady state and transient conditions and to control so as to follow the target track in order to improve product precision and production efficiency. In addition, embedded type hardware is required for smooth control of the entire multi-axis system. Therefore, this paper uses hardware based on FPGA which is widely used in digital signal processing field and various control system because hardware design change is easy and parallel processing is possible. In addition, Labview based servo motor control program was studied that can control the servo motor by ensuring the performance and flexibility of the FPGA and follow the target trajectory according to various speed processing and accurate timing synchronization.

• 제어로봇시스템학회:학술대회논문집
• /
• 제어로봇시스템학회 1987년도 한국자동제어학술회의논문집; 한국과학기술대학, 충남; 16-17 Oct. 1987
• /
• pp.317-323
• /
• 1987

A pressure tracking control of hydroforming processes, which is used in the precision forming of. sheet metals, is considered in this paper. The hydroforming of sheet metal is performed between the high-pressure chamber controlled by pressure control valve and the punch moving with constant speed. Since the pressure in the forming chamber is a critical factor to the quality of the product severely. It is important to control the pressure to follow a prescribed pressure trajectory, depending upon the material volume and shape of the parts to be formed. Taking into consideration of the volume chamge of forming chamber during the process and the nonlinearity of the electro-magnetic relief valve, a mathematical formulation of the model describing the dynamic characteristics of this model obtained. Based upon this model a PID controller is designed for the pressure tracking.

• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 1996년도 특별강연 및 춘계학술발표 개요집
• /
• pp.96-98
• /
• 1996

Welding of corner area across the edge is a difficult problem in robotized arc welding system, especially when continuously-welded leakage-proof product is required. This paper presents the methodology of cooperation plan of an arc welding robot and 1 or 2 axis welding manipulators for corner area welding. Welding trajectory for the robot is generated using clothoid curves; symmetrical double clothoid curve or unsymmetrical clothoid curve depending on the nature of the workpiece. The clothoid curve is first formulated for the case of linear type positioning table and then applied to the case of rotary type manipulator. The methodology is then illustrated for practical downhand welding situations.

• 한국에너지공학회:학술대회논문집
• /
• 한국에너지공학회 2003년도 춘계 학술발표회 논문집
• /
• pp.613-616
• /
• 2003

우리나라의 에너지 수요면에서 살펴보면 가정 및 상업부문은 냉난방, 급탕용 에너지수요의 급증으로 높은 증가율을 보일 전망이다. 냉난방, 급탕용 에너지수요는 10$0^{\circ}C$ 미만의 비교적 중저온이며, 이러한 열수요에 대해 수백도에서 천도 이상의 온도를 얻을 수 있는 화석연료의 연소에 의해 공급하는 것은 에너지ㆍ환경면에서 불합리하다. 또한 도시지역내에서 외부로 배출되고 있는 각종 온도의 열에너지는 도시환경의 저해하고 있어, 에너지절약과 도시환경을 위해 미활용에너지의 이용에 대한 관심이 증가하였다.(중략)