• Title/Summary/Keyword: process water

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A Study on the removal of Metallic Impurities on Si-wafer using Electrolyzed Water (전해수를 이용한 실리콘 웨이퍼 표면의 금속오염 제거)

  • Yoon, Hyo-Seob;Ryoo, Kun-Kul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.1-5
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    • 2000
  • As the semiconductor devices are miniaturized, the number of the unit cleaning processes increases. In order to processes by conventional RCA cleaning process, the consumption of volume of liquid chemical and DI water became huge. Therefore, the problem of environmental issues are evolved by the increased consumption of chemicals. To resolve this matter, an advanced cleaning process by Electrolyzed Water was studied in this work. The electrolyzed water was made by an electrolysis equipment which was composed of three chambers of anode, cathode, and middle chambers. In the case of electrolyzed water with electrolytes in the middle chamber, oxidatively acidic water of anode and reductively alkaline water of cathode were obtained. The oxidation/reduction potentials and pH of anode water and cathode water were measured to be +l000mV and 4.8, and -530mV and 6.3, respectively. The Si-wafers contaminated with metallic impurities were cleaning with the electrolyzed water. To analysis the amounts of metallic impurities on Si-water surfaces, ICP-MS(Inductively Coupled Plasma-Mass spectrometer) was introduced. From results of ICP-MS measurements, it was concluded that the ability of electrolyzed water was equivalent to that of the conventional RCA cleaning.

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Comparative Water Relations of Two Vitis vinifera Cultivars, Riesling and Chardonnay

  • Park, Yong-Mok
    • The Korean Journal of Ecology
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    • v.24 no.4
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    • pp.223-226
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    • 2001
  • The leaf water relations and photosynthetic rate during acute soil drying were compared in potgrown grapevine cultivars, Vitis vinifera cv. Chardonnay and V. vinifera cv. Riesling. Leaf water potential in Riesling decreased significantly from day 2 after water had been withheld, while in Chardonnay leaf water potential for the water-stressed plants was almost identical with that in well watered plants during the first 4 days. Higher stomatal conductance and photosynthetic rate in Chardonnay than Riesling were observed until day 3 after withholding water. Photosynthetic rate in water-stressed Chardonnay was not different from that in control plants until day 3 after withholding water, while that in water-stressed Riesling was reduced markedly from day 2. In Riesling, osmotic potential at turgor loss point was not changed irrespective of watering conditions. However, in Chardonnay osmotic potential at turgor loss point decreased more in the water stressed conditions than in well watered conditions. The osmotic adjustment in Chardonnay under water stress conditions must contribute to the maintenance of higher stomatal conductance and photosynthetic rate than those in Riesling for a significant period of the drying process. Though difference in stomatal conductance between the two cultivars was shown in the process of soil drying, stomatal conductance of both cultivars responded to vapor pressure difference between leaf and ambient air, rather than soil water status and leaf water potential.

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Effect of γ-ray Irradiation on THMs Formation and Water Quality Characteristics in the Chlorination of Humic Acid Contaming Water (감마선 조사가 휴민산 염소화에 의한 THMs 생성능 및 수질특성에 미치는 영향)

  • Kang, Chul-ho;Lim, Hyun-woo;Jung, Sung-woon;Choi, Jong-hyuk;Kim, Jong-hoon;Choi, Yong-wook;Lee, Myun-joo
    • Journal of Korean Society on Water Environment
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    • v.26 no.6
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    • pp.1034-1039
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    • 2010
  • Variation of formation potential of THM (THMFP) by chlorination of humic acid and characteristics of water quality with ${\gamma}$-ray irradiation were investigated, which were divided into two categories by the order of ${\gamma}$-ray irradiation and chlorination in water treatment process. The group A consisted of the ${\gamma}$-ray irradiation followed by chlorination process of humic acid, and the group B consisted of the chlorination followed by ${\gamma}$-ray irradiation process. The pH, ORP, $UV_{254}$, and DOC decreased rapidly with an increase in ${\gamma}$-ray irradiation of 3 kGy. while conductivity was little changed. Maximum degradation ratio of chloroform in THMs of group A was 82%, while that in group B was 69%. No brominated THMs were detected at high irradiation (>3 kGy). We found that group A water treatment process was more effective in lowering the THMFP than that of group B.

Evaluating membrane fouling and its field applicability under different physical cleaning conditions in MBRs (MBR 공정에서 물리세정 조건에 따른 막 오염 제어 성능 평가와 현장 적용성에 관한 연구)

  • Park, Jeonghoon;Kim, Hyungsoo;Park, Kitae;Park, Jungwoo;Park, Sekeun;Kang, Heeseok;Kim, Jihoon
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.5
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    • pp.605-612
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    • 2016
  • Membrane bioreactors (MBRs) employ a process of biological treatment that is based on a membrane that has the advantages of producing high-quality treated water and possessing a compact footprint. However, despite these advantages, the occurrence of "fouling" during the operation of these reactors causes the difficulty of maintenance. Hence, in this study, three physical cleaning methods, namely, backwashing, air scrubbing, and mechanical cleaning ball was performed to identify optimum operating conditions through laboratory scale experiments, and apply them in a pilot plant. Further, the existing MBR process was compared with these methods, and the field applicability of a combination of these physical cleaning methods was investigated. Consequently, MCB, direct control of cake fouling on the membrane surface was found to be the most effective. Moreover, as a result of operating with combination of the physical cleaning process in a pilot plant, the TMP increasing rate was found to be - 0.00007 MPa/day, which was 185% higher than that obtained using the existing MBR process. Therefore, assuming fouling only by cake filtration, about one year of operation without chemical cleaning is considered to be feasible through the optimization of the physical cleaning methods.

Optimal Operation Condition of Livestock Wastewater Treatment Using Shortcut Biological Nitrogen Removal Process (단축질소제거 공정을 이용한 가축분뇨의 적정 처리조건 연구)

  • Jin-Young Kang;Young-Ho Jang;Byeong-Hwan Jeong;Yeon-Jin Kim;Yong-Ho Kim
    • Journal of Korean Society on Water Environment
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    • v.39 no.5
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    • pp.390-395
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    • 2023
  • The feasibility of applying the shortcut nitrogen removal process to treat livestock wastewater on individual farms was examined, and appropriate operating parameters were established. As a result,, it was determined that the nitrification reaction was carried out under 550 mg/L of ammonium nitrogen concentration, but it was less effective under conditions of high ammonia concentration. Consequently, it was confirmed that a partial injection of inflow water was necessary to minimize the effects of ammonia toxicity. Following the sequential batch reactor (SBR) operation results, it was difficult to achieve the effluent quality standard without an external carbon source. Also, selection of the appropriate hydraulic retention time was critical for the optimal SBR operation. Following the livestock farm application, with external carbon source injecting, the total nitrogen concentration in the effluent was 85.1 mg/L. This result revealed that the standard could be accomplished through a single treatment on individual livestock farms. The ratio of nitrite nitrogen to ammonia nitrogen in the effluent was verified to be suitable for implementing the anammox process with a 10 days of hydraulic retention time. This study demonstrated the potential applicability of process in the future. However, in order to apply to livestock farms, managing variations in wastewater load across individual farms and addressing reduced nitrogen oxidation efficiency during the winter season are crucial.

Optimization of an Advanced Oxidation with Ozone and Ceramic Membrane Integrated Process for Greywater Reuse (중수 재이용을 위한 오존 고도산화 및 세라믹 분리막 일체형 공정의 최적화 연구)

  • Lee, Jonghun;Rho, Hojung;Park, Kwang Duck;Woo, Yun Chul
    • Journal of Korean Society on Water Environment
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    • v.37 no.6
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    • pp.433-441
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    • 2021
  • The aim of this study was to optimize the ozonation and ceramic membrane integrated process for greywater reclamation. The integrated process is a repeated sequential process of filtration and backwash with the same ceramic membrane. Also, this study used ozone and oxygen gas for the backwashing process to compare backwashing efficiency. The study results revealed that the optimum filtration and backwash time for the process was 10 minutes each when comparing the filtrate flow and membrane recovery rate. The integrated process was operated at three different operating conditions with i) 10 minutes for filtration and 10 minutes for ozonation, ii) 10 minutes for filtration and 10 minute for oxygen aeration, and iii) continuous filtration without any aeration for synthetic greywater. The integrated process with ozone backwashing could produce 0.55 L/min of filtrate with an average of 18.42% permeability recovery, while the oxygen backwashing produced 0.47 L/min and 6.26%, respectively. And without any backwashing, the integrated process could produce 0.29 L/min. This shows that the ozone backwash process is capable of periodically recovering from membrane fouling. The resistance of the fouled membrane was approximately 34.4% for the process with ozone backwashing, whereas the resistance was restored by 10.8% for the process with oxygen backwashing. Despite the periodical ozone backwashing and chemical cleaning, irreversible fouling gradually increased approximately 3 to 4%. Approximately 97.6% and 15% turbidity and TOC were removed by ceramic membrane filtration, respectively. Therefore, the integrated process with ozonation and ceramic membrane filtration is a potential greywater treatment process.

Solid Separation and Flotation Characteristics of Livestock Wastewater Using DAF Process (DAF 공정을 이용한 축산폐수의 고형물 분리와 부상특성)

  • Kang, Byong-Jun;Yoo, Seung-Joon;Lee, Se-il;Kwak, Dong-Heui
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.3
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    • pp.359-366
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    • 2008
  • The series of experiments under the various conditions were carried out to evaluate the feasibility of dissolved air flotation (DAF) as an alternative of conventional gravity sedimentation (CGS) and to investigate the decrease of the loadings following to biological wastewater treatment processes in livestock wastewater system. On the basis of the experiment result between CGS and DAF processes, for the other water quality criteria as well as suspended solid the removal efficiency of DAF process was about 20~25 % better than CGS process on average. In addition, the particle removal efficiency of DAF process became higher in proportion as the increase of air to solid (A/S) ratio and the general wastewater treatment efficiency of DAF process was enough to meet the requirement of loading decrease to following biological process even at low A/S ratio range. Though DAF process is widely known as an solid separation unit, there was not the notable relationship between particle separation efficiency and several pollutant removal efficiencies like $COD_{Cr}$ and nutrients (T-N, T-P). Assume that the $COD_{Cr}$ was removed as the fraction of particle separation in this experiment, the removal efficiency of T-N and T-P were sensitive to removal efficiency of $COD_{Cr}$, especially.

Effects of membrane fouling formation by feed water quality and membrane flux in water treatment process using ceramic membrane (세라믹 막여과 정수처리 공정에서 유입수질 및 막여과유속이 막오염 형성에 미치는 영향)

  • Kang, Joon-Seok;Park, Seo-Gyeong;Lee, Jeong-Jun;Kim, Han-Seung
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.2
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    • pp.77-87
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    • 2018
  • In this study, the effects of operating conditions on the formation of reversible and irreversible fouling were investigated in the filtration using ceramic membrane for water treatment process. The effect of coagulation pretreatment on fouling formation was also evaluated by comparing the performance of membrane filtration both with and without addition of coagulant. A resistance-in-series-model was applied for the analysis of membrane fouling. Total resistance (RT) and internal fouling resistance (Rf) increased in the membrane filtration process without coagulation as membrane flux and feed water concentrations increased. Internal fouling resistance, which was not recovered by physical cleaning, was more than 70% of the total resistance at the range of the membrane flux more than $5m^3/m^2{\cdot}day$. In the combined process with coagulation, the cake layer resistance (Rc) increased to about 30-80% of total resistance. As the cake layer formed by coagulation floc was easily removed by physical cleaning, the recovery rate by physical cleaning was 54~90%. It was confirmed from the results that the combined process was more efficient to recover the filtration performance by physical cleaning due to higher formation ratio of reversible fouling, resulted in the mitigation of the frequency of chemical cleaning.

Investigation of geosmin removal efficiency by microorganism isolated from biological activated carbon (생물활성탄에서 분리한 미생물의 지오스민 제거효율 평가)

  • Baek, Dawoon;Lim, Jaewon;Cho, Yoonjung;Ahn, Yong-Tae;Lee, Hyeyoung;Park, Donghee;Jung, Dongju;Kim, Tae-Ue
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.1
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    • pp.47-55
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    • 2015
  • Recently, the production of taste and odor (T&O) compounds is a common problem in water industry. Geosmin is one of the T&O components in drinking water. However, geosmin is hardly eliminated through the conventional water treatment systems. Among various advanced processes capable of removing geosmin, adsorption process using granular activated carbon (GAC) is the most commonly used process. As time passes, however GAC process changes into biological activated carbon (BAC) process. There is little information on the BAC process in the literature. In this study, we isolated and identified microorganisms existing within various BAC processes. The microbial concentrations of BAC processes examined were $3.5{\times}10^5$ colony forming units (CFU/g), $2.2{\times}10^6CFU/g$ and $7.0{\times}10^5CFU/g$ in the Seongnam plant, Goyang plant and Goryeong pilot plant, respectively. The dominant bacterial species were found to be Bradyrhizobium japonicum, Novosphingobium rosa and Afipia broomeae in each plants. Removal efficiencies of $3{\mu}g/L$ geosmin by the dominant species were 36.1%, 36.5% and 34.3% in mineral salts medium(MSM) where geosmin was a sole carbon source.

Optimization of Distillation-Pervaporation Membrane Hybrid Process for Separation of Water/Organic Solvent Mixtures (물/유기용매 분리를 위한 증류-투과증발막 혼성공정의 최적화)

  • Yang, Jeongin;Han, Myungwan
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.29-41
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    • 2018
  • Separating a mixture having an azeotrope or low relative volatility with single distillation column is difficult. Separating water-acetic acid mixture and water-ethanol mixture with a distillation column consumes a lot of energy. Pervaporation membrane can be used to separate the mixture in the concentration region where separation is difficult with distillation. We simulated a distillation-membrane hybrid process where membrane is located on the head of the distillation column for efficient separation of water-acetic acid and water-ethanol mixture. Permeability data were obtained from experiments and literature. We formulated an optimization problem for the process with total annual cost (TAC) as an objective function and major design variables as optimization variables. Major optimization variable affecting TAC of the hybrid process was shown to be distillate concentration. We also suggested a simplified optimization procedure to get a close-to-optimal solution.